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71.
An efficient and simple method for the synthesis of 2,2-disubstituted-2H-chromenes by one-step cyclocondensation of a phenol with a variety of 1,1-disubstituted propargyl alcohols using BF3·Et2O as the catalyst is described.  相似文献   
72.
Blend membranes of poly(vinyl alcohol) (PVA) and nylon 66 (NYL) were synthesized and crosslinked with glutaraldehyde (GA) and assessed for their suitability in dehydrating 2-butanol by pervaporation (PV). These blends were subjected to sorption studies to determine the extent of interaction and degree of swelling in pure liquids as well as binary mixtures. Wide-angle X-ray diffraction (WAXD) and thermal gravimetric analysis (TGA) were carried out to investigate changes in crystallinity and thermal stability, respectively. The effect of experimental parameters such as feed water concentration, permeate pressure and barrier thickness on membrane flux and selectivity was evaluated. The membranes were found to have good potential for breaking the azeotrope of 27.6 wt.% water with a flux of 3.07 kg/m2 h 10 μm and selectivity of 26.5. Selectivity was found to improve with decreasing feed water concentration and increasing membrane thickness, whereas opposite trends were observed in case of flux. Higher permeate pressure caused a reduction in both flux and selectivity. These effects were clearly elucidated.  相似文献   
73.
A full account of the total synthesis of (+)-cassaine ( 1) using the transannular Diels-Alder (TADA) reaction as the pivotal construction is described. The strategy began from Evans' oxazolidine 8, the only chiral source used for the total stereochemical outcome of the target molecule. The key intermediate 3 was obtained from 8 in 10 steps in 40% overall yield. Following extensive optimization, the coupling of 3 on both ends with another densely functional partner 2 followed by TADA reaction on macrocycle 4 cleanly furnished the tricycle 5. The stereochemical outcome in 5 was expected via a least-energetic transition state T4. A stereoselective reduction, hydroboration, and methyl cuprate 1,4-addition along with a few other functional interconversions transformed 5 into the key intermediate 37. Final tethering of dimethylaminoethyloxycarbonyl along with epimerization at C8 and alcohol deprotection at C3 yielded the natural product 1.  相似文献   
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76.
Largep T direct photon and dimuon production in experiments using nuclear targets have been studied in detail. We show that, by a careful choice of kinematic configurations in these experiments, very good estimates of nuclear quark and gluon densities can be obtained. Information on the cumulative region of the nuclear structure functions i.e. the regionx>1 can also be obtained by considering semi-integrated cross sections.  相似文献   
77.
A comparative study of the asymmetric reduction of representative aryl and alkyl α-fluoro- and α-chloromethyl ketones using (−)-diisopinocampheylchloroborane [(−)-DIP-Chloride™] and (−)-B-isopinocampheyl-9-borabicyclo[3.3.1]nonane [R-Alpine-Borane®] has been made. It was observed that DIP-Chloride™ is superior in terms of the rate and enantioselectivity for both classes of halo-ketones. While the reduction of monofluoroacetone and trifluoroacetone with DIP-Chloride™ provided the product alcohols in 61% ee and 96% ee, respectively, the reduction of difluoroacetone yielded only 5% ee. The influence of a lone halogen atom was not observed for monochloroacetone, all of which point towards a chelating effect of monofluoroacetone on the Lewis acidic chloroborane.  相似文献   
78.
A new polymorph of cytosine, C4H5N3O, is reported half a century after the report of its first known crystal structure [Barker & Marsh (1964). Acta Cryst. 17 , 1581–1587]. Cytosine thus provides the first polymorphic example in the category of parent nucleobases. The new form, denoted (Ib), was observed unexpectedly during an attempt to cocrystallize cytosine with catechol. Form (Ib) crystallizes in the orthorhombic centrosymmetric space group Pccn with two molecules in the asymmetric unit. The previously known form, denoted (Ia), crystallizes in the orthorhombic noncentrosymmetric space group P212121. The cytosine molecule is planar in both forms. Hydrogen‐bonding interactions are also similar for both forms. Infinite one‐dimensional ribbons composed of cytosine base‐pair dimers in R22(8) arrangements are observed in both (Ia) and (Ib). However, the way that the ribbons are packed differs in (Ia) and (Ib). This appears to guide the centrosymmetric versus noncentrosymmetric space‐group selection through the formation of an inversion‐related motif in polymorph (Ib) and a helical propagation in polymorph (Ia). A few selected polymorphic systems have been gathered from the Cambridge Structural Database to understand possible structural features responsible for achiral molecules adopting centro‐ and noncentrosymmetric space groups.  相似文献   
79.
Four structures of oxoindolyl α‐hydroxy‐β‐amino acid derivatives, namely, methyl 2‐{3‐[(tert‐butoxycarbonyl)amino]‐1‐methyl‐2‐oxoindolin‐3‐yl}‐2‐methoxy‐2‐phenylacetate, C24H28N2O6, (I), methyl 2‐{3‐[(tert‐butoxycarbonyl)amino]‐1‐methyl‐2‐oxoindolin‐3‐yl}‐2‐ethoxy‐2‐phenylacetate, C25H30N2O6, (II), methyl 2‐{3‐[(tert‐butoxycarbonyl)amino]‐1‐methyl‐2‐oxoindolin‐3‐yl}‐2‐[(4‐methoxybenzyl)oxy]‐2‐phenylacetate, C31H34N2O7, (III), and methyl 2‐[(anthracen‐9‐yl)methoxy]‐2‐{3‐[(tert‐butoxycarbonyl)amino]‐1‐methyl‐2‐oxoindolin‐3‐yl}‐2‐phenylacetate, C38H36N2O6, (IV), have been determined. The diastereoselectivity of the chemical reaction involving α‐diazoesters and isatin imines in the presence of benzyl alcohol is confirmed through the relative configuration of the two stereogenic centres. In esters (I) and (III), the amide group adopts an anti conformation, whereas the conformation is syn in esters (II) and (IV). Nevertheless, the amide group forms intramolecular N—H...O hydrogen bonds with the ester and ether O atoms in all four structures. The ether‐linked substituents are in the extended conformation in all four structures. Ester (II) is dominated by intermolecular N—H...O hydrogen‐bond interactions. In contrast, the remaining three structures are sustained by C—H...O hydrogen‐bond interactions.  相似文献   
80.
The aggregate magneto-mechanical behavior of magneto-rheological elastomers (MREs) stems from the magnetic properties of the ferromagnetic inclusion and the mechanical properties of the matrix material. We propose a large deformation micro-magnetic theory, to predict the behavior and interaction of ferromagnetic particles inside an elastomeric matrix. A rate-type variational principle, with the magnetization as the order parameter is proposed. A large deformation Landau-Lifshitz-Gilbert equation for the time evolution of the magnetization, is obtained directly from the proposed variational principle. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
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