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991.
Arsenic doped p-type ZnO thin films were grown on sapphire substrate by magnetron sputtering. As grown films reveal p-type conduction confirmed by Hall-effect and photoluminescence measurements. The p-type film with a hole concentration of 2.16× 1017 cm−3, mobility of 1.30 cm2/V.s and resistivity of 22.29 Ω-m were obtained at substrate temperature of 700 °C. ZnO homojunction synthesized by in-situ deposition of As doped p-ZnO layer on Al doped n-ZnO layer showed p-n diode like characteristics. X-ray pole figure and Transmission Electron Microscope studies confirm epitaxial nature of the films. Photoluminescence results exhibit the peaks associated with donor acceptor pair emission. 相似文献
992.
Dr. Stephan G. Koller Dr. Jonathan O. Bauer Prof. Dr. Carsten Strohmann 《Angewandte Chemie (International ed. in English)》2017,56(27):7991-7994
Selective cleavage of a silicon–carbon bond in tetraorganosilanes is still a great challenge. A new type of Si−C(sp3) bond cleavage in bench-stable (aminomethyl)silanes with common organolithium reagents as nucleophiles has now been identified. Suitable leaving groups are benzyl, allyl, and phenylthiomethyl groups. A β-donor function and polar solvents are essential for the reaction. Simple switching between α-deprotonation and substitution is possible through slight modifications of the reaction conditions. The stereochemical course of the reaction was elucidated by using a silicon-chiral benzylsilane. The new transformation proceeds stereospecifically with inversion of configuration and can be used for the targeted synthesis of enantiomerically pure tetraorganosilanes, which are otherwise difficult to access. Quantum chemical calculations provided insight into the mechanism of the new substitution. 相似文献
993.
994.
Active fiber composites are electromechanical actuators based on piezo-ceramic fibers, which are embedded in a polymer matrix. The fibers are electrically contacted through so-called interdigitated electrodes (IDEs). State-of-the-art metallic IDEs only contact the fibers at two small sections of their circumference at the top and bottom of the composite ply, respectively. This paper presents an original technique to manufacture IDEs made of a conducting polymer (polypyrrole/p-toluene sulfonic acid), where the polymer electrodes contact the fibers around their whole circumference. The necessary process steps are discussed, namely design of the master electrodes and electrochemical polymer growth with and without fibers. Processing issues are discussed and solutions are suggested. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
995.
M. Capone M. Grilli W. Stephan 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,11(4):551-557
We investigate polaron formation in a many-electron system in the presence of a local repulsion sufficiently strong to prevent
local-bipolaron formation. Specifically, we consider a Hubbard-Holstein model of interacting electrons coupled to dispersionless
phonons of frequency . Numerically solving the model in a small one-dimensional cluster, we find that in the nearly adiabatic case , the necessary and sufficient condition for the polaronic regime to occur is that the energy gain in the atomic (i.e., extremely localized) regime overcomes the energy of the purely electronic system . In the antiadiabatic case, , polaron formation is instead driven by the condition of a large ionic displacement (g being the electron-phonon coupling). Dynamical properties of the model in the weak and moderately strong coupling regimes
are also analyzed.
Received 15 February 1999 相似文献
996.
Daniela Bertinetti Sonja Schweinsberg Susanne E Hanke Frank Schwede Oliver Bertinetti Stephan Drewianka Hans-Gottfried Genieser Friedrich W Herberg 《BMC chemical biology》2009,9(1):3-15
Background
In the eukaryotic cell the cAMP-dependent protein kinase (PKA) is a key enzyme in signal transduction and represents the main target of the second messenger cAMP. Here we describe the design, synthesis and characterisation of specifically tailored cAMP analogs which can be utilised as a tool for affinity enrichment and purification as well as for proteomics based analyses of cAMP binding proteins. 相似文献997.
Ohne Zusammenfassung 相似文献
998.
999.
Ohne ZusammenfassungHerrn Prof. Dr. Hans Meyer, dem ich auch die Anregung zu dieser kleinen Untersuchung danke, bin ich für sein freundliches Entgegenkommen verpflichtet. 相似文献
1000.