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EPR, UV/Vis and FTIR spectroscopy as well as thermal analysis (TA/MS) were applied to study the influence of sulfate species present in the anatase support on the specific nature of VOx species in supported VOx/TiO2 catalysts. Those sulfate species modify the local structure of the supported vanadyl species and lead to the formation of two types of VO2+ sites instead of only one type being formed on sulfate‐free anatase. EPR and FTIR spectroscopic measurements revealed that a part of the VO2+ species are directly bound to the surface sulfate species. By TA/MS it was found that SO2 is released at lower temperature from VOx/TiO2 in comparison to the vanadium‐free support. The direct bonding between sulfate and VOx species stabilizes the latter on the surface of VOx/TiO2 resulting in three effects: 1) a higher V site dispersion in comparison to sulfate‐free TiO2, 2) a better resistance of surface vanadyls against diffusion into the bulk of the support and 3) a much faster reoxidation of reduced V sites than observed on sulfate‐free TiO2. 相似文献
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Sylvia Jeney Ernst H K Stelzer Helmut Grubmüller Ernst-Ludwig Florin 《Chemphyschem》2004,5(8):1150-1158
A new method combining three-dimensional (3D) force measurements in an optical trap with the analysis of thermally induced (Brownian) position fluctuations of a trapped probe was used to investigate the mechanical properties of a single molecule, the molecular motor kinesin. One kinesin molecule attached to the probe was bound in a rigorlike state to one microtubule. The optical trap was kept weak to measure the thermal forces acting on the probe, which were mainly counterbalanced by the kinesin tether. The stiffness of kinesin during stretching and compression with respect to its backbone axis were measured. Our results indicate that a section of kinesin close to the motor domain is the dominating element in the flexibility of the motor structure. The experiments demonstrate the power of 3D thermal fluctuation analysis to characterize mechanical properties of individual motor proteins and indicate its usefulness to study single molecule in general 相似文献
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Boamfa MI Viertler K Wewerka A Stelzer F Christianen PC Maan JC 《Physical review letters》2003,90(2):025501
We show that cooling side chain polymer liquid crystals in a magnetic field, from the isotropic to nematic and subsequently to the glass phase, results in a macroscopically ordered, transparent, and strongly birefringent material. The aligned samples retain their properties after the field is removed and can be dealigned only by heating them to the isotropic phase. To induce alignment, a threshold field B(th) is necessary, which strongly depends on the chemical structure details. B(th) reflects the strength of mesogene-polymer backbone coupling, and we will show that this interaction is responsible for the stability of the induced alignment at zero field. 相似文献
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The multiple imaging axis microscope (MIAM) is a wide-field optical microscope that observes a sample simultaneously from multiple directions without requiring the sample to be rotated or tilted. The prototype is capable of high-resolution imaging of the interior of a 300-microm-diameter sample consisting of fluorescent microbeads suspended in an agarose gel. Compared with a single-axis system, the MIAM can achieve a reduction of the axial point-spread function elongation by a factor of 5.8 and a 3.5-fold improvement in volume resolution by simple linear image combination techniques. 相似文献
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Araujo MH Hitchcock PB Nixon JF Kuehner U Stelzer O 《Chemical communications (Cambridge, England)》2003,(9):1092-1093
Hydrozirconation of the eta 2-phosphaalkyne complex [Pt(dppe)(eta 2-tBuCP)] with [ZrHCl(eta 5-C5H5)2], followed by treatment with the chlorophosphaalkene ClP=C(SiMe3)2 affords the eta 2-2,3-diphosphabutadiene complex [Pt(dppe)(eta 2-tBuC(H)=PP=C(SiMe3)2]. In the presence of [Pt(PPh3)2] the latter undergoes an addition reaction with water to afford the structurally characterised Pt(II) complex [Pt(dppe)(tBuCH2P(O)HPC(SiMe3)2]. 相似文献
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F. W. N. de Boer H. J. Wollersheim H. Emling H. Grein E. Grosse W. Spreng G. Eckert Th. W. Elze K. Stelzer Ch. Lauterbach 《Zeitschrift für Physik A Hadrons and Nuclei》1986,325(4):457-466
In a systematic study of nucleon transfer reactions accompanied by Coulomb excitation we have bombarded152Sm,160Gd and232Th with206, 208pb beams at incident energies close to the Coulomb barrier. Particle-gamma coincidence techniques were used to identify excited states of reaction products populated through inelastic scattering and in nucleon transfer reactions. One-neutron stripping and pick-up reactions on152Sm were observed leading to known states of the rotation alignedi 13/2-bands in153Sm and151Sm. In the160Gd+206, 208Pb systems no significant population of low lying states of product nuclei was found in the nucleon-transfer channels. Large cross sections were observed for one- and two-neutron pick-up from232Th at an incident energy of 6.4 MeV/u. Around the grazing angle they are of the same order of magnitude as the cross section measured for inelastic scattering. The results are analyzed in the framework of semiclassical models. 相似文献
20.
A. Mauthofer K. Stelzer J. Idzko Th. W. Elze H. J. Wollersheim H. Emling P. Fuchs E. Grosse D. Schwalm 《Zeitschrift für Physik A Hadrons and Nuclei》1990,336(3):263-278
The nuclear level structure and electromagnetic properties of196Pt were investigated withγ-spectroscopic techniques using multiple Coulomb excitation by208Pb projectiles. Particle-γ, and particle-γ-γ coincidences were measured over a wide range of scattering angles.E2-transition moments and static quadrupole moments have been determined by a comparison of experimental scattering-angle dependentγ yields with calculated yields in a largely model-independent procedure. The results are compared with different theoretical models: the Asymmetric-Rotor Model, the Generalized Collective Model, and the Interacting Boson Model. The best agreement is obtained with the Generalized Collective Model representing a triaxial nucleus which is soft in theγ degree of freedom. 相似文献