全文获取类型
收费全文 | 7081篇 |
免费 | 218篇 |
国内免费 | 2篇 |
专业分类
化学 | 4174篇 |
晶体学 | 65篇 |
力学 | 219篇 |
数学 | 926篇 |
物理学 | 1917篇 |
出版年
2021年 | 47篇 |
2020年 | 83篇 |
2019年 | 62篇 |
2018年 | 68篇 |
2017年 | 56篇 |
2016年 | 158篇 |
2015年 | 147篇 |
2014年 | 139篇 |
2013年 | 293篇 |
2012年 | 333篇 |
2011年 | 367篇 |
2010年 | 227篇 |
2009年 | 187篇 |
2008年 | 310篇 |
2007年 | 318篇 |
2006年 | 295篇 |
2005年 | 269篇 |
2004年 | 256篇 |
2003年 | 199篇 |
2002年 | 212篇 |
2001年 | 140篇 |
2000年 | 123篇 |
1999年 | 112篇 |
1998年 | 76篇 |
1997年 | 86篇 |
1996年 | 78篇 |
1995年 | 92篇 |
1994年 | 64篇 |
1993年 | 65篇 |
1992年 | 101篇 |
1991年 | 61篇 |
1990年 | 85篇 |
1989年 | 60篇 |
1988年 | 89篇 |
1987年 | 68篇 |
1986年 | 57篇 |
1985年 | 78篇 |
1984年 | 64篇 |
1983年 | 58篇 |
1982年 | 66篇 |
1981年 | 77篇 |
1980年 | 80篇 |
1979年 | 64篇 |
1978年 | 67篇 |
1977年 | 72篇 |
1976年 | 60篇 |
1975年 | 59篇 |
1974年 | 55篇 |
1973年 | 48篇 |
1967年 | 43篇 |
排序方式: 共有7301条查询结果,搜索用时 328 毫秒
51.
R. Suntz H. Becker P. Monkhouse J. Wolfrum 《Applied physics. B, Lasers and optics》1988,47(4):287-293
Two-dimensional laser-induced fluorescence (2D-LIF) imaging of OH radicals, excited at 308 nm, has been employed to visualize the flame front in an internal combustion engine burning air/propane mixtures. Light sheet thicknesses down to 70 m have been attained for excitation. Hydroxyl radicals were detected up to pressures of 7.5 bar at engine speeds of 500 rpm. An upper limit of 300 m for the flame front thickness was obtained from line intensity profiles. 相似文献
52.
Büttiker and Landauer studied scattering off an oscillating rectangular barrier in order to shed light on the time aspects of tunneling. The expression for the traversal time resulting from this study is controversial. In addition, doubts have recently been expressed on technical aspects of their work. In an attempt to clarify these issues, we investigate a generalization of their model to arbitrary oscillating barriers,V(x, t)=V
0(x)+V
1(x)cos t. In the process, we confirm that Büttiker and Landauer's work is technically sound. However, we show, by several examples, that no direct general relation exists between the characteristic frequency of an oscillating barrier and the duration of the tunneling process. For a wide range of realistic parameters this characteristic frequency does not even exist.This paper is dedicated to E. G. D. Cohen. 相似文献
53.
Adler J Becker JJ Blaylock GT Bolton T Brient J Browder T Brown JS Bunnell KO Burchell M Burnett TH Cassell RE Coffman D Cook V Coward DH DeJongh F Dorfan DE Drinkard J Dubois GP Eigen G Einsweiler KF Eisenstein BI Freese T Gatto C Gladding G Grab C Hamilton RP Hauser J Heusch CA Hitlin DG Izen JM Kim PC Köpke L Li A Lockman WS Mallik U Matthews CG Mincer AI Mir R Mockett PM Mozley RF Nemati B Odian A Parrish L Partridge R Pitman D Plaetzer SA Richman JD Sadrozinski HF Scarlatella M Schalk TL 《Physical review letters》1989,62(16):1821-1824
54.
55.
56.
Dirk Lützenkirchen‐Hecht Kay Rohrmann Thomas Stöcker Wolfgang Thiel 《Surface and interface analysis : SIA》2007,39(11):845-851
Different ink‐jet printed paper materials were investigated using X‐ray photoelectron spectroscopy (XPS) yielding the elemental composition of the near‐surface region of the papers. We found significant differences with respect to the detected elements and their atomic concentrations in the different inks studied here. Two different groups of inks could be identified by means of a lower ratio of the O and C atomic concentrations and lower concentrations in specific trace elements like Mg, Na and Si. High‐resolution spectra of C 1s and O 1s core levels allowed a detailed determination of the chemical state of the respective elements. On the basis of a detailed deconvolution of these XPS signals, significant differences between all the investigated ink‐jet printed papers were found, thereby allowing their discrimination. The applicability of the measurements and, more generally, the XPS technique for forensic investigations of paper are discussed. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
57.
The association constant K of mono-acetato complex of Tb3+ has been determined at normal p and T conditions by measurement of its luminescence lifetime in aqueous solution containing increasing concentrations of acetate. Two experimental arrangements used for the measurement are described. 相似文献
58.
Analysis of K-shell excitation spectra of gas-phase molecules containing at least two atoms of either B, C. N. O or F reveals the existence of a striking correlation between the bond length of the atomic pair. the sum of their atomic numbers and the associated α-shape resonance energy. Empirical rules are established which allow the derivation of intramolecular distances with accuracies reliably better than ± 0.05 A from the K-.shell absorption spectrum of one of the atoms in the Molecule. 相似文献
59.
M. Lindinger St. Becker G. Bollen K. Dasgupta R. Jertz H. -J. Kluge L. Schweikhard M. Vogel K. Lützenkischen 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1991,20(1):441-443
Doublet mass measurements of the isobars28Si3 and12C7 are performed by use of a Penning trap mass spectrometer and the Fourier transform ion cyclotron resonance (FT-ICR). The carbon and silicon cluster ions are produced by laser ablation. Results of these preliminary measurements are presented. 相似文献
60.
Acyl- and Alkylidenephosphines. XXVIII. Synthesis and Structure of 1,3-Dibenzyl- and 1,3-Diethyl-2,4-bis(phenylimino)-1,3-diphosphetane Catalyzed by small amounts of solid sodium hydroxide, the adducts 1a and 1b formed from benzyl- or ethylbis(trimethylsilyl)phosphine and phenylisocyanate, react at +20°C slowly to give hexamethldisiloxane and oligomeric [(phenylimino)methylidene]phosphines. In different solvents the benzyl compound was found to exist only as a mixture of [N,N′-(E)/(Z)]-isomeric 2,4-bis-(phenylimino)-1,3-diphosphetanes 2a with their alkyl groups at the phosphorus atoms in trans position, whereas in case of the ethyl derivative 2b a second pair of [N,N′-(E)/(Z)]-isomeric dimers with their substituents in cis position and two trimeric forms ( 3b and 4b ) could be detected in cyclopentane. [N,N′-(E)]-1r,3t-dibenzyl- ( 2a ) and [N,N′-(E)]-1r,3t-diethyl-2,4-bis(phenylimino)-1,3-diphosphetane 2b isolated from 1,2-dimethoxyethane or cyclopentane, crystallize in the monoclinic space group P21/c or P21/n, resp., with following dimensions of the unit cell determined at temperatures of measurement of +20 ± 3°C/?130 ± 3°C: a = 2145.4(1)/569.3(1); b = 568.1(2)/719.1(2); c = 1960.2(2)/2042.6(4) pm; β 99.43(1)°/95.03(2)°; Z = (2+2) and 2, resp. X-ray structure determinations (Rw = 0.034/0.041) show both molecules to be centrosymmetric. Characteristic rounded bond lengths (pm) and angles (°) are: endocyclic P? C 185/184; C? P? C 82/81; P? C? P 98/99; exocyclic P? C 186/184; C?N l27/127; C?N? C 121/11. 相似文献