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121.
Consider a time-varying collection of n points on the positive real axis, modeled as Exponentials of n Brownian motions whose drift vector at every time point is determined by the relative ranks of the coordinate processes at that time. If at each time point we divide the points by their sum, under suitable assumptions the rescaled point process converges to a stationary distribution (depending on n and the vector of drifts) as time goes to infinity. This stationary distribution can be exactly computed using a recent result of Pal and Pitman. The model and the rescaled point process are both central objects of study in models of equity markets introduced by Banner, Fernholz, and Karatzas. In this paper, we look at the behavior of this point process under the stationary measure as n tends to infinity. Under a certain ‘continuity at the edge’ condition on the drifts, we show that one of the following must happen: either (i) all points converge to 0, or (ii) the maximum goes to 1 and the rest go to 0, or (iii) the processes converge in law to a non-trivial Poisson–Dirichlet distribution. The underlying idea of the proof is inspired by Talagrand’s analysis of the low temperature phase of Derrida’s Random Energy Model of spin glasses. The main result establishes a universality property for the BFK models and aids in explicit asymptotic computations using known results about the Poisson–Dirichlet law.  相似文献   
122.
Random overlap structures (ROSt’s) are random elements on the space of probability measures on the unit ball of a Hilbert space, where two measures are identified if they differ by an isometry. In spin glasses, they arise as natural limits of Gibbs measures under the appropriate algebra of functions. We prove that the so called ‘cavity mapping’ on the space of ROSt’s is continuous, leading to a proof of the stochastic stability conjecture for the limiting Gibbs measures of a large class of spin glass models. Similar arguments yield the proofs of a number of other properties of ROSt’s that may be useful in future attempts at proving the ultrametricity conjecture. Lastly, assuming that the ultrametricity conjecture holds, the setup yields a constructive proof of the Parisi formula for the free energy of the Sherrington–Kirkpatrick model by making rigorous a heuristic of Aizenman, Sims and Starr.  相似文献   
123.
We prove that first-passage percolation times across thin cylinders of the form [0, n] × [?h n , h n ] d-1 obey Gaussian central limit theorems as long as h n grows slower than n 1/(d+1). It is an open question as to what is the fastest that h n can grow so that a Gaussian CLT still holds. Under the natural but unproven assumption about existence of fluctuation and transversal exponents, and strict convexity of the limiting shape in the direction of (1, 0, . . . , 0), we prove that in dimensions 2 and 3 the CLT holds all the way up to the height of the unrestricted geodesic. We also provide some numerical evidence in support of the conjecture in dimension 2.  相似文献   
124.
    
Xuan Li  Sourav Dutta 《Molecular physics》2013,111(23):3854-3858
We extend our recently developed inversion method to extract excited-state potentials from fluorescence line positions and line strengths. We consider a previous limitation of the method arising due to insufficient input data in cases where the relatively weaker emission data are not experimentally available. We develop a solution to this problem by ‘regenerating’ these weak transition lines via applying a model potential, e.g. a Morse potential. The result of this procedure, illustrated for the Q-branch emission from the lowest three vibrational levels of the B(1Π) state of LiRb, is shown to have an error of 0.29 cm?1 in the classically allowed region and a global error of 5.67 cm?1 for VE(ν′ = 10). The robustness of this procedure is also demonstrated by considering the statistical error in the measured line intensities.  相似文献   
125.
    
In this paper, we report on the concept and the design principle of ultrafast Raman loss spectroscopy (URLS) as a structure‐elucidating tool. URLS is an analogue of stimulated Raman scattering (SRS) but more sensitive than SRS with better signal‐to‐noise ratio. It involves the interaction of two laser sources, namely, a picosecond (ps) Raman pump pulse and a white‐light (WL) continuum, with a sample, leading to the generation of loss signals on the higher energy (blue) side with respect to the wavelength of the Raman pump unlike the gain signal observed on the lower energy (red) side in SRS. These loss signals are at least 1.5 times more intense than the SRS signals. An experimental study providing an insight into the origin of this extra intensity in URLS as compared to SRS is reported. Furthermore, the very requirement of the experimental protocol for the signal detection to be on the higher energy side by design eliminates the interference from fluorescence, which appears on the red side. Unlike CARS, URLS signals are not precluded by the non‐resonant background and, being a self‐phase‐matched process, URLS is experimentally easier. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
126.
    
A facile synthesis route is described for the preparation of a gold–polyaniline nanocomposite material. The gold nanoparticles were highly dispersed and stabilized throughout the polyaniline fibers that formed a metal–polymer composite material. We measured the temperature‐dependent electrical conductivity of the metal–polymer composite material. The conductivity data are commensurate with the one‐dimensional geometry of the resultant material. The temperature dependence of the Hall coefficient on the composite is in evidence of a possible contribution of a charge carrier deficit and a temperature‐dependent mobility in this material.  相似文献   
127.
    
MnO2 thin films are prepared by thermal evaporation technique onto glass substrate at varying deposition pressures. Electrical studies of the films deposited at about 1.99 × 10−3 Pa show a positive temperature coefficient of resistance (TCR) indicating a metallic characteristics, whereas a negative TCR indicating semiconducting behavior is exhibited by the films deposited at a pressure of about 1.73 × 10−4 Pa. Thickness dependent electrical conductivity, activation energy, aging effect are also investigated, and the thickness dependent conductivity is well in conformity with the Fuchs-Sondheimer theory. These pressure dependent studies may be of importance for the application of this material in energy efficient surface coating devices.  相似文献   
128.
129.
We present an unconditionally-secure key pre-distribution scheme for a wireless sensor network using t-degree bivariate polynomials. The proposed scheme is proven to be perfectly resilient against both node disconnection and link failure. The memory requirements, computation and communication overheads of our scheme are also favorable. Our scheme demonstrates superior performance compared to the existing similar schemes.  相似文献   
130.
The complex absorbing potential along with correlated independent particle potential (CIP) Fock space multireference coupled cluster method is used for the study of resonances. We have studied shape resonance of e?‐ F2, e?‐ N2O and e?‐CO molecules. In particular, we have studied e?‐ F2 scattering at different bond lengths to know whether is bound at the equilibrium bond length of F2. © 2013 Wiley Periodicals, Inc.  相似文献   
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