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111.
Garino C Ghiani S Gobetto R Nervi C Salassa L Ancarani V Neyroz P Franklin L Alexander Ross JB Seibert E 《Inorganic chemistry》2005,44(11):3875-3879
The synthesis and physical-chemical characterization of the metal-ligand complex [Os(bpy)2(CO)(enIA)][OTf]2 (where enIA = ethylenediamine iodoacetamide) with a sulfhydryl-specific functional group is described. The UV and visible absorption and luminescence emission, including lifetime and steady-state anisotropy, are reported for the free probe and the probe covalently linked to two test proteins. The spectroscopic properties of the probe are unaffected by chemical modification and subsequent covalent linkage to the proteins. The luminescence lifetime in aqueous buffer is approximately 200 ns and the limiting anisotropy is greater than 0.125, suggesting a potentially useful probe for biophysical investigations. 相似文献
112.
In order to explore the influence of cation substitution on the vibrational dynamics of water molecules in zeolites, the evolution of structural properties of the O-H stretching band of water in fully hydrated Na-A and Mg-exchanged A zeolites has been studied, for different percentages of induced ion exchange, by Fourier transform infrared attenuated total reflection spectroscopy as a function of temperature. The differences revealed in the O-H stretching band shapes have been accounted by fitting the spectra as a sum of four components, corresponding to water molecules exhibiting different types of hydrogen bonding. The dependencies of the relative intensities, peak wave numbers, and bandwidths of the resolved components on temperature and Mg2+ content have been discussed. Evidence of the "structure-maker" role played by a zeolitic surface on physisorbed water, systematically enhanced by increasing the percentage of induced ion exchange, is given in the whole explored temperature range. 相似文献
113.
Isoelectric focusing (IEF) was used to distinguish 4 freshwater fish species that are sold in the European Union under the generic label of "perch": Perca fluviatilis (European perch), Lates niloticus (Nile perch), Stizostedion lucioperca (European pikeperch), and Morone chrysops x saxatilis (Sunshine bass). These species have different commercial values but are easily interchangeable because they are sold already filleted, in view of the numerous bones of the whole fish. IEF of the water-soluble proteins extracted from fish muscle resulted in species-specific patterns. None of the bands was common to all 4 species. Intraspecies polymorphism was low and did not concern the bands identified as characteristic of the species. 相似文献
114.
Rosaria D’Amato Mauro Falconieri Fabio Fabbri Valentina Bello Elisabetta Borsella 《Journal of nanoparticle research》2010,12(5):1845-1858
The preparation of sizeable quantities of luminescent Si nanoparticles (Si-np) with controlled morphology is a challenging
task. Here, we describe two strategies aiming at size reduction of the Si-np produced in a laser-assisted silane pyrolysis
reactor without detrimental effects on the process yield and on the nanoparticle structural and compositional properties.
The first method is based on the addition of a sensitizer gas to dilute silane and consequently reduce the nucleation centres
density without decreasing the reaction temperature. The second consists in the introduction of a collector at a variable
distance from the irradiated region to freeze the particle growth and decrease the inter-particle sintering probability. We
report on the characterization of the produced Si-np, and we show that by combining the two methods, we are able to prepare
4 nm crystalline core size nanoparticles with a productivity of 1 g per hour. We also describe the enhancement effect of the
wet-chemical oxidation processes on the luminescence emission intensity of the Si-np. 相似文献
115.
Valentina Rossi 《Applied Categorical Structures》2006,14(4):291-311
Given a regular Gumm category such that any regular epimorphism is effective for descent, we prove that any Birkhoff subcategory in gives rise to an admissible Galois structure. This result allows one to consider some new applications of the categorical Galois theory in the context of topological algebras. Given a regular Mal’cev category , we first characterize the coverings of the Galois structure induced by the subcategory of the abelian objects in . Then we consider as a subcategory of the category of the equivalence relations in , and we characterize the coverings of the corresponding Galois structure . By composing the Galois structures and we obtain the Galois structure induced by as a subcategory of . We give the characterization of the -coverings in terms of the coverings of and . 相似文献
116.
Xu J Dong RY Domenici V Fodor-Csorba K Veracini CA 《The journal of physical chemistry. B》2006,110(19):9434-9441
In this paper, the difficulty in orienting the B(2) phase of the banana mesogen 1,3-Phenylene-bis 4-[4-(10-undecenyloxy)-benzoyloxy] benzoate (Pbis11BB) in a relatively high magnetic field is reported based on some observations using both (13)C and (2)H NMR. (2)H NMR spectra recorded for the two labeled isotopomers of Pbis11BB in the isotropic and B(2) phases are shown here. Preliminary results on the deuteron spin-spin relaxation (T(2)) data are reported at 61 MHz in order to underline the peculiar slow dynamics of banana-shaped liquid crystals (BLC), and these results are discussed in the framework of recent studies on similar BLC. The molecular structure and dynamics in the B(2) and crystalline phases are also studied by (13)C solid-state NMR techniques. The results also point to the slow dynamics in the B(2) phase of Pbis11BB. In particular, two-dimensional MAS exchange experiment has been performed to shed light on the molecular conformation structure of the five-ring banana core in the crystalline phase of Pbis11BB, and to compare with that of quantum mechanical calculations reported in the literature. 相似文献
117.
Irradiation of electron-donating substituted phenyl halides (fluorides and chlorides) or esters (mesylates, triflates and phosphates) in aqueous MeCN in the presence of KCN gives the corresponding benzonitriles in 48 to 100% yield through an ArSN1 reaction with the intermediacy of a triplet phenyl cation. 相似文献
118.
In this paper, the structure of locally finite groups of infinite rank whose subgroups of infinite rank are permutable in a subgroup of finite index is investigated. 相似文献
119.
As a consequence of integral bounds for three classes of quaternionic spherical harmonics, we prove some bounds from below for the norm of quaternionic harmonic projectors, for . 相似文献
120.
The CIMPA Research School on Mathematical Models for Security Applications was dedicated to the memory of Emeritus Professor Mirka Miller, who suggested that it be held in Havana. Mirka Miller, member of the editorial board of Mathematics in Computer Science, devoted her research to Graph Theory and Data Security, fields where she made important and beautiful contributions. 相似文献