Beiträge zur Chemie des Kautschuks,III

Ohne Zusammenfassung     

Beiträge zur Chemie des Kautschuks,VII

Ohne Zusammenfassung     

Detection of Hopf points by counting sectors in the complex plane

Summary. Let ( real) be a family of real by matrices. A value of is called a Hopf value if has a conjugate pair of purely imaginary eigenvalues , . We describe a technique for detecting Hopf values based on the evolution of the Schur complement of in a bordered extension of where varies along the positive imaginary axis of the complex plane. We compare the efficiency of this method with more obvious methods such as the use of the QR algorithm and of the determinant function of as well as with recent work on the Cayley transform. In particular, we show the advantages of the Schur complement method in the case of large sparse matrices arising in dynamical problems by discretizing boundary value problems. The Hopf values of the Jacobian matrices are important in this setting because they are related to the Hopf bifurcation phenomenon where steady state solutions bifurcate into periodic solutions. Received September 15, 1994 / Revised version received July 7, 1995     

Core-edge coupling and the effect of the EDGE on overall plasma performance

Several attempts to model the entire plasma cross section have been reported in the last few years. Two possibilities are to either couple a core code to a scrape-off layer (SOL) code at a specified interface or to extend the computational region of an SOL-code all the way to the plasma centre. The most advanced global code is the code COCONUT which is based on the former principle and comprises the Monte-Carlo code NIMBUS, the 2D scrape-off layer code EDGE2D, the core transport code JETTO and the core impurity transport code SANCO. A main feature of COCONUT is its modular structure which ensures a high degree of flexibility and the capability to cover a large range of time-scales. The influence of the SOL on the core is lllustrated with a range of global simulations carried out with COCONUT. The simulations show that the primary effect of the SOL is the control of the particle sources and sinks with a secondary effect on plasma dilution, radiation and perhaps pedestal temperatures.     

Synthèse dc la pyrido[2,3-f] phtalazine et des diformyl-6,7; -4,6; -4,7; -2,4 quinoleines

This article describes the synthesis of a new heterocycle, pyrido[2,3,f]phtalazine and three new diformylquinolincs.     

An interpretation of the yield behaviour of polymers in terms of correlated motion

An interpretation of yield behaviour in polymers is given in terms of the stress-activated flow of structural units over an energy barrier together with an additional correlated component to the motion. This correlated contribution takes account, in the simplest way possible, of the state of other conformations, and it is shown to lead to an effective activation-energy barrier which depends in part on the strain present at any time in the material. In this manner, the present work relates to previous work by M.G. Brereton, S.G. Croll, R.A. Duckett and I.M. Ward (1974), who, on purely phenomenological grounds, proposed a relation between stress and strain which had the form of a feedback equation. Specifically, the strain resulting from an applied stress was assumed to modify the material in a way which reduced its resistance to stress. The basic equation obtained here is non-linear and shows a yield-like behaviour resulting from a dynamical (as opposed to a geometrical) instability. Furthermore, it indicates a consistent relation between yield in creep tests and in constant strain-rate tests.     

Synthèse des pyrido[2,3-d] el [3,2-d] -s-triazolo[3,4-f] pyrimidines el de (pyrazolyl-1')-4 pyrido[2,3-d] et [3,2-d] pyrimidines

The synthesis of two new heterocycles is described: pyrido-[2,3-d]-.s-triazolo[ 3,4-f] pyrimidine and pyrido[3,2-d]-.s-triayzolo-[3,4-f] pyrimidine. 4-[I'-Pyrazolyl]pyrido[2,3-d]pyrimidines and 4-[1′-pyrazoly1] pyrido[ 3,2-d] pyrimidine are obtained by the action of 4-hydrazinopyrido[2,3-d]pyrimidine and 4-hydrazinopyrido-[3,2-d]pyrimidine with several β-diketones.     

Partitions of the 8‐dimensional vector space over GF(2)

Let V = V(n, q) denote the vector space of dimension n over GF(q). A set of subspaces of V is called a partition of V if every nonzero vector in V is contained in exactly one subspace of V. Given a partition 𝒫 of V with exactly a_i subspaces of dimension i for 1≤i≤n, we have , and we call the n‐tuple (a_n, a_{n − 1}, …, a₁) the type of 𝒫. In this article we identify all 8‐tuples (a₈, a₇, …, a₂, 0) that are the types of partitions of V(8, 2). © 2010 Wiley Periodicals, Inc. J Combin Designs 18: 462–474, 2010     

The developmental pattern of stimulus and response interference in a color-object Stroop task: an ERP study

Background

Several studies have shown that Stroop interference is stronger in children than in adults. However, in a standard Stroop paradigm, stimulus interference and response interference are confounded. The purpose of the present study was to determine whether interference at the stimulus level and the response level are subject to distinct maturational patterns across childhood. Three groups of children (6–7 year-olds, 8–9 year-olds, and 10–12 year-olds) and a group of adults performed a manual Color-Object Stroop designed to disentangle stimulus interference and response interference. This was accomplished by comparing three trial types. In congruent (C) trials there was no interference. In stimulus incongruent (SI) trials there was only stimulus interference. In response incongruent (RI) trials there was stimulus interference and response interference. Stimulus interference and response interference were measured by a comparison of SI with C, and RI with SI trials, respectively. Event-related potentials (ERPs) were measured to study the temporal dynamics of these processes of interference.

Results

There was no behavioral evidence for stimulus interference in any of the groups, but in 6–7 year-old children ERPs in the SI condition in comparison with the C condition showed an occipital P1-reduction (80–140 ms) and a widely distributed amplitude enhancement of a negative component followed by an amplitude reduction of a positive component (400–560 ms). For response interference, all groups showed a comparable reaction time (RT) delay, but children made more errors than adults. ERPs in the RI condition in comparison with the SI condition showed an amplitude reduction of a positive component over lateral parietal (-occipital) sites in 10–12 year-olds and adults (300–540 ms), and a widely distributed amplitude enhancement of a positive component in all age groups (680–960 ms). The size of the enhancement correlated positively with the RT response interference effect.

Conclusion

Although processes of stimulus interference control as measured with the color-object Stroop task seem to reach mature levels relatively early in childhood (6–7 years), development of response interference control appears to continue into late adolescence as 10–12 year-olds were still more susceptible to errors of response interference than adults.