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81.
    
During the last two decades, revealing mechanisms of origin waves with anomalous amplitude (rogue waves) have been in the focus of researchers from different fields ranging from oceanography to laser physics. Mode‐locked lasers, as a test bed system, provide a unique opportunity to collect more data on rogue waves in the form of random pulses (soliton rain) and to clarify the mechanisms of rogue‐wave emergence caused by soliton–soliton and soliton–dispersive wave interactions. Here, for the first time, for an Er‐doped mode‐locked laser, a new type of vector rogue waves is demonstrated experimentally and theoretically, which is driven by desynchronization of the orthogonal linear states of polarization, so leading to output power oscillations in the form of anomalous spikes‐dips (bright‐dark rogue waves). The results can pave the way to unlocking the universal nature of the origin of rogue waves and thus can be of interest to the broad scientific community.  相似文献   
82.
    
In this study, we focus our attention on the impact of ozone (O3) and ultraviolet radiation (UV) on materials usable for three‐dimensional (3D) printing. Specifically, we have studied the potential degradative effect on the most commonly used filaments, such as polylactic acid (PLA) and acrylonitrile–butadiene–styrene (ABS). The effect has been examined on objects printed on a 3D printer and on the materials of discharge chambers of O3 generators from which they were printed. For the purpose of adequate assessment of the actual impact of O3 and UV, samples were monitored for a period of 18‐hr of exposure. The methods of Raman spectroscopy, optical and scanning electron microscopy and Fourier‐transform infrared spectroscopy (FTIR) have been employed for an objective evaluation of potential modifications. A generator equipped with a chamber printed from a new PLA filament and an active electrode system in the form of a stripes electrode, or more precisely, in the second case, a honeycomb‐active electrode, both cut out of a thin copper foil, was used for the generation of O3 and UV radiation. The tested materials showed substantial resistance to O3 exposure under the test conditions. The result of measurements suggested that these materials could be used for chambers for the O3 as well as for active particle generation.  相似文献   
83.
    
The reactivity of 5-aminouracil derivatives in the model reaction of autoxidation of styrene initiated by 2,2′-azobis(2-methylpropionitrile) was studied. Alkyl substituents at the 6-position of the uracil ring have a significant effect on the kinetic parameters of inhibition. The N-H bond dissociation energy calculated at the M06-2X/MG3S and G4 levels of the theory does not agree with the experimental values of the rate constants. The transition state was calculated at the M05/MG3S level of theory for 1,3-dimethyl-5-aminouracil, 1,3,6-trimethyl-5-aminouracil, 1,3-dimethyl-6-ethyl-5-aminouracil, 1,3-dimethyl-6-isopropyl-5-aminouracil and 3-butyl-6-methyl-5-aminouracil. The enthalpy of the transition state is in agreement with the experimental data and it can be used to evaluate the reactivity of the 5-aminouracil derivatives with peroxyl radicals.  相似文献   
84.
85.
Applying symmetry reduction to a class of SL ( 2 , R ) $mathrm{SL}(2,mathbb {R})$ -invariant third-order ordinary differential equations (ODEs), we obtain Abel equations whose general solution can be parameterized by hypergeometric functions. Particular case of this construction provides a general parametric solution to the Kudashev equation, an ODE arising in the Gurevich–Pitaevskii problem, thus giving the first term of a large-time asymptotic expansion of its solution in the oscillatory (Whitham) zone.  相似文献   
86.
    
In this work, we estimate the number of randomly selected elements of a tensor that with high probability guarantees local convergence of Riemannian gradient descent for tensor train completion. We derive a new bound for the orthogonal projections onto the tangent spaces based on the harmonic mean of the unfoldings' singular values and introduce a notion of core coherence for tensor trains. We also extend the results to tensor train completion with auxiliary subspace information and obtain the corresponding local convergence guarantees.  相似文献   
87.
The interstellar medium provides a unique laboratory for highly supersonic, driven hydrodynamic turbulence. We propose a theory of such turbulence, test it by numerical simulations, and use the results to explain observational scaling properties of interstellar molecular clouds, the regions where stars are born.  相似文献   
88.
The equations connecting elements of the Yukawa matrix to elements of the active neutrino mass matrix in the νMSM theory (an extension of the Standard Model by a singlet of three right-handed neutrinos) was analyzed, and explicit relations for the ratio of the Yukawa matrix elements and elements of the active neutrino mass matrix were obtained. This relation can be used for getting more accurate constraints on the model parameters. Particularly, with the help of the obtained results we investigated CP-violating phase in the νMSM theory. We demonstrate that even in the case when elements of the active neutrino mass matrix are real the baryon asymmetry can be generated also.  相似文献   
89.
We propose a phenomenological theory of strong incompressible magnetohydrodynamic turbulence in the presence of a strong large-scale external magnetic field. We argue that in the inertial range of scales, magnetic-field and velocity-field fluctuations tend to align the directions of their polarizations. However, the perfect alignment cannot be reached; it is precluded by the presence of a constant energy flux over scales. As a consequence, the directions of shear-Alfvén fluid and magnetic-field fluctuations at each scale lambda become effectively aligned within the angle phi(lambda) proportional to lambda (1/4), which leads to scale-dependent depletion of the nonlinear interaction and to the field-perpendicular energy spectrum E(k(perpendicular)) proportional to k(perpendicular)(-3/2). Our results may be universal, i.e., independent of the external magnetic field, since small-scale fluctuations locally experience a strong field produced by large-scale eddies.  相似文献   
90.
Peak assignment is a complex but important task for analyzing the vibration spectra of surface-bound molecules. Here we describe a simple approach for calculating infrared and Raman spectra for surface-bound molecules using a cluster model approach with quantum capping potentials (QCPs). The utility of the approach is demonstrated by comparisons to the measured high resolution electron energy loss spectra for ethylene on clean silicon. By capping the silicon cluster with QCPs we computed spectra that agree very well with the HREEL spectrum, allowing us to easily assign the experimental peaks. QCPs are similar to effective core potentials, can be used with any ab initio technique and most computational chemistry packages, and their use requires no special expertise.  相似文献   
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