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81.
A.J. Belfield T.G. Rogers A.J.M. Spencer 《Journal of the mechanics and physics of solids》1983,31(1):25-54
We Consider fibre-reinforced elastic plates with the reinforcement continuously distributed in concentric circles ; such a material is locally transversely isotropic, with the circumferential direction as the preferred direction. For an annulus bounded by concentric circles, the exact solution of the traction boundary value problem is obtained. When the extension modulus in the fibre direction is large compared to other extension and shear moduli, the material is strongly anisotropic. For this case a simpler approximate solution is obtained by treating the material as inextensible in the fibre direction. It is shown that the exact solution reduces to the inextensible solution in the appropriate limit. The inextensible theory predicts the occurrence of stress concentration layers in which the direct stress is infinite ; for materials with small but finite extensibility these layers correspond to thin regions of high stress and high stress gradient. A boundary layer theory is developed for these regions. For a typical carbon fibre-resin composite, the combined boundary layer and inextensible solutions give an excellent approximation to the exact solution. The theory is applied to the problem of an isotropic plate, under uniform stress at infinity, containing a circular hole which is strengthened by the addition of an annulus of fibre-reinforced material. 相似文献
82.
Manuel A.V. Ribeiro da Silva Luís M.N.B.F. Santos Luís M. Spencer S. Lima 《The Journal of chemical thermodynamics》2010,42(1):134-139
The energetic study of 1,2,3-triphenylbenzene (1,2,3-TPhB) and 1,3,5-triphenylbenzene (1,3,5-TPhB) isomers was carried out by making use of the mini-bomb combustion calorimetry and Knudsen mass-loss effusion techniques. The mini-bomb combustion calorimetry technique was used to derive the standard (p° = 0.1 MPa) molar enthalpies of formation in the crystalline state from the measured standard molar energies of combustion for both isomers. The Knudsen mass-loss effusion technique was used to measure the dependence with the temperature of the vapour pressure of crystalline 1,2,3-TPhB, which allowed the derivation of the standard molar enthalpy of sublimation, by application of the Clausius–Clapeyron equation. The sublimation study of 1,3,5-TPhB had been performed previously. From the combination of data obtained by both techniques, the standard molar enthalpies of formation in the gaseous state, for both isomers, at T = 298.15 K, were calculated. The results indicate a higher stability of the 1,3,5-TPhB isomer relative to 1,2,3-TPhB, similarly to the terphenyls. Nevertheless, the 1,2,3-TPhB isomer is not as energetically destabilized as one might expect, supporting the existence of a π–π displacive stacking interaction between both pairs of outer phenyl rings. The volatility difference between the two isomers is ruled by the enthalpy of sublimation. The volatility of the 1,2,3-TPhB is two orders of magnitude higher than the 1,3,5-TPhB isomer, at T = 298.15 K.
Empty Cell | ||
1,2,3-Triphenylbenzene (1,2,3-TPhB) | ?12248.2 ± 4.1 | 376.7 ± 5.3 |
1,3,5-Triphenylbenzene (1,3,5-TPhB) | ?12224.6 ± 3.6 | 366.8 ± 4.9 |