全文获取类型
收费全文 | 489篇 |
免费 | 11篇 |
国内免费 | 2篇 |
专业分类
化学 | 355篇 |
晶体学 | 14篇 |
力学 | 24篇 |
数学 | 34篇 |
物理学 | 75篇 |
出版年
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 7篇 |
2020年 | 16篇 |
2019年 | 17篇 |
2018年 | 10篇 |
2017年 | 13篇 |
2016年 | 16篇 |
2015年 | 8篇 |
2014年 | 7篇 |
2013年 | 38篇 |
2012年 | 30篇 |
2011年 | 51篇 |
2010年 | 29篇 |
2009年 | 26篇 |
2008年 | 38篇 |
2007年 | 24篇 |
2006年 | 29篇 |
2005年 | 21篇 |
2004年 | 24篇 |
2003年 | 14篇 |
2002年 | 9篇 |
2001年 | 4篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 3篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1965年 | 1篇 |
1961年 | 1篇 |
排序方式: 共有502条查询结果,搜索用时 0 毫秒
31.
Alan R. Katritzky Nabin K. Meher Sureyya Hanci Reena Gyanda Srinivasa R. Tala Sindhu Mathai Randolph S. Duran Sophie Bernard Firouzeh Sabri Sandeep K. Singh Jacek Doskocz David A. Ciaramitaro 《Journal of polymer science. Part A, Polymer chemistry》2008,46(1):238-256
Fourteen commercial polyols have been characterized by GPC, NMR spectroscopy, and elemental analysis. From these, eight corresponding tosylates, six nitrate esters, seven mesylates, 13 alkynes, and 14 azides have been prepared and all these derivatives have been fully characterized. Five alkyne monomers and eight azide monomers were also prepared. Twelve alkynes and 13 azides (functionality 2–4) were combined in 1,3‐dipolar cycloaddition reactions under neat conditions to prepare triazole‐cured polymers, avoiding any heavy metal catalyst. Characterization by NMR spectroscopy, elemental analysis, and gel permeation chromatography indicated triazole polymers 14 , 22 , 23 , 28 , and 30 with degrees of polymerization of 17–28 to be the best candidates for future work. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 238–256, 2008 相似文献
32.
This paper deals with a new solution technique for approximately solving certain variational problems in elasticity by using discrete optimization techniques that were originally used in information theory. This allows us to easily and approximately solve large deformation buckling problems for slender cantilever beams (including post-buckling behavior) as well as problems where the strain energy function is non-convex.The core idea is to quantize or discretize the variables describing the possible configurations of the body. This, when combined with the fact that the variational problem has an inherent Markov structure allows us to use computationally efficient search techniques based on dynamic programming (equivalent to finding the shortest path in a weighted directed graph) to find optimal solutions within the quantized state space. The results can be used in two ways: (1) directly as a fast approximate solution to the variational problem (2) As a means for finding very good (nearly minimum energy) initial configurations for application of conventional minimization techniques, which might otherwise fail because of a poor starting configurations which are far from the global minimum. We demonstrate both these uses in the paper. 相似文献
33.
V. Srinivasa Rao A. B. Samui 《Journal of polymer science. Part A, Polymer chemistry》2009,47(8):2143-2155
A series of main chain photoactive liquid crystalline polyethers, containing rigid bisbenzylidene photoactive mesogen and flexible methylene spacers, were synthesized by polycondensation of bisbenzylidene diols and dibromoalkanes. The polyethers were characterized with 1H NMR, gel permeation chromatography (GPC), differential scanning calorimeter (DSC), thermo gravimetric analyzer (TGA), and polarized light optical microscopy. The individual and combined effects of spacer length and number of methoxy substituents on mesogenic and photoactive properties were investigated. Both first order and second order transition temperatures decreased with increased spacer length and the number of substituents. The combined effect of spacers and substituents drastically reduced the transition temperatures. All monomers and polymers showed mainly the smectic mesophase. In a few cases, nematic droplets along with the smectic phase were observed. The width of the liquid crystalline phase reduced with an increasing number of methoxy substituents on mesogenic unit. Variation of spacer length has a negligible effect on photocycloaddition. However, steric hinderance caused by the substituents decreased the photoactivity as the number of substituents increased. Total energies of crosslinked dimers calculated from modeling studies supported the above findings. Intermolecular photocycloaddition was also confirmed by photoviscosity measurement. The refractive index change was found to be in the range of 0.017–0.031. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 2143–2155, 2009 相似文献
34.
J.S. Yadav B.V. Subba Reddy T. Srinivasa Rao K. Bhavani A. Raju 《Tetrahedron letters》2010,51(19):2622-4577
The vinyl arenes undergo smooth hydroalkylation with 1,3-diketones in the presence of 10 mol % of iodine to afford phenethyl diketones and ketoesters in good yields in short reaction times. The use of inexpensive and readily available molecular iodine makes this method quite simple, more convenient and practical. 相似文献
35.
Borak JB Lee HY Raghavan SR Falvey DE 《Chemical communications (Cambridge, England)》2010,46(47):8983-8985
Photorelease and photoisomerization of trans-cinnamic acid in aqueous CTAB solutions induces a bulk solution viscosity increase and decrease, respectively, triggered by orthogonal irradiation wavelengths. 相似文献
36.
Kulkarni NV Budagumpi S Kurdekar GS Revankar VK Didagi S 《Chemical & pharmaceutical bulletin》2010,58(12):1569-1575
A novel Cu(II) and Zn(II) complexes of triazolo-quinoline derivatives were synthesized by in situ method and were characterized by the spectro-analytical methods and their pharmacological properties were evaluated. The compound C3 has exhibited promising anticonvulsant activity towards the electroshock induced seizures in Wistar rats and possesses low toxicity, providing a high safety profile. 相似文献
37.
Akkinepally Bhargav Reddy I. Neelakanta Rao H. Jeevan Rao P. Srinivasa Shim Jaesool 《Journal of Solid State Electrochemistry》2023,27(4):955-967
Journal of Solid State Electrochemistry - The rational design of low-cost electrode materials with superior redox activity and high electrochemical conductivity has attracted extensive interest for... 相似文献
38.
39.
A mild and highly efficient deoxygenation of variety of N-oxides using an inexpensive CuX, or a CuX-Zn or CuX-Al couple is described. 相似文献
40.
The problem of viscous fluid past an axisymmetric body embedded in a fluid saturated porous medium is studied using the Brinkman's extension. A general formula for the drag on the body is derived in the form of a limit of an expression involving the stream function characterizing the flow. The flow past an axisymmetric approximate sphere is also considered. The stream function in this case is obtained in terms of Bessel functions and Gegenbauer's functions. The drag acting on the body is evaluated by using the formula derived. Its variation is studied with respect to geometric and permeability parameters. The special cases of flow past a sphere and a spheroid are obtained from the present analysis. To cite this article: D. Srinivasa Charya, J.V. Ramana Murthy, C. R. Mecanique 330 (2002) 417–423. 相似文献