全文获取类型
收费全文 | 8133篇 |
免费 | 425篇 |
国内免费 | 37篇 |
专业分类
化学 | 5692篇 |
晶体学 | 20篇 |
力学 | 205篇 |
数学 | 1401篇 |
物理学 | 1277篇 |
出版年
2023年 | 76篇 |
2022年 | 95篇 |
2021年 | 137篇 |
2020年 | 189篇 |
2019年 | 190篇 |
2018年 | 115篇 |
2017年 | 115篇 |
2016年 | 357篇 |
2015年 | 317篇 |
2014年 | 296篇 |
2013年 | 473篇 |
2012年 | 558篇 |
2011年 | 655篇 |
2010年 | 381篇 |
2009年 | 324篇 |
2008年 | 519篇 |
2007年 | 465篇 |
2006年 | 444篇 |
2005年 | 411篇 |
2004年 | 347篇 |
2003年 | 322篇 |
2002年 | 290篇 |
2001年 | 170篇 |
2000年 | 123篇 |
1999年 | 122篇 |
1998年 | 93篇 |
1997年 | 102篇 |
1996年 | 105篇 |
1995年 | 90篇 |
1994年 | 63篇 |
1993年 | 65篇 |
1992年 | 54篇 |
1991年 | 36篇 |
1990年 | 37篇 |
1989年 | 30篇 |
1988年 | 34篇 |
1987年 | 27篇 |
1986年 | 32篇 |
1985年 | 25篇 |
1984年 | 23篇 |
1983年 | 15篇 |
1982年 | 24篇 |
1981年 | 18篇 |
1980年 | 21篇 |
1979年 | 13篇 |
1978年 | 24篇 |
1977年 | 14篇 |
1975年 | 12篇 |
1974年 | 14篇 |
1970年 | 9篇 |
排序方式: 共有8595条查询结果,搜索用时 218 毫秒
251.
Siwei Wang Jesse Ward Sven Leyffer Stefan M. Wild Chris Jacobsen Stefan Vogt 《Journal of synchrotron radiation》2014,21(3):568-579
A novel approach to locate, identify and refine positions and whole areas of cell structures based on elemental contents measured by X‐ray fluorescence microscopy is introduced. It is shown that, by initializing with only a handful of prototypical cell regions, this approach can obtain consistent identification of whole cells, even when cells are overlapping, without training by explicit annotation. It is robust both to different measurements on the same sample and to different initializations. This effort provides a versatile framework to identify targeted cellular structures from datasets too complex for manual analysis, like most X‐ray fluorescence microscopy data. Possible future extensions are also discussed. 相似文献
252.
253.
254.
255.
256.
Optimal utilization of computational resources mandates spatio-temporal variation in resolution for computing complex engineering flows. Closure modeling in regions bridging between different resolutions is rendered difficult due to changing interactions between resolved and unresolved fields. We develop a closure model for the bridging region based on energy conservation principles. Then we proceed to provide a proof of concept in decaying isotropic turbulence with temporally varying resolution. The simplicity of the flow permits a thorough examination of various aspects of the proposed closure not feasible in more complex flows. The results demonstrate the potential promise of the approach, but more validation studies need to be performed.While the present development is in the context of partially averaged Navier–Stokes (PANS) method, the closure principle should apply for other variable-resolution (VR) approaches. 相似文献
257.
258.
259.
260.
Yunjiao Che Stefan Zschoche Franziska Obst Dietmar Appelhans Brigitte Voit 《Journal of polymer science. Part A, Polymer chemistry》2019,57(24):2590-2601
We present novel redox‐responsive hydrogels based on poly(N‐isopropylacrylamide) or poly(acrylamide), consisting of a reversible disulfide crosslinking agent N,N′‐bis(acryloyl)cystamine and a permanent crosslinking agent N,N′‐methylenebisacrylamide for microfluidic applications. The mechanism of swelling/deswelling behavior starts with the cleavage and reformation of disulfide bonds, leading to a change of crosslinking density and crosslinking points. Raman and ultraviolet‐visible spectroscopy confirm that conversion efficiency of thiol–disulfide interchange up to 99%. Rheological analysis reveals that the E modulus of hydrogel is dependent on the crosslinking density and can be repeatedly manipulated between high‐ and low‐stiffness states over at least 5 cycles without significant decrease. Kinetic studies showed that the mechanical strength of the gels changes as the redox reaction proceeds. This process is much faster than the autonomous diffusion in the hydrogel. Moreover, cooperative diffusion coefficient (Dcoop) indicates that the swelling process of the hydrogel is affected by the reduction reaction. Finally, this reversibly switchable redox behavior of bulky hydrogel could be proven in microstructured hydrogel dots through short‐term photopatterning process. These hydrogel dots on glass substrates also showed the desired short response time on cyclic swelling and shrinking processes known from downsized hydrogel shapes. Such stimuli‐responsive hydrogels with redox‐sensitive crosslinkers open a new pathway in exchanging analytes for sensing and separating in microfluidics applications. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 2590–2601 相似文献