Diastereoselective chelation-controlled additions to β-silyloxy aldehydes

A general diastereoselective method for the addition of dialkylzincs and (E)-di- and (E)-trisubstituted vinylzinc reagents to β-silyloxy aldehydes is presented. This method employs alkyl zinc triflate and nonaflate Lewis acids and affords chelation-controlled products (6:1 to > 20:1 dr).     

Harmonic balance analysis of the bistable piezoelectric inertial generator

This paper applies the method of Harmonic Balance to analytically predict the existence, stability, and influence of parameter variations on the intrawell and interwell oscillations of bistable piezoelectric inertial generator. Existing work on the bistable piezoelectric harvester in the presence of varying harmonic environmental loading has been relegated to simulation and experimental analyses. Furthermore, linear piezoelectric behavior and linear damping has always been presumed. This paper improves upon an existing model for the bistable piezoelectric harvester by incorporating nonlinear dissipation and cubic softening influences in the electroelastic laminates before applying analytical methods. A framework for theoretically predicting empirical observations, such as optimal impedance loads for steady-state motions, is provided as well as other dynamic considerations such as potential well escape phenomena.     

Carbonyl coordination chemistry from a new angle: a computational study of alpha-carbon acidity based on electrophile coordination geometry

[reaction: see text] The dependence of acidity on Li+ coordination geometry to alpha-carbon acids is investigated by generating potential energy surfaces of Li+ complexation with acetaldehyde and its respective enolate. The global minimum for the enolate complex shows significant Li+-pi-system coordination to both oxygen and the alpha-carbon. The gas-phase acidity analysis reveals significantly more alpha-carbon coordination, which presumably enhances the lability of the cleaving proton in the transition state of deprotonation.     

Structure–property relationships of blended polysaccharide and protein biomaterials in ionic liquid

Cellulose and silk blended biomaterial films were regenerated from ionic liquid solution and investigated to characterize and understand the effect of inter- and intra-molecular interactions upon the morphology and thermal properties. The blended films were dissolved in 1-allyl-3-methylimidazolium chloride ionic liquid, coagulated and regenerated with water. Various characterization techniques were implemented to characterize structural, morphological and thermal properties: FTIR, SEM, TGA, DSC and X-ray scattering. The results showed that the cellulose microcrystalline structure and β-sheets from the silk can be disrupted by inter- and intra-molecular hydrogen bonds forming intermediate semicrystalline or amorphous structures. The SEM showed morphological effects of such interactions that cause varying thermal degradation and glass transition temperature. The X-ray scattering confirms such findings at the molecular level, demonstrating that the cellulose microfibril diameter decreases as the silk content increases. It also shows that the β-sheets size increases as the cellulose content increases. These various techniques provide evidence that suggest the hydrogen bonds between the β-sheets and the glucose units in the cellulose chains control the thermal and structural properties of the blended films, changing the morphology and physicochemical properties.     

Almost-affable abelian groups

In this paper we show that a direct summand of a simply presented mixed abelain group is an almost affable group. As a consequence, the classification theorem due to the author is extended to the largest possible class.     

The relationship between formal scattering theory and the density matrix

A study has been carried out on the relationship between formal scattering theory and the density matrix formalism. The density operator is developed in terms of the scattering operator S and the observable square modulus matrix elements of S are shown to be equivalent to elements of the density matrix. The Møller wave operators are similarly treated and subsequently used in obtaining the density matrix expression for the transition matrix. Finally, using the latter, it is shown that the hierarchy of approximations to the density matrix yields equivalent results to those obtained from the Born series.