Porphyrazines as molecular scaffolds: flexible syntheses of novel multimetallic complexes

Reductive deselenation of selenodiazole-fused porphyrazines, followed by acylation of the resultant labile porphyrazinediamines, was used to prepare macrocycles bearing two Collins ligands, two oxamido residues, or two quinoline-2-carboxamido units. Peripheral coordination of copper(II) to the di-(quinoline-2-carboxamido)-porphyrazine gave a metal-linked face-to-face porphyrazine dimer array. Sequential derivatization of the two amino groups in the porphyrazinediamines was used to prepare mixed peripheral ligand systems including a dimetallic picolinamido-Schiff base porphyrazine. Such systems exhibit strong metal-metal spin coupling and are anticipated to be of value in the synthesis of novel electronic and magnetic materials.     

Cryogenic NMR spectroscopy of endohedral hydrogen-fullerene complexes

We have observed 1H NMR spectra of hydrogen molecules trapped inside modified fullerene cages under cryogenic conditions. Experiments on static samples were performed at sample temperatures down to 4.3 K, while magic-angle-spinning (MAS) experiments were performed at temperatures down to 20 K at spinning frequencies of 15 kHz. Both types of NMR spectra show a large increase in the intramolecular 1H-1H dipolar coupling at temperatures below 50 K, revealing thermal selection of a small number of spatial rotational states. The static and MAS spectra were compared to estimate the degree of sample heating in high-speed cryogenic MAS-NMR experiments. The cryogenic MAS-NMR data show that the site resolution of magic-angle-spinning NMR may be combined with the high signal strength of cryogenic operation and that cryogenic phenomena may be studied with chemical site selectivity.     

Intersection models of weakly chordal graphs

We first present new structural properties of a two-pair in various graphs. A two-pair is used in a well-known characterization of weakly chordal graphs. Based on these properties, we prove the main theorem: a graph G is a weakly chordal ()-free graph if and only if G is an edge intersection graph of subtrees on a tree with maximum degree 4. This characterizes the so called [4, 4, 2] graphs. The proof of the theorem constructively finds the representation. Thus, we obtain an algorithm to construct an edge intersection model of subtrees on a tree with maximum degree 4 for such a given graph. This is a recognition algorithm for [4, 4, 2] graphs.     

NMR probing of the spin polarization of the ν=5/2 quantum Hall state

Resistively detected nuclear magnetic resonance is used to measure the Knight shift of the 75As nuclei and determine the electron spin polarization of the fractional quantum Hall states of the second Landau level. We show that the 5/2 state is fully polarized within experimental error, thus confirming a fundamental assumption of the Moore-Read theory. We measure the electron heating under radio frequency excitation and show that we are able to detect NMR at electron temperatures down to 30 mK.     

ChemInform Abstract: Copper(I) and Copper(II) Coordination Structure under Hydrothermal Conditions at 325 °C: An X‐Ray Absorption Fine Structure and Molecular Dynamics Study.

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.