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181.
Hemant Kumar Srivastava Abed Al Aziz Quntar Abdulatif Azab Avital Shurki 《Tetrahedron》2009,65(22):4389-3774
The reaction of 6-chloro-1-hexynylphosphonate with primary and secondary amines afforded exclusively 2-aminocyclohexenylphosphonates in 62-85% isolated yields. In contrast, reaction of various amines with isobutyl 7-chlorohept-2-ynoate in acetonitrile at 70 °C gave (E)-sec-butyl 2-(1-alkylpiperidin-2-ylidene)acetates in 65-78% isolated yields. Calculations offer an explanation for the difference in the behavior of the two compounds classes. It is shown that C-C cyclization in the alkyne-phosphonate group occurs via an initial formation of a zwitterionic intermediate, which is stabilized by both an inductive effect of the phosphonate group and a newly formed hydrogen bond. The alkyne-carboxylate group, on the other hand, proceeds via enamine formation as a result of the smaller inductive effect of the carboxylate combined with involvement of an allene-like resonance form. This resonance form both delocalizes the negative charge in the zwitterionic intermediate making it to be less available for attack, and affects the geometry thus preventing formation of the stabilizing hydrogen bond. Hence, the zwitterionic intermediate of the alkyne-carboxylates is less stable leading to formation of an enamine, which is followed by N-C cyclization to give the azaheterocycles. 相似文献
182.
Bhim Bali Prasad Khushaboo Tiwari Meenakshi Singh Piyush S. Sharma Amit K. Patel Shrinkhala Srivastava 《Chromatographia》2009,69(9-10):949-957
A combination approach in solid-phase microextraction, based on a molecularly imprinted polymer-brush coating on an optical fiber coupled with a complementary molecularly imprinted polymer sensor, has been adopted for isolation, preconcentration, and analysis of dopamine at ultratrace levels in highly dilute aqueous samples. This combination enabled enhanced (up to 8.5-fold) preconcentration of the analyte, which is appropriate for achieving a stringent detection limit in clinical diagnosis of several neurodegenerative diseases. The detection limit of dopamine in biological samples was 0.018 ng mL?1 with a relative standard deviation less than 2.1% and without any non-specific contributions. 相似文献
183.
It is shown in this paper, by making use of contour integration and the Cauchy integral theorem, that two general families of definite integrals can be evaluated in closed form and are expressible only in terms of the Hurwitz zeta function and elementary functions. In addition, a number of interesting (known or new) special cases and consequences of the main results are considered and some comparison with results of symbolic computation is made. 相似文献
184.
The variation of density and flow speed of ions in a laser produced plasma as function of the intensity of the wave for different beam width parameter is studied. It is found that self-focusing of the beam increases the density and decreases the velocity in the overdense region whereas it decreases the density and increases the velocity in the underdense region. 相似文献
185.
Pratibha Srivastava Inder Pal Singh Kapoor Gurdip Singh Roland Fröhlich 《Journal of Thermal Analysis and Calorimetry》2010,100(1):233-238
Phenylenediammonium dibromide (PDADBr) salts have been prepared and characterized by X-ray crystallography. The thermal decomposition
of PDADBr has been studied by thermogravimetry (TG) and differential thermal analysis (DTA). Kinetic parameters have been
evaluated using model fitting and isoconversional methods. The thermolytic pathways have also been suggested which involve
proton transfer as a primary step to regenerate parent amine and HBr. Interaction between amine and HBr at higher temperature
yields gaseous products. 相似文献
186.
B. S. Tomar A. Goswami S. K. Das T. Datta B. K. Srivastava A. G. C. Nair Satya Prakash M. V. Ramaniah 《Zeitschrift für Physik A Hadrons and Nuclei》1987,327(2):225-229
Independent isomeric yield ratios of128Sb were determined radiochemically in the thermal neutron induced fission of241Pu and 34 MeV alpha particle induced fission of238U, both involving the same compound nucleus (242Pu). Fragment angular momenta estimated from the measured isomer ratios using the statistical model analysis showed significantly larger fragment angular momenta in the medium energy fissioning system compared to the low energy fissioning system. This has been attributed to the effect of higher excitation energy and angular momentum in the entrance channel leading to increased fragment temperature, moments of inertia and angular velocity. An attempt was made to calculate the fragment angular momentum in the medium energy fission using the Fermi gas model for the fissioning nucleus, taking into account the multichance fission, saddle shapes of the fissioning nuclei and the angular velocity components of the fissioning nuclei both along and orthogonal to the fission axis. The calculated angular momenta agree well with the experimental results. 相似文献
187.
Idris Mohd Srivastava Seema Baggi Tulsidas R. Shukla Sudhir Kumar 《平面色谱法杂志一现代薄层色谱法》2010,23(5):339-342
JPC – Journal of Planar Chromatography – Modern TLC - A simple, accurate, and inexpensive high-performance thin-layer chromatography (HPTLC) method has been established for analysis of... 相似文献
188.
Priyanka G. Mandhane 《Tetrahedron letters》2010,51(23):3138-939
An environmentally benign aqueous Biginelli protocol for the synthesis of substituted 3,4-dihydropyrimidin-2(1H)-ones using thiamine hydrochloride as a catalyst has been achieved. These ultrasound-assisted reactions proceed efficiently in water in the absence of organic solvent. Utilization of ultrasound irradiation, simple reaction conditions, isolation, and purification makes this manipulation very interesting from an economic and environmental perspective. 相似文献
189.
Aejazur Rahman Saumya S Srivastava Amita Sneh Neesar Ahmed Musti V Krishnasastry 《BMC biochemistry》2010,11(1):35
Background
Mycobacterium tuberculosis is a virulent bacillus causing tuberculosis, a disease responsible for million deaths each year worldwide. In order to understand its mechanism of pathogenesis in humans and to help control tuberculosis, functions of numerous Mycobacterium tuberculosis genes are being characterized. In this study we report the dual functionality of tlyA gene product of Mycobacterium tuberculosis annotated as Rv1694, a 268 amino acid long basic protein. 相似文献190.
Matthew Curtis Mikael A. Minier Priyanka Chitranshi O. David Sparkman Patrick R. Jones Liang Xue 《Journal of the American Society for Mass Spectrometry》2010,21(8):1371-1381
Direct analysis in real time (DART) mass spectrometry is a recently developed innovative technology, which has shown broad
applications for fast and convenient analysis of complex samples. Due to the ease of sample preparation, we have recently
initiated an investigation of the feasibility of detecting nucleotides and nucleosides using the DART-AccuTOF instrument,
which we will refer to as the DART mass spectrometer. Our experimental results reveal that the ions representing the intact
molecules of nucleotides are not detectable in either positive-ion or negative-ion mode. Instead, all four natural nucleotides
fragment in the DART ion source, and a common fragment ion, [C5H5O]+ (1), is observed, which is probably formed via multiple-elimination reactions. Interestingly, 1 can form adducts with nucleobases
in different molar ratios in the DART ion source. In contrast to nucleotides, the ions representing the intact molecules of
nucleosides are detected in both positive-ion and negative-ion mode using DART mass spectrometry. Surprisingly, the fragmentation
pattern of nucleosides is different from that of nucleotides in the DART ion source. In the cases of nucleosides (under positive-ion
conditions), the production of 1 is not observed, indicating that the phosphate group plays an important role for the multiple
eliminations observed in the spectra of nucleotides. The in-source reactions described in the present work show the complexity
of the conditions in the DART ion source, and we hope that our results illustrate a better understanding about DART mass spectrometry. 相似文献