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101.
The effect of ultrasonic vibrations on crystallization processes 总被引:1,自引:0,他引:1
Stanley L. Hem 《Ultrasonics》1967,5(4):202-207
Ultrasound has long been used during a phase transition to produce small, uniform crystals. Many theories have been suggested to explain the action of ultrasound in this application. This paper reviews the proposed mechanisms of ultrasonic crystallization. 相似文献
102.
To study transport properties of scale-free and Erdos-Rényi networks, we analyze the conductance G between two arbitrarily chosen nodes of random scale-free networks with degree distribution P(k)-k(-lambda) in which all links have unit resistance. We predict a broad range of values of G, with a power-law tail distribution phi(SF)(G)-G(-g(G)), where g(G)=2lambda-1, and confirm our predictions by simulations. The power-law tail in phi(SF)(G) leads to large values of G, signaling better transport in scale-free networks compared to Erdos-Rényi networks where the tail of the conductivity distribution decays exponentially. Based on a simple physical "transport backbone" picture we show that the conductances of scale-free and Erdos-Rényi networks are well approximated by ck(A)k(B)/(k(A)+k(B)) for any pair of nodes A and B with degrees k(A) and k(B), where c emerges as the main parameter characterizing network transport. 相似文献
103.
H. E. Stanley P. Kumar G. Franzese L. Xu Z. Yan M. G. Mazza S. V. Buldyrev S.-H. Chen F. Mallamace 《The European physical journal. Special topics》2008,161(1):1-17
We present evidence from experiments and computer
simulations supporting the hypothesis that water displays
polyamorphism, i.e., water separates into two distinct liquid
phases. This concept of a new liquid-liquid phase transition is
finding application to other liquids as well as water, such as
silicon and silica. Specifically, we investigate, the relation
between changes in dynamic and thermodynamic anomalies arising from
the presence of the liquid-liquid critical point in (i) Two models
of water, TIP5P and ST2, which display a first order liquid-liquid
phase transition at low temperatures; (ii) the Jagla model, a
spherically symmetric two-scale potential known to possess a
liquid-liquid critical point, in which the competition between two
liquid structures is generated by repulsive and attractive ramp
interactions; and (iii) A Hamiltonian model of water where the idea
of two length/energy scales is built in. This model also displays a
first order liquid-liquid phase transition at low temperatures
besides the first order liquid-gas phase transition at high
temperatures. We find a correlation between the dynamic fragility
crossover and the locus of specific heat maxima CPmax
(“Widom line”) emanating from the critical point. Our findings are
consistent with a possible relation between the previously
hypothesised liquid-liquid phase transition and the transition in
the dynamics recently observed in neutron scattering experiments on
confined water. More generally, we argue that this connection
between CPmax and the dynamic crossover is not limited to
the case of water, a hydrogen bonded network liquid, but is a more
general feature of crossing the Widom line, an extension of the
first-order coexistence line in the supercritical region.
Dedicated to Armin Bunde on the occasion of his 60th birthday. 相似文献
104.
Joanne E. Stanley Anthony C. Swain Kieran C. Molloy David W. H. Rankin Heather E. Robertson Blair F. Johnston 《应用有机金属化学》2005,19(5):644-657
Perfluoroalkytin compounds R(4−n)Sn(Rf)n (R = Me, Et, Bu, Rf = C4F9, n = 1; R = Bu, Rf = C4F9, n = 2, 3; R = Bu, Rf = C6F13, n = 1) have been synthesized, characterized by 1H, 13C, 19F and 119Sn NMR, and evaluated as precursors for the atmospheric pressure chemical vapour deposition of fluorine‐doped SnO2 thin films. All precursors were sufficiently volatile in the range 84–136 °C and glass substrate temperatures of ca 550 °C to yield high‐quality films with ca 0.79–2.02% fluorine incorporation, save for Bu3SnC6F13, which incorporated <0.05% fluorine. Films were characterized by X‐ray diffraction, scanning electron microscopy, thickness, haze, emissivity, and sheet resistance. The fastest growth rates and highest quality films were obtained from Et3SnC4F9. An electron diffraction study of Me3SnC4F9 revealed four conformations, of which only the two of lowest abundance showed close F Sn contacts that could plausibly be associated with halogen transfer to tin, and in each case it was fluorine attached to either the γ‐ or δ‐carbon atoms of the Rf chain. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
105.
Morphine fluorescence spectra were obtained for morphine sulfate in distilled water, in KRP solution, and in KRP solutions with various concentrations of Ca++ and Mg++. No evidence of fluorescence shifting indicative of complex formation was observed. Similar solutions were used in a potentiometric study, and no evidence for complex formation was observed. 相似文献
106.
Nicholas Douglas Charles J. Neef Robert A. Rogers Jake A. Stanley Jacob Armitage Ben Martin Todd W. Hudnall William J. Brittain 《Journal of Physical Organic Chemistry》2013,26(8):688-695
The synthesis and reactivity of a tetrahydrochromeno[2,3‐b]indoles are reported. Evidence for reversible ring‐opening is based on H/D exchange and trapping experiments. These compounds readily undergo reaction with tetra‐n‐butylammonium cyanide. The cyanide reaction is 10–100× faster when the solution is irradiated with 350 nm light. Reaction with trimethylsilyl cyanide occurs only with UV irradiation demonstrating photoreactivity. The rate of tetrahydrochromeno[2,3‐b]indole ring‐opening is greater for (i) Me substitution at the hemiaminal carbon (compared to Ph), and (ii) substitution of fluorine at the 9‐position of the indole. Under acidic conditions, the ring‐opened indolium ion is observed. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
107.
108.
109.
W.-S. Jung F. Z. Wang S. Havlin T. Kaizoji H.-T. Moon H. E. Stanley 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,62(1):113-119
We investigate scaling and memory effects in return intervals between price volatilities above a certain threshold q for the
Japanese stock market using daily and intraday data sets. We find that the distribution of return intervals can be approximated
by a scaling function that depends only on the ratio between the return interval τ and its mean 〈τ〉. We also find memory effects
such that a large (or small) return interval follows a large (or small) interval by investigating the conditional distribution
and mean return interval. The results are similar to previous studies of other markets and indicate that similar statistical
features appear in different financial markets. We also compare our results between the period before and after the big crash
at the end of 1989. We find that scaling and memory effects of the return intervals show similar features although the statistical
properties of the returns are different. 相似文献
110.
Skibinsky A Buldyrev SV Scala A Havlin S Stanley HE 《Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics》1999,60(3):2664-2669
We investigate the formation of a two-dimensional quasicrystal in a monodisperse system, using molecular dynamics simulations of hard-sphere particles interacting via a two-dimensional square-well potential. We find that more than one stable crystalline phase can form for certain values of the square-well parameters. Quenching the liquid phase at a very low temperature, we obtain an amorphous phase. By heating this amorphous phase, we obtain a quasicrystalline structure with fivefold symmetry. From estimations of the Helmholtz potentials of the stable crystalline phases and of the quasicrystal, we conclude that the observed quasicrystal phase can be the stable phase in a specific range of temperatures. 相似文献