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71.
Yuki Arakawa Hiroki Kuwahara Masatoshi Tokita Gen-ichi Konishi Hideto Tsuji 《Molecular Crystals and Liquid Crystals》2018,662(1):197-207
ABSTRACTWe present a new fabrication approach to achieve a high birefringence film by means of photopolymerization based on an alkylthio-containing rod-like liquid crystalline molecule exhibiting large temperature dependence of birefringence. We designed a new reactive mesogen having alkylthio linkages (BPM–S). It was found that BPM–S had a larger increment of birefringence with decreasing temperature, relative to commercially available alkoxy analog LC242. This result could be thought to be due to enhanced intermolecular attractive interaction for an alkylthio mesogen implied by the proximity of laterally neighboring molecules and cybotactic nematic tendency based on wide-angle X-ray measurement. The uniaxially-aligned photo-polymerized film for BPM–S showed higher birefringence than that for LC 242. 相似文献
72.
73.
Ohkita M Kawano M Suzuki T Tsuji T 《Chemical communications (Cambridge, England)》2002,(24):3054-3055
The crystallization of 2,4,6-triethynyl-1,3,5-triazine (2) leads to a pi-stacked layered structure of a C(sp)-H...N hydrogen-bonded unique hexagonal network structure, which may be regarded as a supramolecular analogue of a hitherto unknown graphyne network: in-plane intermolecular interactions are short and linear H...N contacts (2.31 and 2.34 A) and the interlayer separation is 3.23 A. 相似文献
74.
The synthesis of MoVNbTe(Sb)O(x)() composite oxide catalysts based on the self-organization of polyoxometalates (POMs) was investigated. The catalysts which were synthesized via reduction of POMs by using reducing agents under mild conditions and/followed by calcination in an O(2)-excluded atmosphere which superior performance for propane (amm)oxidation. It was suggested that the metastable phase formed at an elevated temperature with a specific oxidation state corresponds to the catalytic activity. 相似文献
75.
Different types of finite element methods (FEMs) for microwave and optical waveguides are reviewed and are utilized for modeling of a traveling-wave (TW) optical modulator, as one of the typical microwave photonic devices. Using the quasi-TEM and the full-wave vector FEM solvers for microwave waveguides and the scalar FEM solver for optical waveguides, the behaviour of a TW Z-cut Ti:LiNbO3 Mach–Zehnder optical modulator with a ridge structure is investigated. 相似文献
76.
S. Tsuji I.S.T. Tsong S.V. Krishnaswamy 《Spectrochimica Acta Part B: Atomic Spectroscopy》1981,36(10):1005-1014
Spectral scans of 12 metals: Al, Co, Cr, Cu, Fe, Mg, Mo, Ni, Pd, Si, Ti and W under Ar+ ion bombardment have been taken with and without backfilled oxygen in the target chamber to study the effect of oxygen on the emission of continuum radiation. Some of the observed broad band features can be attributed to sputtered metal-oxide molecular emission while other continua remain unidentified. In all cases except Pd, increasing the partial pressure of oxygen enhances the continuum emission. 相似文献
77.
Zearalenone was synthesized by a general cyclization method of orsellic acid type macrolides having ketone moiety using the intramolecular alkylation of the protected cyanohydrin. This alkylation tolerates the presence of ester group and requires short reaction time. 相似文献
78.
Jiro Tsuji Yuichi Kobayashi Hideaki Kataoka Takashi Takahashi 《Tetrahedron letters》1980,21(35):3393-3394
2-Substituted 2-alkoxycarbonyl-3-vinylcyclopentanones (2), easily prepared by the palladium-catalyzed cyclization of 2-substituted 3-oxo-8-phenoxy-6-octenoates (1), are very suitable building blocks for CD rings of steroids, bearing particularly a functionalized 18-methyl group. 相似文献
79.
80.