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排序方式: 共有75条查询结果,搜索用时 31 毫秒
41.
Subbotin A Stepanyan R Knaapila M Ikkala O ten Brinke G 《The European physical journal. E, Soft matter》2003,12(2):333-345
Phase behavior and microstructure formation of rod and coil molecules, which can associate to form hairy-rod polymeric supramolecules, are addressed theoretically. Association induces considerable compatibility enhancement between the rod and coil molecules and various microscopically ordered structures can appear in the compatibility region. The equilibria between microphase-separated states, the coil-rich isotropic liquid and the rod-rich nematic are discussed in detail. In the regime where hairy-rod supramolecules with a high grafting density appear as a result of the association, three phase diagram types are possible depending on the value of the association energy. In the low grafting density regime only the lamellar microstructure is proven to be stable.Received: 10 June 2003, Published online: 21 November 2003PACS:
36.20.-r Macromolecules and polymer molecules - 64.60.Cn Order-disorder transformations; statistical mechanics of model systems 相似文献
42.
Rohe D Armstrong CS Asaturyan R Baker OK Bueltmann S Carasco C Day D Ent R Fenker HC Garrow K Gasparian A Gueye P Hauger M Honegger A Jourdan J Keppel CE Kubon G Lindgren R Lung A Mack DJ Mitchell JH Mkrtchyan H Mocelj D Normand K Petitjean T Rondon O Segbefia E Sick I Stepanyan S Tang L Tiefenbacher F Vulcan WF Warren G Wood SA Yuan L Zeier M Zhu H Zihlmann B;E- Collaboration 《Physical review letters》2004,93(18):182501
We have carried out an (e,e'p) experiment at high momentum transfer and in parallel kinematics to measure the strength of the nuclear spectral function S(k,E) at high nucleon momenta k and large removal energies E. This strength is related to the presence of short-range and tensor correlations, and was known hitherto only indirectly and with considerable uncertainty from the lack of strength in the independent-particle region. This experiment locates by direct measurement the correlated strength predicted by theory. 相似文献
43.
Wesselmann FR Slifer K Tajima S Aghalaryan A Ahmidouch A Asaturyan R Bloch F Boeglin W Bosted P Carasco C Carlini R Cha J Chen JP Christy ME Cole L Coman L Crabb D Danagoulian S Day D Dunne J Elaasar M Ent R Fenker H Frlez E Gan L Gaskell D Gomez J Hu B Jones MK Jourdan J Keith C Keppel CE Khandaker M Klein A Kramer L Liang Y Lichtenstadt J Lindgren R Mack D McKee P McNulty D Meekins D Mkrtchyan H Nasseripour R Niculescu I Normand K Norum B Pocanic D Prok Y Raue B Reinhold J Roche J Rohe D 《Physical review letters》2007,98(13):132003
We have examined the spin structure of the proton in the region of the nucleon resonances (1.085 GeV相似文献
44.
45.
V. V. Shchepin Yu. G. Stepanyan P. S. Silaichev M. A. Ezhikova M. I. Kodess 《Russian Journal of Organic Chemistry》2010,46(4):499-502
Bromine-containing organozinc compounds generated from 1,1-dibromo-3,3-dimethylbutan-2-one reacted with 2-arylmethylideneindan-1,3-diones
and 5-arylmethylidene-2,2-dimethyl-1,3-dioxane-4,6-diones to give 3-aryl-2-(2,2-dimethylpropanoyl)spiro[cyclopropane-1,2′-indan]-1′,3′-diones
and 1-aryl-6,6-dimethyl-2-(2,2-dimethylpropanoyl)-5,7-dioxaspiro[2.5]octan-4,8-diones, respectively. Reactions of 2-arylmethylideneindan-1,3-diones
with bromine-containing zinc enolates derived from 1-aryl-2,2-dibromopropan-1-ones and 2,2-dibromo-1,2,3,4-tetrahydronaphthalen-1-one
resulted in the formation of 2-aroyl-3-aryl-2-methylspiro-[cyclopropane-1,2′-indan]-1′,3′-diones and 2,3: 8,9-dibenzo-12-phenyldispiro[4.0.5.1]dodecane-1,4,7-trione,
respectively. 相似文献
46.
Avagyan A. S. Vardanyan S. O. Sargsyan A. B. Aghekyan A. A. Panosyan H. A. Paronikyan R. V. Stepanyan H. M. Muradyan R. E. 《Russian Journal of Organic Chemistry》2020,56(3):385-389
Russian Journal of Organic Chemistry - Reactions of 5-(1,4-benzodioxan-2-yl)-1,3,4-oxadiazole-2-thiol with N-substituted chloroacetamides gave a series of the corresponding derivatives at the... 相似文献
47.
V. N. Ovchiyan Ts. R. Stepanyan A. H. Martirosyan V. R. Harutyunyan 《Journal of Contemporary Physics (Armenian Academy of Sciences)》2011,46(1):37-39
For improving water-resistivity, adhesion, and physical-mechanical properties of silicate coatings, we have developed a technique of modification of silicate film-forming materials with organic polymer-forming monomers (e.g., aldehydes and amines), oligomers, and other additives. The inner structure of the modified silicate converter was studied by X-ray diffraction method. It is shown that addition of polymer-forming monomers leads to increase in the fraction of crystalline phase with respect to amorphous. The described modification technique seems to be more perspective, since it allows producing coatings with good anticorrosive, physical-mechanical, and other valuable properties. 相似文献
48.
W. Luh A. Stepanyan 《Journal of Contemporary Mathematical Analysis (Armenian Academy of Sciences)》2011,46(4):227-235
We deal with overconvergence phenomena of power series with radius of convergence zero. Among others it is shown that the
partial sums of such a series can be elongated to become Cesàro summable on a set S ⊂ {z: |z| > 0} if and only if the considered power series is overconvergent. 相似文献
49.
Ashot S. Saghiyan Lala A. Stepanyan Luiza L. Manasyan Arpine V. Geolchanyan Silva M. Djamgaryan Hrant R. Ajvazyan Henry A. Panosyan Viktor I. Maleev Tatiana F. Saveleva 《Tetrahedron: Asymmetry》2010,21(21-22):2638-2645
New chiral NiII complexes of Schiff bases of dehydroalanine with modified chiral auxiliaries (S)-2-N-[N′-(3,4-dichlorobenzyl)prolyl]aminobenzophenone (3,4-DCBPB), (S)-2-N-[N′-(3,4-dimethylbenzyl)prolyl]aminobenzophenone (3,4-DMBPB), (S)-2-N-[N′-(2-chlorobenzyl)prolyl]aminobenzophenone (2-CBPB), and (S)-2-N-[N′-(2-fluorobenzyl)prolyl]-aminobenzophenone (2-FBPB) have been synthesized. Asymmetric Michael addition reactions of primary and secondary amines and thiols to the dehydroalanine moieties of the complexes were studied. (S)-2-FBPB was found to be the best chiral auxiliary in terms of both selectivity of the reactions (de ~92–96%) and reactivity of the complexes. A novel synthetic route toward (S)-2-carboxypiperazine was developed based on the auxiliary. 相似文献