排序方式: 共有49条查询结果,搜索用时 15 毫秒
21.
Phomphrai K Pracha S Phonjanthuek P Pohmakotr M 《Dalton transactions (Cambridge, England : 2003)》2008,(23):3048-3050
Alkyl (S)-lactate and alkyl (S,S)-lactyllactate were rapidly and conveniently synthesized from L-lactide using Group 1 and 2 metal complexes as catalyst in alcohol. 相似文献
22.
The syntheses of indolizidine alkaloids, i.e., (±)-coniceine, (±)-indolizidine 167B, (±)-5-butylindolizidine and (±)-monomorine I via Pummerer cyclization are described. The key step is the transformation of lactam sulfoxide to bicyclic lactam via the Pummerer cyclization. 相似文献
23.
Napasawan Chumnanvej Praewpan Katrun Manat Pohmakotr Vichai Reutrakul Darunee Soorukram Chutima Kuhakarn 《中国化学》2016,34(8):830-838
A highly efficient method for direct nitration‐oximization of styrene derivatives using tert‐butyl nitrite (t‐BuONO) in DMSO was developed. The present method offers a convenient and practical approach for the synthesis of α‐nitrooximes in moderate to high yields. The salient features entail mild reaction conditions, metal‐free reagent, environmentally benign solvent and simple experimental procedure. 相似文献
24.
Darunee Soorukram Jaray PanmuangPatoomratana Tuchinda Chutima KuhakarnVichai Reutrakul Manat Pohmakotr 《Tetrahedron》2014
A stereoselective approach to secolignans is described. The key synthetic strategy involves an asymmetric aldol reaction to control the creation of the stereogenic center at the β-carbon of the target secolignans. In the present work, peperomin C and its analogues, i.e., 2,6-didehydropeperomin C and 2-epi-peperomin C were successfully synthesized in good yields with high stereoselectivities. 相似文献
25.
Charoensak Muangkaew Praewpan Katrun Patcharaphon Kanchanarugee Manat Pohmakotr Vichai Reutrakul Darunee Soorukram Thaworn Jaipetch Chutima Kuhakarn 《Tetrahedron》2013
A convenient method for 1,2-acetoxysulfenylation of alkenes using disulfide promoted by (diacetoxyiodo)benzene (PhI(OAc)2, DIB)/KI was developed. The reaction is highly regioselective for styrene derivatives while aliphatic alkenes lead to a mixture of two regioisomers. 相似文献
26.
Phomphrai K Pongchan-o C Thumrongpatanaraks W Sangtrirutnugul P Kongsaeree P Pohmakotr M 《Dalton transactions (Cambridge, England : 2003)》2011,40(10):2157-2159
A series of bis(amidinate) tin(II) complexes is synthesized and shown to rapidly polymerize ε-caprolactone (ε-CL) in the presence and absence of benzyl alcohol giving high-molecular-weight poly(ε-CL) (M(n) up to 160,600 Da). Ligands having electron donating groups were found to accelerate the polymerization by making the complex more nucleophilic. 相似文献
27.
Reutrakul V Thongpaisanwong T Tuchinda P Kuhakarn C Pohmakotr M 《The Journal of organic chemistry》2004,69(20):6913-6915
Bromodifluorophenylsulfanylmethane has been demonstrated to be a highly versatile gem-difluoromethylene (CF2) building block via the reaction of difluorophenylsulfanylmethyl radical with olefins. gem-Difluoroalkenes and products containing a midchain CF2 group and with manipulatable functionality can be readily synthesized. The first example of a gem-difluoromethylene radical synthon is also reported. 相似文献
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29.
Preparation of β-alkylsubstituted α,β-unsaturated aldehydes using a new d3-reagent is described. 相似文献
30.
Waraporn Panchan Deanna L. Snyder Manat Pohmakotr Thaworn Jaipetch 《Tetrahedron》2010,66(14):2732-1086
The combination of (diacetoxy)iodobenzene (PhI(OAc)2, DIB) and lithium bromide (LiBr) efficiently oxidized cyclic and acyclic acetals to the corresponding hydroxyalkyl carboxylic esters and simple esters in good to excellent yields. The merits of this reaction are that it employs commercially available and non-explosive hypervalent iodine(III) reagent, water as the solvent, a short reaction time, and mild reaction conditions. 相似文献