首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4979篇
  免费   245篇
  国内免费   18篇
化学   3077篇
晶体学   22篇
力学   153篇
数学   933篇
物理学   1057篇
  2023年   62篇
  2022年   39篇
  2021年   84篇
  2020年   106篇
  2019年   112篇
  2018年   78篇
  2017年   78篇
  2016年   211篇
  2015年   172篇
  2014年   204篇
  2013年   291篇
  2012年   285篇
  2011年   301篇
  2010年   184篇
  2009年   165篇
  2008年   247篇
  2007年   214篇
  2006年   198篇
  2005年   159篇
  2004年   143篇
  2003年   122篇
  2002年   117篇
  2001年   86篇
  2000年   73篇
  1999年   65篇
  1998年   60篇
  1997年   58篇
  1996年   83篇
  1995年   80篇
  1994年   58篇
  1993年   53篇
  1992年   40篇
  1991年   44篇
  1990年   41篇
  1989年   32篇
  1988年   29篇
  1987年   34篇
  1986年   34篇
  1985年   49篇
  1984年   26篇
  1983年   27篇
  1982年   30篇
  1981年   29篇
  1980年   30篇
  1979年   29篇
  1978年   31篇
  1977年   34篇
  1976年   26篇
  1975年   23篇
  1973年   26篇
排序方式: 共有5242条查询结果,搜索用时 15 毫秒
91.
We demonstrate time-resolved counting of single atoms extracted from a weakly interacting Bose-Einstein condensate of 87Rb atoms. The atoms are detected with a high-finesse optical cavity and single atom transits are identified. An atom laser beam is formed by continuously output coupling atoms from the Bose-Einstein condensate. We investigate the full counting statistics of this beam and measure its second order correlation function g((2))(tau) in a Hanbury Brown-Twiss type experiment. For the monoenergetic atom laser we observe a constant correlation function g((2))(tau)=1.00 +/- 0.01 and an atom number distribution close to a Poissonian statistics. A pseudothermal atomic beam shows a bunching behavior and a Bose distributed counting statistics.  相似文献   
92.
The strain state of Fe films grown on Si(1 1 1) has been investigated by X-ray diffraction (XRD) in the thickness range between 11 and 304 monolayers. Fe grows tetragonally distorted with the orientation relationship Fe(1 1 1) // Si(1 1 1) . At low coverage, the films grow pseudomorphic. Above 15 monolayers the films are characterized by the coexistence of a pseudomorphic phase with another one which relaxes with the Fe thickness. This relaxation proceeds rapidly in the earlier stages then slowly with the film thickness. The XRD characterization allows one to obtain quantitative information on the in-plane and out-of-plane strains.  相似文献   
93.
We study the momentum distribution and relaxation dynamics of semiconductor microcavity polaritons by angle-resolved and time-resolved spectroscopy. Above a critical pump level, the thermalization time of polaritons at positive detunings becomes shorter than their lifetime, and the polaritons form a quantum degenerate Bose-Einstein distribution in thermal equilibrium with the lattice.  相似文献   
94.
Structural parameters of peptides and proteins in biomembranes can be directly measured by solid state NMR of selectively labeled amino acids. The 19F nucleus is a promising label to overcome the low sensitivity of 2H, 13C or 15N, and to serve as a background-free reporter group in biological compounds. To make the advantages of solid state 19F NMR fully available for structural studies of polypeptides, we have systematically measured the chemical shift anisotropies and relaxation properties of the most relevant aromatic and aliphatic 19F-labeled amino acids. In this first part of two consecutive contributions, six different 19F-substituents on representative aromatic side chains were characterized as polycrystalline powders by static and MAS experiments. The data are also compared with results on the same amino acids incorporated in synthetic peptides. The spectra show a wide variety of lineshapes, from which the principal values of the CSA tensors were extracted. In addition, temperature-dependent T(1) and T(2) relaxation times were determined by 19F NMR in the solid state, and isotropic chemical shifts and scalar couplings were obtained in solution.  相似文献   
95.
We used the high-precision laser interferometer technique of power recycling to characterize the optical loss of an all-reflective grating beam splitter. This beam splitter was used to set up a Michelson interferometer with a power-recycling resonator with a finesse of 883. Analyzing the results obtained, we determined the beam splitter's total optical loss to be (0.193+/-0.019)%. Low loss all-reflective beam splitters might find application in future high-power laser interferometers for the detection of gravitational waves.  相似文献   
96.
We investigate the excitation of surface plasmon polaritons on silver tubes with finite-difference time-domain simulations. These surface plasmon polaritons exhibit azimuthal whispering gallery modes with quality factors in the hundreds. We show that the high quality factors arise from the coupling of the surface plasmon modes to photonic modes inside the tube. We examine the influence of a gain material on the quality factors and find that for material data of rhodamine 6G, the quality factors are enhanced significantly up to values of 3000.  相似文献   
97.
The successful measurement of anisotropic NMR parameters like residual dipolar couplings (RDCs), residual quadrupolar couplings (RQCs), or residual chemical shift anisotropy (RCSA) involves the partial alignment of solute molecules in an alignment medium. To avoid any influence of the change of environment from the isotropic to the anisotropic sample, the measurement of both datasets with a single sample is highly desirable. Here, we introduce the scaling of alignment for mechanically stretched polymer gels by varying the angle of the director of alignment relative to the static magnetic field, which we call variable angle NMR spectroscopy (VA-NMR). The technique is closely related to variable angle sample spinning NMR spectroscopy (VASS-NMR) of liquid crystalline samples, but due to the mechanical fixation of the director of alignment no sample spinning is necessary. Also, in contrast to VASS-NMR, VA-NMR works for the full range of sample inclinations between 0° and 90°. Isotropic spectra are obtained at the magic angle. As a demonstration of the approach we measure 13C-RCSA values for strychnine in a stretched PDMS/CDCl? gel and show their usefulness for assignment purposes. In this context special care has been taken with respect to the exact calibration of chemical shift data, for which three approaches have been derived and tested.  相似文献   
98.
Graphene nanostructures are promising candidates for future nanoelectronics and solid-state quantum information technology. In this review we provide an overview of a number of electron transport experiments on etched graphene nanostructures. We briefly revisit the electronic properties and the transport characteristics of bulk, i.e., two-dimensional graphene. The fabrication techniques for making graphene nanostructures such as nanoribbons, single electron transistors and quantum dots, mainly based on a dry etching ??paper-cutting?? technique are discussed in detail. The limitations of the current fabrication technology are discussed when we outline the quantum transport properties of the nanostructured devices. In particular we focus here on transport through graphene nanoribbons and constrictions, single electron transistors as well as on graphene quantum dots including double quantum dots. These quasi-one-dimensional (nanoribbons) and quasi-zero-dimensional (quantum dots) graphene nanostructures show a clear route of how to overcome the gapless nature of graphene allowing the confinement of individual carriers and their control by lateral graphene gates and charge detectors. In particular, we emphasize that graphene quantum dots and double quantum dots are very promising systems for spin-based solid state quantum computation, since they are believed to have exceptionally long spin coherence times due to weak spin-orbit coupling and weak hyperfine interaction in graphene.  相似文献   
99.
Using an ultrastable continuous-wave laser at 580 nm we performed spectral hole burning of Eu(3+):Y(2)SiO(5) at a very high spectral resolution. The essential parameters determining the usefulness as a macroscopic frequency reference, linewidth, temperature sensitivity, and long-term stability, were characterized using a H-maser stabilized frequency comb. Spectral holes with a linewidth as low as 6 kHz were observed and the upper limit of the drift of the hole frequency was determined to be 5±3 mHz/s. We discuss the necessary requirements for achieving ultrahigh stability in laser frequency stabilization to these spectral holes.  相似文献   
100.
We investigated the incorporation efficiencies of different fluorescently labelled dNTPs with polymerases by complementary strand synthesis. For this reason single stranded DNA was immobilized on a coverslip and the increase of fluorescence due to the synthesis of the corresponding strand with tagged dNTPs was detected with a supercritical angle fluorescence biosensor in real-time. By comparison of the observed signal intensities it was possible to conclude that the system Cy5-dCTP-Klenow (exonuclease free) fragment gives the best incorporation yield of the investigated enzymes and dNTPs.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号