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11.
Minko S Müller M Motornov M Nitschke M Grundke K Stamm M 《Journal of the American Chemical Society》2003,125(13):3896-3900
We report a route to fabricate two-level structured self-adaptive surfaces (SAS) of polymer materials. The first level of structure is built by a rough polymer film that consists of needlelike structures of micrometer size. The second level of structure is formed by the nanoscopic self-assembled domains of a demixed polymer brush irreversibly grafted onto the needles. By exposing the surface to solvents that are selective to one of the components of the brush, we reversibly tune the surface properties. The large-scale surface structure amplifies the response and enables us to control wettability, adhesion, and chemical composition of the surface over a wide range. 相似文献
12.
R.?J.?Davies N.?E.?ZafeiropoulosEmail author K.?Schneider S.?V.?Roth M.?Burghammer C.?Riekel J.?C.?Kotek M.?Stamm 《Colloid and polymer science》2004,282(8):854-866
The mechanical behaviour of semi-crystalline polymers is greatly influenced by the properties of the crystalline and the amorphous phases. As a result this topic has been the subject of extensive research. However, to date, a comprehensive relationship between the structure and mechanical properties for semi-crystalline polymers has yet to be established. This present study concerns the commissioning of a novel method for in situ data collection during the deformation of polymers. This involves the combination of three different techniques into a single experiment, namely tensile testing, synchrotron radiation wide angle X-ray scattering, and optical microscopy. For this current investigation, three isotactic polypropylene samples have been studied, produced using different thermal treatments. This enables the influence of thermal treatment on the mechanical properties and crystallographic structure to be assessed. The results indicate that tensile properties are influenced by thermal treatment via the relative fraction of -phase material in the sample. As the temperature increases at which thermal treatment takes place, iPP ductility decreases due to the greater rigidity of the increasing -phase content. Differences in crystal strain between the different iPP crystal phases are also observed although the reasons for such differences remain unclear. 相似文献
13.
K Yoon Y Yang P Lu D Wan HC Peng K Stamm Masias PT Fanson CT Campbell Y Xia 《Angewandte Chemie (International ed. in English)》2012,51(38):9543-9546
Ceria (CeO(2) ) hollow fibers with Pt nanoparticles (Pt?NPs) embedded in their inner surfaces were prepared by sequentially depositing Pt?NPs and CeO(2) sheaths on electrospun fibers of polystyrene, followed by calcination in air at 400?°C. Despite a relatively low Pt loading in this system, the turnover frequency for CO oxidation was 2-3 orders of magnitude higher than those of other systems, and the reactivity was also stable up to 700?°C. 相似文献
14.
Bittrich E Burkert S Müller M Eichhorn KJ Stamm M Uhlmann P 《Langmuir : the ACS journal of surfaces and colloids》2012,28(7):3439-3448
Temperature-sensitive poly(N-isopropylacrylamide) (PNIPAAm) brushes with different molecular weights M(n) and grafting densities σ were prepared by the "grafting-to" method. Changes in their physicochemical properties according to temperature were investigated with the help of in situ spectroscopic ellipsometry and in situ attenuated total reflection Fourier-transform infrared (ATR-FTIR) spectroscopy. Brush criteria indicate a transition between a brush conformation below the lower critical solution temperature (LCST) and an intermediate to mushroom conformation above the LCST. By in situ ellipsometry distinct changes in the brush layer parameters (wet thickness, refractive index, buffer content) were observed. A broadening of the temperature region with maximum deswelling occurred with decreasing grafting density. The brush layer properties were independent of the grafting density below the LCST, but showed a virtually monotonic behavior above the LCST. The midtemperature ?(half) of the deswelling process increased with increasing grafting density. Thus grafting density-dependent design parameters for such functional films were presented. For the first time, ATR-FTIR spectroscopy was used to monitor segment density and hydrogen bonding changes of these very thin PNIPAAm brushes as a function of temperature based on significant variations of the methyl stretching, Amide I, as well as Amide II bands with respect to intensity and wavenumber position. No dependence on M(n) and σ in the wavenumber shift of these bands above the LCST was found. The temperature profile of these band intensities and thus segment density was found to be rather step-like, exceeding temperatures around the LCST, while the respective profile of their wavenumber positions suggested continuous structural and hydration processes. Remaining buffer amounts and residual intermolecular segment/water interaction in the collapsed brushes above the LCST could be confirmed by both in situ methods. 相似文献
15.
Peter ?ernoch Petr Štěpánek Miroslav Šlouf Manfred Stamm 《European Polymer Journal》2007,43(4):1144-1153
A systematic study of formation of surface patterns in block copolymer thin layers after their exposure to solvent vapors was performed. The studied effect involves layers of thickness approximately equal to the ordering size of polymers - about 45 nm. Experiments were performed on three styrene - methacrylate derivative block copolymers, synthesized by living anionic polymerization: poly(4-octylstyrene)-block-poly(butyl methacrylate), poly(4-fluorostyrene)-block-poly(butyl methacrylate) and poly(p-octylstyrene)-block-poly(methyl methacrylate). The polymers were exposed to vapors of chloroform, 1,4-dioxane, hexane, acetone and tetrahydrofuran. 相似文献
16.
Uhlmann P Houbenov N Brenner N Grundke K Burkert S Stamm M 《Langmuir : the ACS journal of surfaces and colloids》2007,23(1):57-64
Binary brushes constituted from two incompatible polymers can be used in the form of ultrathin polymeric layers as a versatile tool for surface engineering to tune physicochemical surface characteristics such as wettability, surface charge, chemical composition, and morphology and furthermore to create responsive surface properties. Mixed brushes of oppositely charged weak polyelectrolytes represent a special case of responding surfaces that are sensitive to changes in the pH value of the aqueous environment and therefore represent interesting tools for biosurface engineering. The polyelectrolyte brushes used for this study were composed of two oppositely charged polyelelctrolytes poly(2-vinylpyridine) (P2VP) and poly(acrylic acid) (PAA). The in-situ properties and surface characteristics such as as surface charge, surface tension, and extent of swelling of these brush layers are functions of the pH value of the surrounding aqueous solution. To test the behavior of the mixed polylelctrolyte brushes in contact with biosystems, protein adsorption experiments with globular model proteins were performed at different pH values and salt concentrations (confinement of counterions) of the buffer solutions. The influence of the pH value, buffer salt concentration, and isoelectric points (IEP) of the brush and protein on the adsorbed amount and the interfacial tension during protein adsorption as well as the protein adsorption mechanism postulated in reference to recently developed theories of protein adsorption on polyelectrolyte brushes is discussed. In the salted regime, protein adsorption was found to be similar to the often-described adsorption at hydrophobic surfaces. However, in the osmotic regime the balance of electrostatic repulsion and a strong entropic driving force, "counterion release", was found to be the main influence on protein adsorption. 相似文献
17.
Binary polymer brushes grafted to Si wafers were prepared from hydrophilic and hydrophobic polymer components, which allow switching the surface properties (as revealed by contact angles) by exposure to varying solvents. The hydrophilic component was poly-2-vinylpyridine; the hydrophobic component was a copolymer of styrene and 2-(4-vinylphenyl)indene containing the photodimerizable phenylindene chromophore. The brushes were prepared via thermal and via photochemical grafting-to methods, which led to distinct layer thicknesses. Structural patterns differing in surface properties were produced and fixed via crosslinking the hydrophobic component by 2pi+2pi photodimerization of phenylindene moieties. The patterns were visually observable. 相似文献
18.
P. Müller-Buschbaum J. S. Gutmann R. Cubitt M. Stamm 《Colloid and polymer science》1999,277(12):1193-1199
The surface morphologies of confined, dewetted polymer films were investigated with atomic force microscopy (AFM) and grazing-incidence
small-angle neutron scattering (GISANS). On examining homopolymer films of deuterated polystyrene (dPS) both techniques reveal
the resulting droplet structure which is described by one most prominent in-plane length. Due to the contrast resulting from
deuteration in the case of polymer blend films of dPS and poly(p-methyl styrene) GISANS is able to probe the in-plane composition of the dewetting structure. An additional phase separation
process at different length scales gives rise to a sub- and superstructure which is not detectable by AFM. In addition, the
influence of the wavelength used in the GISANS experiments on the structures observed is discussed.
Received: 13 April 1999 Accepted in revised form: 29 June 1999 相似文献
19.
Ignacio García Agnieszka Tercjak Nikolaos E. Zafeiropoulos Manfred Stamm Iaki Mondragon 《Macromolecular rapid communications》2007,28(24):2361-2365
Magnetic nanomaterials have been studied in order to generate novel nanocomposites that display both the magnetic properties of the nanoparticles and the ability to self‐assemble of the amorphous block copolymer matrix. Towards this goal, iron oxide magnetic nanoparticles have been modified with PS brushes by ATRP in order to improve both the dispersion and the affinity of the nanoparticles with one of the blocks of a polystyrene‐block‐polybutadiene‐block‐polystyrene block copolymer. This method of preparation of nanocomposites opens new strategies for the generation of magnetic nanomaterials. The samples are characterized using DSC and atomic and magnetic force microscopies.
20.
We consider the development of efficient and fast computational methods for parametrized electromagnetic scattering problems involving many scattering three dimensional bodies. The parametrization may describe the location, orientation, size, shape and number of scattering bodies as well as properties of the source field such as frequency, polarization and incident direction. The emphasis is on problems that need to be solved rapidly to accurately simulate the interaction of scattered fields under parametric variation, e.g., for design, detection, or uncertainty quantification. For such problems, the use of a brute force approach is often ruled out due to the computational cost associated with solving the problem for each parameter value.In this work, we propose an iterative reduced basis method based on a boundary element discretization of few reference scatterers to resolve the computationally challenging large scale problem. The approach includes (i) a computationally intensive offline procedure to create a selection of a set of snapshot parameters and the construction of an associated reduced basis for each reference scatterer and (ii) an inexpensive online algorithm to generate the surface current and scattered field of the parametrized configuration, for any choice of parameters within the parameter domains used in the offline procedure. Comparison of our numerical results with directly measured results for some benchmark configurations demonstrate the power of our method to rapidly simulate the interacting electromagnetic fields under parametric variation of the overall multiple particle configuration. 相似文献