Evaluation of the sulfate dynamics in groundwater by means of environmental isotopes

Elevated sulfate concentrations and their heterogeneous distribution in the drinking water catchment area Torgau-Mockritz (Germany) were investigated by means of multiple isotope signatures such as 834S, delta18O-H2O, deltaD, tritium, and 85K5r. delta34S values of the groundwater sulfate vary between -19...+ 37 per thousand CDT. No simple correlation exists between sulfate concentrations and delta34S. Superimposition of different sulfur sources and mobilization processes combined with a complicated groundwater movement create a complex distribution pattern. The oxidation of reduced sedimentary sulfur has to be regarded as a main source of dissolved sulfate at least regionally. Tritium and 14C data revealed that old groundwater can be excluded as source for high sulfate contents. Correlated temporal variations in the concentrations of tritium and sulfate are observed in deeper sampling positions. Highly variable delta18O and 8D, as detected in parts of the catchment area, indicate local influences of surface water infiltration into the aquifer. The spatial distribution of isotope signatures enables the identification of zones with descending younger water or hindered groundwater movement and hence provides useful hints for flow modeling.     

Construction of Symmetric and Symplectic Bilinear Forms

Let V be a finite-dimensional vector-space. A linear mapping on V is called simple if V( - 1) is 1-dimensional. Let S be a set of simple bijections on V. We discuss conditions entraining that each element of S is orthogonal (respectively symplectic) under an appropriate symmetric (respectively symplectic) bilinear form on V.     

Investigation of the solid phase synthesis of tyrosine‐derived diphenol monomers with resin‐bound carbodiimide coupling reagents

Tyrosine‐derived pseudo‐polypeptides have recently been established as potential biomaterials. The bulk production of these polymers is dependant upon the convenient synthesis of tyrosine‐derived diphenolic monomers. Suitable solution phase methods for the synthesis of such monomers, with transient activated esters, have been reported previously by Kohn, J.; Langer, R. In Biomaterials Science: An Introduction to Materials in Medicine; Ratner, B. D.; Hoffman, A. S.; Schoen, F. J.; Lemons, J. E., Eds.; Academic Press: New York, 1996; pp 64–72. However, for all the methods reported by them, purification and isolation of the diphenol monomer involves rigorous extraction, column purification, or an extensive aqueous workup. These may lead to the incorporation of solvent‐based as well as inorganic impurities and also may lead to difficulties in the process scale‐up. In this article, an alternate and relatively more convenient method for the synthesis of tyrosine‐based diphenol monomers is reported. This involved the investigation of polymer resin‐bound carbodiimide in the solid‐phase synthesis of L‐tyrosine‐based diphenolic monomers. This method was found to eliminate the need for rigorous purification processes and was found to maintain reasonable yield as well as maintain purity of the final monomer product. The monomer was able to produce polymers of a reasonably high‐molecular‐weight and a narrow polydispersity. The amide bond formation by such a polymer‐tethered reagent can be described to follow a reverse‐Merrifield sense and the method is relatively convenient to scale up. The L‐tyrosine‐based diphenolic monomeric compound formed by this method was analyzed by NMR, Fourier transform infrared, and elemental microanalysis techniques for chemical structure and composition. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4906–4915, 2004     

Electroexcitation of 208Pb,distribution of electric dipole and quadrupole strength and fragmentation of the isoscalar quadrupole giant resonance

Low momentum transfer, high-resolution inelastic electron scattering on ²⁰⁸Pb has been used to study the distribution of E1 and E2 strength in the region of excitation energy E_x = 8?12MeV. The E1 and E2 strength is very fragmented and the EWSR strength amounts to (10⁺⁷_?6)% and (29⁺¹¹_?8)% in the investigated energy region, respectively. The E2 strength found is less than most current theoretical predictions but agrees qualitatively with a 1p - 1h +2p - 2h model calculation presented in this paper. The E2 strength is also smaller than what is known from hadron scattering and the shape of the strength distribution is also markedly different in electron and hadron scattering.     

Search for M1 strength in 51V and the difference in 51V(e,e′) and 51V(p,p′) spectra

Following the studies of the distribution of M1 strength in the even-even N = 28 isotones ⁴⁸Ca, ⁵⁰Ti, ⁵²Cr and ⁵⁴Fe by inelastic electron scattering, the result of a search for M1 transitions in the odd-even N = 28 nucleus ⁵¹V is reported. No strong M1 excitation has been detected, in contrast to a recent (p, p') experiment. There is no immediate explanation for this discrepancy. Shell-model calculations indicate that a part of it might be accounted for by an interference between the spin and orbital term of the electromagnetic transition operator in the (e, e') experiment.     

Importance of nucleon knock-out in inelasticα and6Li scattering

At 26 MeV/A, inelastic scattering of⁶Li ions from²⁸Si proceeds predominantly via direct one-nucleon removal, while inelasticα scattering leads, in addition, to excitation of the target nucleus.     

The particle-hole spectra of 16O and 16N as observed in pick-up reactions from 17O

The reactions ¹⁷O(d, t) ¹⁶O and ¹⁷O(d, τ)¹⁶N have been investigated at E_d = 52 MeV. Energy spectra of tritons and τ-particles have been measured simultaneously up to excitation energies of 22 MeV in ¹⁶O and 10 MeV in ¹⁶N, respectively. Spectroscopic factors have been obtained by a DWBA analysis of the measured angular distributions. From the comparison of the t- and τ-spectra analog (T = 1) states in ¹⁶O could be identified and the distribution of T = 0 and T = 1 spectroscopic strengths could be deduced. Nearly the total $\text{1}\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and $\text{1}\text{p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ hole strengths have been found and the $\text{1}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{1}\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}\text{and}\text{1}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{1}\text{p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}$ particle-hole multiplets could be located both for T = 0 and T = 1. The average residual interactions in both shell-model configurations turned out to be strikingly different.     

The 1 ħω spectra of mass 15, 16 and 17 nuclei

Tamm-Dancoff calculations including the complete 1p and 2s-1d shells are presented for non-normal parity states of nuclei with mass 15, 16 and 17. The basis is confined to ?ω excitations. Spurious states have been eliminated. The particle-particle and hole-hole interactions were taken from previous work. The particle-hole interaction was represented by 80 matrix elements from Kuo, eight of which were varied to fit 30 selected levels with a rms deviation of 310 keV. Spectroscopic factors and electromagnetic transition rates generally agree quite well with the experimental data. It is shown that the inclusion of the 1p_{$\text{3}\text{2}$} and 1d_{$\text{3}\text{2}$}. shells is essential even at low excitation energies in these nuclei.     

The D<Superscript>1</Superscript>Π state of the NaRb molecule

We present a detailed experimental study of the D¹Π state of the NaRb molecule by means of Fourier transform spectroscopy of laser induced fluorescence. The entire data field for the D¹Π state of Na⁸⁵Rb and Na⁸⁷Rb consists of rovibrational levels with v^′=0-39 and J^′=1-200. The data were incorporated into a direct fit of a single potential energy curve to the level energies using the Inverted Perturbation Approach method. The D¹Π state q factors, which describe the Λ-doubling, have been obtained in a wide range of rotational and vibrational quantum numbers. Analysis revealed several perturbation regions in the D¹Π state. Electronic supplementary material Online Material