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131.
132.
D. Stephan 《Crystal Research and Technology》1978,13(2):155-163
The asymmetrical Bragg case of X-ray diffraction on a thick real crystal is theoretically investigated on a layer model containing dynamically diffracting mosaic blocks. By means of this theory the experimental dependence of the integrated reflectivity Ri on the asymmetry angle α deviation from the kinematical formula may be understood as a result of extinction- and absorption processes inside the mosaic crystal. Thus the remarkably thick surface layers or surface protuberances assumed by Mathieson and in previous papers for the interpretation of the experimental Ri(α) become needless or they are considerably thinner. respectively, indeed. – On the base of the represented theory the determination of special (model-dependent) characteristics of the dislocation network is possible via absolute Ri(α)-measuring values. 相似文献
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134.
Stephan Christgau Jette Odderhede Kenny Stahl Jens E. T. Andersen 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(6):m259-m262
[Sr(C5H7NO4)]·6H2O, (I), and [Sr(C5H8NO4)2]·5H2O, (II), both crystallize with similar strontium–glutamate–water layers. In (I), the neutral layers are connected through hydrogen bonds by water molecules, while in (II), the positively charged layers are connected through hydrogen bonds and electrostatic interactions by interleaving layers of hydrogen glutamate anions and water molecules. 相似文献
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Olaf Kühl Stephan Millinghaus Gottfried J. Palm 《Central European Journal of Chemistry》2011,9(4):706-711
Starting from the paddlewheel complex copper(II)acetate, the green N-methylimidazole adduct of copper(II)acetate is formed
and transformed into the monomeric and dimeric N-methylimidazole adducts of copper(II)acetate [Cu(C4H6N2)2(CH3COO)2]n·xH2O (n = 1,2; x = 0, 6). The formation of the blue dimer or the purple monomer depends on the solvent and the presence or absence
of water. 相似文献
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140.
The photo-excitation and Auger decay processes of inner-shell double vacancy states 1s2s2p^6(1,3^S)3s3p of neutral neon atoms have been studied theoretically. Multi-configuration Dirac-Fock (MCDF) calculations have been carried out, with electron correlation effects taken into consideration. The relaxation of core and excited orbitals and configuration interaction are found to be crucial to creating the double vacancy states by single photo-absorption. The predominant decay paths for the double vacancy states turn out to be of the LLM Auger decay to 1s 2s^22p^53s(3p), KLL Auger decay to 1s^22s2p^43s3p, and KLM Auger decay to 1s^22p^63s(3p). They lead to further Auger decay, creating the neon ions of multiple charge states. For both double and single vacancy states the spectator type of Auger process is dominated in all the Auger decay processes. Theoretical Anger electron spectra are presented for further investigations, experimental and theoretical. 相似文献