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61.
Stephen W. Burgess Jogin R. Wu Kerry Swift Barry R. Lentz 《Journal of fluorescence》1991,1(2):105-112
Rate constants were determined for the transfer of the fluorescent lipid probe 1-palmitoyl-2-[[2-[4-(6-phenyl-trans-1,3,5-hexatrienyl)phenyl]ethyl] oxy]carbonyl]-3-sn-phosphatidylcholine (DPHpPC) between large, unilamellar extrusion vesicles composed either of dipalmitoyl phosphatidylcholine (DPPC) or of DPPC mixed with a small amount (0.5 mol%) of lyso phosphatidylcholine (Lyso PC). Transfer of the lipid probe in the presence of varying concentrations of poly(ethylene glycol) (PEG) was monitored using the SLM 48000-MHF Multi-Harmonic Fourier Transform phase and modulation spectrofluorometer to collect multifrequency phase and modulation fluorescence data sets on a subsecond time scale. The unique ability of this instrument to yield accurate fluorescence lifetime data on this time scale allowed transfer to be detected in terms of a time-dependent change in the fluorescent lifetime distribution associated with the lipid-like DPHpPC probe. This probe demonstrates two short fluoresence decay times (ca. 1.1–1.4 and 4.3–4.8 ns) in a probe-rich environment but a single long lifetime (ca. 7 ns) in a probe-poor environment. A simple two-state model for initial lipid transfer was used to analyze the multifrequency data sets collected over a 4-s time frame to obtain the time rate of change of the concentrations of donor and acceptor probe populations following rapid mixing of vesicles with PEG. The ability to measure fluorescence lifetimes on this time scale has allowed us to show that the of rate of lipid transfer increased dramatically at 35% PEG in both fusing and nonfusing vesicle systems. These results are interpreted in terms of a distinct interbilayer structure associated with intimate bilayer contact induced by high and potentially fusogenic concentrations of PEG. 相似文献
62.
63.
Robert J. Willis Stephen B. Huxford 《The Journal of the Operational Research Society》1991,42(9):727-731
A complex manual rostering system for directory assistance, telephone operators has been rationalized and the technique of integer programming used to automatically generate staff rosters. These rosters can be generated by relatively unskilled clerical staff. They result in operator costs comparable to manually generated rosters and can be produced in a fraction of the time taken to produce their manual counterparts. Implementation is reported. 相似文献
64.
Stephen Z. D. Cheng 《Journal of Thermal Analysis and Calorimetry》1997,50(5-6):907-910
65.
12 , 169 (1987). Reasonably good agreements in the peak output power and laser efficiency have been achieved. Model calculations
also predict that an efficiency as high as 2.7% can be obtained once the conditions of the above-mentioned experiments have
been optimized. From the consideration that the skin depth effectively limits the absorption length of the microwave pumping
and hence the excitable volume, it is concluded that high input power densities (>2 MW/cm3) and higher gas pressures (between 3 and 10 atm) are the preferable conditions to achieve higher efficiency. Preliminary
calculations on CCl4 containing XeCl gas mixtures show that improvement in laser efficiency by several folds may be achieved as a result of the
higher intrinsic efficiency of excimer formation.
Received: 23 September 1996 / Revised version: 25 March 1997 相似文献
66.
Herve Loïc 《Integral Equations and Operator Theory》1998,32(2):199-215
LetX be a locally compact space, andT, a quasi-compact positive operator onC
0(X), with positive spectral radius,r. Then the peripheral spectrum ofT is a finite set of poles containingr, and the residue of the resolvent ofT at each peripheral pole is of finite rank. Using the concept of closed absorbing set, we develop an iterative process that gives the order,p, ofr, some special bases of the algebraic eigenspaces ker(T-r)
p
and ker(T
*-r)
p
, and finally the dimension of the algebraic eigenspace associated to each peripheral pole. 相似文献
67.
Suzanne J. Dilly Steven J. Carlisle Andrew J. Clark Andrew R. Shepherd Stephen C. Smith Paul C. Taylor Andrew Marsh 《Journal of polymer science. Part A, Polymer chemistry》2006,44(7):2248-2259
A practical and divergent synthesis of supported [1,3,5]‐triazine dendritic molecules on Wang resin, PEGA resin, SynPhase? Lanterns, and silica gel is described. The alkylamine linkers used allow derivatization with functionality for both synthetic (e.g., supported reagent and scavenger activity) and chemical biology applications. The use of supported intermediates allows differentiation of symmetric linkers without the need for protecting group chemistry. The synthetic route uses inexpensive, readily available starting materials in a straightforward and scaleable strategy. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2248–2259, 2006 相似文献
68.
A. Badalà R. Barbera G. Lo Re A. Palmeri G. S. Pappalardo A. Pulvirenti F. Riggi 《Acta Physica Hungarica A》2006,25(2-4):337-346
Results are shown from a Monte Carlo simulation study of the capabilities of the Inner Tracking System of the ALICE experiment, used in standalone mode, for HBT analysis of Pb?Pb collisions at LHC energies (5.5 ATeV). Different values of the coherence factor and the Gaussian source radius have been studied. For this purpose, a specific ITS stand-alone tracking algorithm, based on the Denby-Peterson neural algorithm, has been developed. 相似文献
69.
70.