全文获取类型
收费全文 | 982篇 |
免费 | 42篇 |
国内免费 | 2篇 |
专业分类
化学 | 597篇 |
晶体学 | 3篇 |
力学 | 39篇 |
数学 | 80篇 |
物理学 | 307篇 |
出版年
2023年 | 15篇 |
2022年 | 26篇 |
2021年 | 21篇 |
2020年 | 37篇 |
2019年 | 41篇 |
2018年 | 26篇 |
2017年 | 17篇 |
2016年 | 44篇 |
2015年 | 33篇 |
2014年 | 53篇 |
2013年 | 96篇 |
2012年 | 82篇 |
2011年 | 76篇 |
2010年 | 46篇 |
2009年 | 36篇 |
2008年 | 43篇 |
2007年 | 60篇 |
2006年 | 30篇 |
2005年 | 33篇 |
2004年 | 17篇 |
2003年 | 14篇 |
2002年 | 11篇 |
2001年 | 6篇 |
2000年 | 4篇 |
1999年 | 7篇 |
1998年 | 6篇 |
1997年 | 6篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 7篇 |
1992年 | 8篇 |
1991年 | 4篇 |
1990年 | 8篇 |
1989年 | 9篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 7篇 |
1985年 | 10篇 |
1984年 | 11篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1981年 | 10篇 |
1980年 | 9篇 |
1979年 | 8篇 |
1978年 | 4篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1974年 | 2篇 |
1939年 | 3篇 |
排序方式: 共有1026条查询结果,搜索用时 15 毫秒
111.
Animesh K. Ojha Sunil K. Srivastava S. Schlücker W. Kiefer B. P. Asthana Ranjan K. Singh 《Journal of Raman spectroscopy : JRS》2007,38(12):1656-1664
A concentration‐dependent Raman study of the ν(C Br) stretching and trigonal bending modes of 2‐ and 3‐Br‐pyridine (2Br‐p and 3Br‐p) in CH3OH was performed at different mole fractions of the reference molecule, 2Br‐p/3Br‐p, from 0.1 to 0.9 in order to understand the origin of blue/red wavenumber shifts of the vibrational modes due to hydrogen‐bond formation. The appearance of additional Raman bands in these binary systems at ∼617 cm−1in the case of 2Br‐p and at ∼618 cm−1 in the case of 3Br‐p compared to neat bromopyridine derivatives were attributed to specific hydrogen‐bonded complexes formed in the mixtures. The interpretation of experimental results is supported by density functional calculations on optimized geometries and vibrational wavenumbers of 2Br‐p and 3Br‐p and a series of hydrogen‐bonded complexes with methanol. The parameters obtained from these calculations were used for a qualitative explanation of the blue/red shifts. The wavenumber shifts and linewidth changes for the ν(C Br) stretching and trigonal bending modes as a function of concentration reveal that the caging effects leading to motional narrowing and diffusion‐causing line broadening are simultaneously operative, in addition to the blue shift caused due to hydrogen bonding. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
112.
B. K. Rao S. N. Khanna P. Jena 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1986,3(2):219-222
The equilibrium geometries, relative stabilities, and vertical ionization potentials of compound clusters involving Li n , Na, Mg, and Al atoms have been calculated using ab initio self-consistent field linear combination of atomic orbitals — molecular orbital (SCF-LCAO-MO) method. The exchange energies are calculated exactly using the unrestricted Hartree-Fock (UHF) method whereas the correlation correction is included within the framework of configuration interaction involving pair excitations of valence electrons. While the later correction has no significant effect on the equilibrium geometries of clusters, it is essential for the understanding of relative stabilities. Clusters with even numbers of electrons are found to be more stable than those with odd numbers of electrons regardless of their charge state and atomic composition. The equilibrium geometries of homo-nuclear clusters can be significantly altered by replacing one of its constituent atoms with a hetero-nuclear atom. The role of electronic structure on the geometries and stabilities of compound clusters is discussed. 相似文献
113.
Soumya Chakrabarti 《General Relativity and Gravitation》2017,49(2):24
An analogue of the Oppenheimer–Synder collapsing model is treated analytically, where the matter source is a scalar field with an exponential potential. An exact solution is derived followed by matching to a suitable exterior geometry, and an analysis of the visibility of the singularity. In some situations, the collapse indeed leads to a finite time curvature singularity, which is always hidden from the exterior by an apparent horizon. 相似文献
114.
Yashwantsinh S. Jadeja Khushal M. Kapadiya Hetal J. Jebaliya Anamik K. Shah Ranjan C. Khunt 《Magnetic resonance in chemistry : MRC》2017,55(6):589-594
Hesperidin is flavonoid molecule found in citrus fruits (Citrus reticulata), especially difficult to extract, classify and characterize. Present work is to study the unresolved relative configuration of Hesperidin through the dihedral angle, coupling constant and different NMR techniques. The Karplus equation and its modifications have been originated from the valence bond theory and associated with dihedral angle and coupling constant. The result data set of calculated dihedral angle can probe significant method to assign the virtual configuration of natural products and also resolved stereochemistry of Hesperidin at C‐2 position in. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
115.
116.
Bradley A. Ochs Dan Fries Devesh Ranjan Suresh Menon 《Flow, Turbulence and Combustion》2018,101(3):927-951
It is unclear whether turbulent flame speed scalings established in low speed regimes are applicable to supersonic flames. To investigate this question, the canonical flame kernel is investigated in a scramjet-like channel having a one degree wall divergence. The growth, shape and internal kernel dynamics are investigated. Results are presented for three Mach numbers, four equivalence ratios, and three turbulence generators. Schlieren photography provides flame images for growth rate statistics and particle image velocimetry (PIV) provides turbulence statistics and investigation of internal kernel dynamics. Supersonic flame kernels are self-propagating and respond to the equivalence ratio in a fashion that is similar to low speed flames. However, supersonic flame kernels have features that are not present in subsonic flame kernels. Baroclinicity, resulting from pressure-density misalignment, creates a reacting vortex ring structure. Further, the mean kernel shape has a Mach number dependence and the vortex ring enhances the turbulent flame speed through entrainment of reactants and augmented flame surface growth. Hence, the previously established (low speed) flame speed scalings are inappropriate for supersonic flame kernels. Drawing motivation from vortex ring literature, the ring propagation velocity is used as the characteristic velocity and a new flame speed scaling is proposed. 相似文献
117.
P.?TudiscoView authors OrcID profile R.?Ranjan S.?MenonEmail author 《Flow, Turbulence and Combustion》2018,101(1):55-76
The time-domain impedance boundary condition (TDIBC) is used as a reduced-order model (ROM) in large-eddy simulation (LES) to study self-sustained transverse oscillations in an experimentally studied high-pressure, shear coaxial multi-injector combustor. This work is an extension of the recent study using ROM-LES to simulate a single-element combustor that exhibited longitudinal instability. Here, we focus on transverse instability in a seven-injector combustor. The fuel and oxidizer inlets are truncated and the conventional inflow boundary conditions at the original inlet are replaced by an impedance describing function (IDF) in the form of a reflection coefficient that couples with LES through characteristic based boundary conditions at the truncated inlet. The impedance model is also generalized to include the effects of entropy fluctuations at the inflow. The hybrid ROM-LES simulations are compared with LES simulations with the full combustor geometry. Results show very good agreement and confirm that the use of TDIBC within LES is a viable tool to account for complex acoustic/boundary interaction in a physical way without explicitly solving the full geometry at LES level. Some simplifications and approximations have to be invoked and these constraints are also discussed. 相似文献
118.
In this paper we report a new method of fabrication of surface tensionconfined microfluidic devices on glass. We have also
successfully carried out some well-known chemical reactions in these fluidic channels to demonstrate the usefulness of these
wall-less microchannels. The confined flow path of liquid was achieved on the basis of extreme differences in hydrophobic
and hydrophilic characters of the surface. The flow paths were fabricated by making parallel lines using permanent marker
pen ink or other polymer on glass surfaces. Two mirror image patterned glass plates were then sandwiched one on top of the
other, separated by a thin gap-created using a spacer. The aqueous liquid moves between the surfaces by capillary forces,
confined to the hydrophilic areas without wetting the hydrophobic lines, achieving liquid confinement without physical side-walls.
We have shown that the microfluidic devices designed in such a way can be very useful due to their simplicity and low fabrication
cost. More importantly, we have also demonstrated that the minimum requirement of such a working device is a hydrophilic line
surrounded by hydrophobic environment, two walls of which are constituted of air and the rest is made of a hydrophobic surface. 相似文献
119.
Prediction and simulation of wear response of Linz–Donawitz (LD) slag filled glass–epoxy composites using neural computation 下载免费PDF全文
This article reports on the implementation of a soft computing technique based on artificial neural networks (ANNs) in analyzing the wear performance of a new class of hybrid composites filled with Linz–Donawitz slag (LDS). LDS is a major solid waste generated in huge quantities during steel making. It comes from slag formers such as burned lime/dolomite and from oxidizing of silica, iron etc. while refining the iron into steel in the LD furnace. In this work, hybrid composites consisting of short glass fiber (SGF) reinforced epoxy filled with different LDS content (0, 7.5, 15 and 22.5 wt%) are prepared by simple hand lay‐up technique. Solid particle erosion trials, as per ASTM G 76 test standards, are conducted on the composite samples following a well‐planned experimental schedule based on Taguchi design of experiments. Significant process parameters predominantly influencing the rate of erosion are identified. The study reveals that the LDS content is the most significant among various factors influencing the wear rate of these composites. Further, a model based on ANN for the prediction of erosion performance of these composites is implemented. The ANN prediction profiles for the characteristic wear properties exhibit very good agreement with the measured results demonstrating that a well‐trained network has been created. The simulated results explaining the effect of significant process variables on the wear rate indicate that the trained neural network possesses enough generalization capability of predicting wear rate even beyond the experimental range. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
120.
Om Prakash Shiv Kumar Pushkar Singh Volker Deckert S. Chatterjee A.K. Ghosh Ranjan K. Singh 《Journal of Raman spectroscopy : JRS》2016,47(7):813-818
Interest in the synthesis of hybrid substrates for surface‐enhanced Raman scattering (SERS) has surged recently. Hereof, in the present work, a hybrid SERS substrate CuO : Mn/Ag heterojunction has been synthesised. To accomplish this, the nanostructred Ag island film and CuO : Mn nanoparticles are synthesised by vacuum thermal evaporation method and sol–gel method respectively, and thereafter, a heterojunction between the CuO : Mn and Ag is fabricated by adsorption of CuO : Mn (10‐3 m in ethanol) on Ag island film. Further, the SERS sensitivity of CuO : Mn/Ag heterojunctions has been studied by probing methyl orange. We observed that with Mn‐doping in the lattice of CuO, the SERS signal is enhanced considerably because of ferromagnetic ordering in CuO : Mn. DFT/B3LYP/6‐311 G(d, p) method is used to calculate the energy of HOMO and LUMO level of methyl orange. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献