Low-frequency whale and seismic airgun sounds recorded in the mid-Atlantic Ocean

Beginning in February 1999, an array of six autonomous hydrophones was moored near the Mid-Atlantic Ridge (35 degrees N-15 degrees N, 50 degrees W-33 degrees W). Two years of data were reviewed for whale vocalizations by visually examining spectrograms. Four distinct sounds were detected that are believed to be of biological origin: (1) a two-part low-frequency moan at roughly 18 Hz lasting 25 s which has previously been attributed to blue whales (Balaenoptera musculus); (2) series of short pulses approximately 18 s apart centered at 22 Hz, which are likely produced by fin whales (B. physalus); (3) series of short, pulsive sounds at 30 Hz and above and approximately 1 s apart that resemble sounds attributed to minke whales (B. acutorostrata); and (4) downswept, pulsive sounds above 30 Hz that are likely from baleen whales. Vocalizations were detected most often in the winter, and blue- and fin whale sounds were detected most often on the northern hydrophones. Sounds from seismic airguns were recorded frequently, particularly during summer, from locations over 3000 km from this array. Whales were detected by these hydrophones despite its location in a very remote part of the Atlantic Ocean that has traditionally been difficult to survey.     

Quantum necking in stressed metallic nanowires

When a macroscopic metallic wire is subject to tensile stress, it necks down smoothly as it elongates. We show that nanowires with radii comparable to the Fermi wavelength display remarkably different behavior. Using concepts from fluid dynamics, a partial differential equation for nanowire shape evolution is derived from a semiclassical energy functional that includes electron-shell effects. A rich dynamics involving movement and interaction of kinks connecting locally stable radii is found, and a new class of universal equilibrium shapes is predicted.     

Spectral broadening and stimulated Raman conversion in a continuous-wave optical parametric oscillator

We have confirmed that single-frequency oscillation of a continuous-wave singly resonant optical parametric oscillator is limited to operation below a critical value of the pumping ratio, as predicted by early theoretical treatments. We also report different regimes of spectral broadening as well as stimulated Raman conversion of the signal wave above this critical pump level. We show that spectral broadening may be eliminated by implementing output coupling of the signal wave and demonstrate 8.6 W of total signal and idler output with single-frequency spectra at both wavelengths for 14.5 W of pump power.     

Singing behavior of fin whales in the Davis Strait with implications for mating, migration and foraging

Most baleen whales undertake migrations between low-latitude breeding grounds and high-latitude feeding grounds. Though little is known about the timing of their migration from the Arctic, fin whales are assumed to undertake a similar migratory pattern. To address questions about habitat use and migrations, the acoustic activity of fin whales in Davis Strait, between Greenland and Canada, was monitored continuously for two years using three bottom-moored acoustic recorders. The acoustic power in the fin whale call frequencies peaked in November-December, showing that fin whales are present in Davis Strait much later in the year than previously expected. The closely timed peaks in song activity and conception time imply that not all fin whales migrate south to mate, but rather start mating at high latitudes rather than or before migrating. Singing activity was strongly linked to daylight hours, suggesting that fin whales might feed during the few daylight hours of the late fall and early Arctic winter. A negative correlation between the advancing sea ice front and power in fin whale frequencies indicates that future changes in sea ice conditions from global warming might change the distribution and migratory patterns of fin whales near the poles.     

Fluorescent sensor for fluoride anion based on a sulfonamido-chromone scaffold

New scaffolds of sulfonamido-chromone derivatives recently synthesized were found to be effective fluorescent sensors for fluoride anion. This new class of fluorophore showed a blue shift in the emission spectra upon addition of various equivalents of fluoride. These compounds also exhibit excellent selectivity for the fluoride anion via a deprotonation process. They were also shown to have a detection limit of F^? down to 0.5?ppm.