全文获取类型
收费全文 | 2051篇 |
免费 | 77篇 |
国内免费 | 8篇 |
专业分类
化学 | 1306篇 |
晶体学 | 57篇 |
力学 | 50篇 |
数学 | 197篇 |
物理学 | 526篇 |
出版年
2023年 | 25篇 |
2022年 | 43篇 |
2021年 | 38篇 |
2020年 | 56篇 |
2019年 | 51篇 |
2018年 | 31篇 |
2017年 | 30篇 |
2016年 | 59篇 |
2015年 | 56篇 |
2014年 | 79篇 |
2013年 | 161篇 |
2012年 | 114篇 |
2011年 | 153篇 |
2010年 | 79篇 |
2009年 | 76篇 |
2008年 | 120篇 |
2007年 | 132篇 |
2006年 | 72篇 |
2005年 | 70篇 |
2004年 | 61篇 |
2003年 | 35篇 |
2002年 | 32篇 |
2001年 | 29篇 |
2000年 | 19篇 |
1999年 | 9篇 |
1998年 | 13篇 |
1997年 | 11篇 |
1996年 | 17篇 |
1995年 | 19篇 |
1994年 | 23篇 |
1993年 | 26篇 |
1992年 | 20篇 |
1991年 | 7篇 |
1990年 | 11篇 |
1989年 | 12篇 |
1988年 | 19篇 |
1987年 | 17篇 |
1986年 | 19篇 |
1985年 | 21篇 |
1984年 | 21篇 |
1983年 | 24篇 |
1982年 | 20篇 |
1981年 | 19篇 |
1980年 | 19篇 |
1979年 | 17篇 |
1978年 | 22篇 |
1977年 | 13篇 |
1976年 | 19篇 |
1974年 | 16篇 |
1973年 | 12篇 |
排序方式: 共有2136条查询结果,搜索用时 15 毫秒
991.
992.
In this paper, peristaltic motion of micropolar fluid in a circular cylindrical flexible tube with viscoelastic or elastic wall properties has been considered. A finite difference scheme is developed to solve the governing equations of motion resulting from a perturbation technique for small values of amplitude ratio. The time mean axial velocity profiles are presented for the case of free pumping and analysed to observe the influence of wall properties for various values of micropolar fluid parameters. In the case of viscoelastic wall, the effect of viscous damping on mean flow reversal at the boundary is seen. 相似文献
993.
994.
995.
In this article we study different properties of convergent, null and bounded sequence spaces of fuzzy real numbers defined
by an Orlicz function, like completeness, solidness, symmetricity, convergence free etc. We prove some inclusion results,
too.
The work of the first author was carried under University Grants Commission of India project No.-F. No. 30-240/2004 (RS). 相似文献
996.
Carbon dots (CDs), a new member of the carbon-based material family, possess unique properties, such as high fluorescence, non-toxicity, eco-friendliness, stability and cost-effectiveness. These properties helped CDs to receive tremendous attention in various fields, namely, biological, opto-electronic, bio-imaging and energy-related applications. Although CDs are widely explored in bio-imaging and bio-sensing applications, their effectiveness in forensic science and technology is comparatively new. In this review, applications of CDs pertaining to latent FPs recovery since 2015 to 2020 is summarized comprehensively. 相似文献
997.
Sujeet K. Chaurasia Rajendra K. Singh S. Chandra 《Journal of Polymer Science.Polymer Physics》2011,49(4):291-300
Polymer electrolytes, (PEO:LiClO4)+x IL (1‐Buty‐3‐methylimidazolium hexafluorophosphate) with varying concentration of IL; x = 0,5,10,15,20 wt % have been prepared by solution cast technique and characterized by X‐Ray diffraction, differential scanning calorimetery, FTIR, conductivity and dielectric relaxation measurements in the frequency range of 100 Hz–5 MHz. Temperature dependence of relaxation frequency and conductivity were found to be typical of thermally activated process both at T > Tm and T < Tm. Composition dependence of conductivity, dielectric relaxation, and degree of crystallinity has also been studied. On addition of IL, the degree of crystallinity after a decrease at 5 wt % IL increases slightly at 10 wt % and then finally decreasing. Variation of conductivity and relaxation frequency with composition could only be partly explained on the basis of variation of degree of crystallinity. An additional feature of ion–ion interaction (contact ion pair formation between IL or salt cations and their associated anions) has been invoked which was supported by FTIR studies. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
998.
Sepay Nayim Sepay Nadir Al Hoque Ashique Mondal Rina Halder Umesh Chandra Muddassir Mohd. 《Structural chemistry》2020,31(5):1831-1840
Structural Chemistry - Novel coronavirus, 2019-nCoV is a danger to the world and is spreading rapidly. Very little structural information about 2019-nCoV make this situation more difficult for drug... 相似文献
999.
Surajit Maity Mridula Guin Dr. Prashant Chandra Singh Prof. G. Naresh Patwari 《Chemphyschem》2011,12(1):26-46
Molecules with multiple hydrogen bonding sites offer the opportunity to investigate competitive hydrogen bonding. Such an investigation can become quite interesting, particularly when the molecule of interest has neither lone‐pair electrons nor strongly acidic/basic groups. Phenylacetylene is one such molecule with three hydrogen bonding sites that cannot be ranked into any known hierarchical pattern. Herein we review the structures of several binary complexes of phenylacetylene investigated using infrared optical double‐resonance spectroscopy in combination with high‐level ab initio methods. The diversity of intermolecular structures formed by phenylacetylene with various reagents is remarkable. The nature of intermolecular interaction with various reagents is the result of a subtle balance between various configurations and competition between the electrostatic and dispersion energy terms, while trying to maximize the total interaction strength. 相似文献
1000.
Facile synthesis of metal–organic framework based on zeolitic imidazolate (ZIF-11) has been optimized to get a material with rho topology. For the first time AgNPs in various dosing amounts (using 150, 300 and 500 μL of its suspension in methanol) have been successfully encapsulated within ZIF-11 matrix at room temperature using binary solvent (methanol and toluene) yielding novel multi-core-shell AgNPs@ZIF-11 (AZ1, AZ2 and AZ3) composites. Encapsulation of AgNPs (particle size: 11.76 ± 2.3 nm) has been confirmed by TEM and ultraviolet diffuse reflectance spectroscopic (UV-DRS) analysis. The lowering of band gap of ZIF-11 from 4.36 to 4.21 eV indicates the micro-environment of AgNPs within ZIF-11 framework, which has also been ensured by XPS analysis. ZIF-11 and AgNPs@ZIF-11 composites are highly stable up to 500 °C under air and N2 atmosphere. It has been found that AZ1 composite exhibits excellent photocatalytic activity (almost 100% degradation) toward MB (1.6 mg/L) at pH ≥ 8. Further, various factors such as loading amount of AgNPs (150, 300 and 500 μL suspension in methanol), amount of catalysts (5 mg, 10 mg and 15 mg) and concentration (1.6 mg L−1, 3.19 mg L−1 and 6.38 mg L−1) of methylene blue (MB) dye during photodegradation experiments have been investigated. The capacious achievement of AZ1 composite is its reusability and recyclability; it can be reutilized up to three cycles with the same efficiency (100%) while under fourth and fifth cycle, it can degrade off 92.12% and 72.75% MB, respectively. AgNPs may act as a mediator to promote the quick transfer of photo-induced electrons and electron–hole pairs separation in ZIF-11. This work opens a new type of easily fabricated core-shell composites utilizing ZIF-11 for wastewater remediation process. 相似文献