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51.
Annals of Operations Research - 相似文献
52.
53.
Coupled-channels calculations have been carried out for pion inelastic scattering and charge exchange on 1p-shell nuclei at pion energies between 120 and 226 MeV. A momentum space technique is used, with the 1p-shell shell-model wavefunctions of Cohen and Kurath. Results are presented here for A=13. Channel-coupling effects are negligible in the strong 3/2- and 5/2- inelastic excitations of 13C, but enhance the analog charge-exchange cross sections by 7 to 20%. 相似文献
54.
We prove that the “naive” convolution Dirichlet series $D_{2}(s)$ attached to a degree 2 Siegel Hecke cusp form $F$ , has a pole at $s=1$ . As an application, we write down the asymptotic formula for the partial sums of the squares of the eigenvalues of $F$ with an explicit error term. Further, as a corollary, we are able to show that the abscissa of absolute convergence of the (normalized) spinor-zeta function attached to $F$ is $s = 1$ . 相似文献
55.
Soumya Sasmal Vaibhav V. Goud Kaustubha Mohanty 《Journal of Thermal Analysis and Calorimetry》2013,111(3):1649-1655
Fuels derived from biomass are renewable as well as environment friendly. In this study, three biomasses viz. husk of areca nut (Areca catheu), trunks of moj (Albizzia lucida), and bon bogori (Ziziphus rugosus) available in North-East region of India were tested as potential biofuel sources. The accentuation of this study was to determine the kinetic parameters using thermogravimetric (TG) technique under air and nitrogen atmosphere. The experiments were carried out within temperature range 300–973 K under air and nitrogen atmosphere at four different heating rates viz. 5, 10, 15, and 20 K min?1, respectively. The mass losses at different lumps in the TG graphs were estimated. The first-order kinetic parameters such as activation energy and pre-exponential factor were calculated for different reaction zones for all the three biomass samples. Effects of atmosphere on combustion characteristics (e.g., peak temperature, ignition temperature, and reactivity index) of biomasses were also determined in this study. Areca nut husk has highest ignition temperature (526.38 K) and reactivity index (0.21) but moj has highest peak temperature (597.91 K) along with highest activation energy (348.04 kJ mol?1) and pre-exponential factor (1.12 × 1024 min?1), respectively. 相似文献
56.
We report experimental implementation of a protocol for testing the Leggett-Garg inequality (LGI) for nuclear spins precessing in an external magnetic field. The implementation involves certain controlled operations, performed in parallel on pairs of spin-1/2 nuclei (target and probe) from molecules of a nuclear magnetic resonance ensemble, which enable evaluation of temporal correlations from an LG string. Our experiment demonstrates violation of the LGI for time intervals between successive measurements, over which the effects of relaxation on the quantum state of target spin are negligible. Further, it is observed that the temporal correlations decay, and the same target spin appears to display macrorealistic behavior consistent with LGI. 相似文献
57.
Ampa Jimtaisong Linsheng Feng Soumya Sreehari Craig A. Bayse Rudy L. Luck 《Journal of Cluster Science》2008,19(1):181-195
Reacting MoO2(acac)2 with Ph2POOH or Me2POOH in EtOH results in the formation of the tetranuclear molybdenum (V) clusters Mo4(μ
3-O)4(μ-O2PR2)4O4, PR2 = PPh2, 1, or PMe2, 2, in functional yields (>90% and 55% respectively). The reaction of WO2(acac)2 with Ph2POOH in MeOH affords the tungsten dimer [(CH3O)2(O)W(μ-O)(μ-O2PPh2)2W(O)(CH3O)2], 3. The single crystal X-ray determined structures of complexes 1–3 are reported. In 1 and 2, the four Mo=O units are interconnected by four triply bridging oxygen atoms, resulting in a distorted cubic-like structure
for the Mo4(μ
3-O)4O4 units. Each molybdenum atom forms two additional Mo–O bonds with two oxygen atoms from different adjacent phosphinato ligands.
Complex 3, a tungsten dimer, contains packing disorder and consists of bridging oxo and diphenylphosphinato ligands. The bonding of
1 and 2 assessed by density-functional methods showed that bonding between the Mo(V) centers occurs through σ overlap of the d
xy
orbitals.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
Dedicated to the memory of Professor F. A. Cotton. Veritas numquam perit. 相似文献
58.
AbstractThe spineless cuttlefish Sepiella inermis encompasses a major share in the marine fisheries sector, and represents as a culinary delicacy in many cultures. Bioactivity-guided fractionation of methanol:ethyl acetate (MeOH:EtOAc, 1:1) extract of the edible parts of the species ensued in identification of two hexahydro chromenyl analogues namely, methyl 7-ethyl-hexahydro-8a-methyl-2H-chromene-4-carboxylate (1) and methyl 1-acetoxy-hexahydro-3-methyl-3-propyl-1H-isochromene-4-carboxylate (2). The isolated metabolites were checked for their radical scavenging and anti-inflammatory potentials by selective in vitro models. The isochromenyl derivative exhibited potential 2,2-diphenyl-1-picryl-hydrazil and 2,2′-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (IC50?<?0.45?mg mL?1) radical-scavenging capacities along with pro-inflammatory cyclooxygenase-2 (COX-2) (IC50 0.75?mg mL?1) and 5-lipoxygenase (5-LOX) (IC50 0.77?mg mL?1) inhibitory activities. The titled compounds displayed the selectivity indices (IC50 anti-COX-1/IC50 anti-COX-2) greater than 1.25, in comparison with synthetic anti-inflammatory drug ibuprofen (0.44), which attributed to their greater selectivity towards inducible pro-inflammatory enzyme COX-2. 相似文献
59.
Ben. J. Tickner Dr. Wissam Iali Dr. Soumya S. Roy Dr. Adrian C. Whitwood Prof. Simon B. Duckett 《Chemphyschem》2019,20(2):241-245
The formation and hyperpolarization of an [Ir(H)2(amine)(IMes)(η2-imine)]Cl complex that can be created in a hyperpolarized nuclear singlet state is reported. These complexes are formed when an equilibrium mixture of pyruvate, amine (benzylamine or phenylethylamine), and the corresponding imine condensation product, react with preformed [Ir(H)2(amine)3(IMes)]Cl. These iridium α-carboxyimine complexes exist as two regioisomers differentiated by the position of amine. When examined with para-hydrogen the hydride resonances of the isomer with amine trans to hydride become strongly hyperpolarized. The initial hydride singlet states readily transfer to the corresponding 13C2 state in the labelled imine and exhibit magnetic state lifetimes of up to 11 seconds. Their 13C signals have been detected with up to 420 fold signal gains at 9.4 T. On a longer timescale, and in the absence of H2, further reaction leads to the formation of neutral carbonate containing [Ir(amine)(η2-CO3)(IMes)(η2-imine)]. Complexes are characterized by, IR, MS, NMR and X-ray diffraction. 相似文献
60.
Soumya S. Patnaik Ruth Pachter Timothy J. Bunning Robert L. Crane W. Wade Adams 《Liquid crystals》1994,16(6):911-923
A molecular simulation study of a cyclic siloxane macromolecule based on a pentamethylcyclosiloxane core and biphenylyl 4-allyloxybenzoate mesogenic units is reported. Molecular dynamics and semi-empirical calculations were used to provide insight into the conformation and the dielectric properties of the material. Out of three proposed conformations of the molecules, a cylindrical conformation was found to be the most probable. The intermolecular interactions were found to be optimized for the case where the mesogenic groups were planar and parallel to each other. The calculated mesogen length and inter-mesogen distances were consistent with available X-ray data. Electrostatic interactions were found to make a very significant contribution to the total energy. For the cylindrical model, the major component of the dipole was calculated to be along the long axis of the molecules. This is consistent with the alignment of the molecules parallel to a low frequency applied electric field as found experimentally. 相似文献