排序方式： 共有103条查询结果，搜索用时 31 毫秒
1.
We obtain cosmological solutions which admit emergent universe (EU) scenario in the framework of Einstein Gauss–Bonnet (GB)
gravity coupled with a dilaton field in 4-dimensions. The coupling parameter of the GB terms and the dilaton in the theory
are determined for obtaining an EU scenario. The corresponding dilaton potential which admits such scenario is determined.
It is found that the GB terms coupled with a dilaton field plays an important role in describing the dynamics of the evolution
of the early as well as the late universe. We note an interesting case where the GB term dominates initially in the asymptotic
past regime, subsequently it decreases and thereafter its contribution in determining the dynamics of the evolution dominates
once again. We note that the Einstein’s static universe solution permitted here is unstable which the asymptotic EU might
follow. We also compare our EU model with supernova data. 相似文献
2.
3.
Rakshit S Grohmann C Besset T Glorius F 《Journal of the American Chemical Society》2011,133(8):2350-2353
An efficient Rh(III)-catalyzed oxidative olefination by directed C-H bond activation of N-methoxybenzamides is reported. In this mild, practical, selective, and high-yielding process, the N-O bond acts as an internal oxidant. In addition, simply changing the substituent of the directing/oxidizing group results in the selective formation of valuable tetrahydroisoquinolinone products. 相似文献
4.
5.
Souvik Sarkar Aritra Sarkar Prof. Dr. Subi J. George 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(45):20013-20017
Stereoselective and temporally controlled supramolecular polymerizations are ubiquitous in nature and are desirable attributes for the design of chiral, well-defined functional materials. Kinetically controlled, living supramolecular polymerization (LSP) has emerged recently for the synthesis of supramolecular polymers with controlled length and narrow dispersity. On the other hand, stringent design requirements for chiral-discriminating monomers precludes the stereoselective control of the supramolecular polymer structure. Herein, a synergetic stereo- and structural control of supramolecular polymerization by the realization of an unprecedented stereoselective seed-induced LSP is reported. Homochiral and seeded growth is demonstrated with bischromophoric naphthalene diimide (NDI) enantiomers with a chiral binaphthyl amine core, exhibiting strong self-recognition abilities and pathway complexity. 相似文献
6.
Dimers of the pyrrole amino acid (Paa), 5-(aminomethyl)pyrrole-2-carboxylic acid, and its derivatives having Lys anchored on N- and C-termini bind in the minor groove of DNA with considerable apparent binding affinities. When the Lys unit is attached to the C-terminus, the resulting ligand binds to ds-DNA with twice the affinity, of the order of 105, than the one carrying two positive charges at the same end. 相似文献
7.
8.
This article designs an efficient two‐class pattern classifier utilizing asynchronous cellular automata (ACAs). The two‐state three‐neighborhood one‐dimensional ACAs that converge to fixed points from arbitrary seeds are used here for pattern classification. To design the classifier, (1) we first identify a set of ACAs that always converge to fixed points from any seeds, (2) each ACA should have at least two but not huge number of fixed point attractors, and (3) the convergence time of these ACAs are not to be exponential. To address the second issue, we propose a graph, coined as fixed point graph of an ACA that facilitates in counting the fixed points. We further perform an experimental study to estimate the convergence time of ACAs, and find there are some convergent ACAs which demand exponential convergence time. Finally, we identify there are 73 (out of 256) ACAs which can be effective candidates as pattern classifier. We use each of the candidate ACAs on some standard datasets, and observe the effectiveness of each ACAs as pattern classifier. It is observed that the proposed classifier is very competitive and performs reliably better than many standard existing classifier algorithms. © 2016 Wiley Periodicals, Inc. Complexity 21: 370–386, 2016 相似文献
9.
C. K. Nisha Sunkara V. Manorama Souvik Maiti K. N. Jayachandran V. K. Aswald P. S. Goyal 《Pramana》2004,63(2):315-320
The interaction of cationic random copolymers of methoxy poly(ethylene glycol) monomethacrylate and (3-(methacryloylamino)propyl) trimethylammonium chloride with oppositely charged surfactant, sodium dodecyl sulphate, and the influence of surfactant association on the polymer conformation have been investigated by small-angle neutron scattering. SANS data showed a positive indication of the formation of RCPSDS complexes. Even though the complete structure of the polyion complexes could not be ascertained, the results obtained give us the information on the local structure in these polymer-surfactant systems. The data were analysed using the log-normal distribution of the polydispersed spherical aggregate model for the local structure in these complexes. For all the systems the median radius and the polydispersity were found to be in the range of 20 ± 2 Å and 0.6 ± 0.05, respectively. 相似文献
10.
Reyhaneh Armin Sebastian Zühlke Gisela Grunewaldt-Stcker Felix Mahnkopp-Dirks Souvik Kusari 《Molecules (Basel, Switzerland)》2021,26(12)
Apple Replant Disease (ARD) is a significant problem in apple orchards that causes root tissue damage, stunted plant growth, and decline in fruit quality, size, and overall yield. Dysbiosis of apple root-associated microbiome and selective richness of Streptomyces species in the rhizosphere typically concurs root impairment associated with ARD. However, possible roles of Streptomyces secondary metabolites within these observations remain unstudied. Therefore, we employed the One Strain Many Compounds (OSMAC) approach coupled to high-performance liquid chromatography-high-resolution tandem mass spectrometry (HPLC-HRMSn) to evaluate the chemical ecology of an apple root-associated Streptomyces ciscaucasicus strain GS2, temporally over 14 days. The chemical OSMAC approach comprised cultivation media alterations using six different media compositions, which led to the biosynthesis of the iron-chelated siderophores, ferrioxamines. The biological OSMAC approach was concomitantly applied by dual-culture cultivation for microorganismal interactions with an endophytic Streptomyces pulveraceus strain ES16 and the pathogen Cylindrocarpon olidum. This led to the modulation of ferrioxamines produced and further triggered biosynthesis of the unchelated siderophores, desferrioxamines. The structures of the compounds were elucidated using HRMSn and by comparison with the literature. We evaluated the dynamics of siderophore production under the combined influence of chemical and biological OSMAC triggers, temporally over 3, 7, and 14 days, to discern the strain’s siderophore-mediated chemical ecology. We discuss our results based on the plausible chemical implications of S. ciscaucasicus strain GS2 in the rhizosphere. 相似文献