Development of high resolution resonance ionization mass spectrometry for trace analysis of 93mNb

⁹³Nb(n, n′)^93mNb reaction allows retrospective estimation of integrated fast neutron dose in nuclear reactor. We proposed isomer-selective trace analysis of ^93mNb by Resonance Ionization Mass Spectrometry (RIMS) combined with a gas-jet atomic source and an injection locked Ti:Sapphire laser system operated at several kHz. Resonant ionization spectroscopy of Nb in gas-jet using Ti:Sapphire laser was demonstrated.     

Achievement of a 920-MHz high resolution NMR

We have developed a 920-MHz NMR system and performed the proton NMR measurement of H(2)O and ethylbenzene using the superconducting magnet operating at 21.6 T (920 MHz for proton), which is the highest field produced by a superconducting NMR magnet in the persistent mode. From the NMR measurements, it is verified that both homogeneity and stability of the magnet have a specification sufficient for a high resolution NMR.     

Noise waveforms with repetitive phase and nonrepetitive amplitude

By use of frequency-shifted feedback lasers, noise with a stationary amplitude and a periodically stationary phase is generated. The ensemble-averaged time correlation function is periodic, whereas the power spectrum is broadband, resulting in a waveform that does not obey the Wiener-Khintchine relations. An application to multiple-access communications is discussed.     

Effect of controlling optical wavelength by spectacle lenses on visual quality

Optical Review - In this study, the effects of selectively yellow-cut lenses on contrast sensitivity were investigated in healthy young and middle-aged individuals and elderly patients with...     

From optical spectroscopy to a concentration quenching model and a theoretical approach to laser optimization for Yb3+-doped YLiF4 crystals

A spectroscopic characterization was carried out to identify crystal-field levels for magnetic-dipole transitions of Yb³⁺ ions located in the Y³⁺ dodecahedral S₄ crystallographic site in YLiF₄ (YLF) crystals which were grown either by the Czochralski technique or by the laser heated pedestal growth (LHPG) technique. The concentration dependence of the measured decay time of the ²F_5/2 excited level of Yb³⁺ was analysed in order to understand relevant concentration quenching mechanisms. Under Yb³⁺ ion infrared pumping, self-trapping and up-conversion non-radiative energy transfer to trace rare-earth impurities (Er³⁺, Tm³⁺) has been observed over the visible region and interpreted by a limited-diffusion process within the Yb³⁺ doping ion subsystem to the impurities. The principal parameters useful for a theoretical approach for potential laser applications of Yb³⁺-doped YLiF₄ crystals have also been given.     

Semiconductor diamond heater in the Kawai multianvil apparatus: an innovation to generate the lower mantle geotherm

Semiconductor diamond is considered the best heater material to generate ultra-high temperatures in a Kawai cell. In two pioneering studies, a mixture of graphite and amorphous boron (or boron carbide, B₄C) was converted to semiconductor diamond in the diamond stability field and was confirmed to generate 2000°C and 3500°C, respectively. Following these works, we synthesized a homemade boron-doped graphite block with fine machinability. With this technical breakthrough, we developed a semiconductor diamond heater in a smaller Kawai-type cell assembly. Here, we report the procedure for making machinable boron-doped graphite, and the performance of the material as a heater in a Kawai cell at 15?GPa using tungsten carbide anvils and at ～50?GPa using sintered diamond anvils. Furthermore, we present a finite element simulation of the temperature distribution generated by a semiconductor diamond heater, which is much more homogeneous than that generated by a metal heater.     

Systematics of Mössbauer parameters in Fe57-doped titanate and germanate ilmenites

The Mössbauer spectra of ilmenite (FeTiO₃), Fe²⁺-doped ilmenites, MTiO₃ (M = Cd, Mn, Zn, Co, Mg and Ni) and MGeO₃ (M = Mn, Zn and Mg), have been studied from 4.2 K to room temperature. Systematic variations in the isomer shift and quadrupole splitting at room temperature are correlated with the change in ionic radii of the host M ions and the c/a ratio of the host crystal, respectively. The quadrupole splittings show a remarkable temperature variation; the magnetic ilmenites show either a sudden increase or a sudden decrease of quadrupole splittings below the Néel temperature, depending on the orientation of the spin axis with respect to the c axis.     

Size distribution of fractured areas in one-dimensional systems

We study a one-dimensional model for fracture, identifying fractured areas with intervals on which a stress field exceeds a threshold value. When is a diffusion process, the cumulative numberN(l) of fractured areas whose length is greater thanl obeys a power lawCl ^–p asl0 with probability one. The exponentp and the constantC are determined. The exponentp agrees with the Hausdorff dimension of the end points of fractured areas, i.e., ^–1(). Even if is self-similar with parameterH>0, i.e.,(cx)– is equivalent toc ^H {(x)–} for anyc>0, the exponentp does not depend solely onH;p=H, where(0, 1/H) is another parameter characterizing. Non-diffusion processes are given whereN(l) does not follow a power law.     

Canonical linear transformation on fock space with an indefinite metric

We first construct a Fock space with an indefinite metric ,=( , ), where is a unitary and Hermitian operator. We define a -selfadjoint (Segal's) field (f) which obeys the canonical commutation relations (CCR) with an indefinite metric. We consider a transformation 349-2 (T = real linear) which leaves the CCR invariant. We investigate the implementability of T by an operator on the Fock space.