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991.
M. Muller S. Bourbigot S. Duquesne R. Klein G. Giannini C. Lindsay J. Vlassenbroeck 《Polymer Degradation and Stability》2013
The morphology of carbonized materials resulting from an intumescence phenomenon was studied. The investigated material is a polyurethane matrix filled either by 30 wt.-% of ammonium polyphosphate or by a combination of 28 wt.-% of ammonium polyphosphate and 2 wt.-% of nano-magnesium oxide. These fillers were incorporated in the polyurethane directly during the synthesis step. The carbonized materials or char, are obtained in a specific fire scenario. Characterization of their morphology is carried out using X-ray computed tomography. The heat conductivity of the systems is additionally measured as a function of temperature in order to correlate structure and properties of the intumescent residues. The formation of different char structures with incorporation of magnesium oxide (in particular formation of bubbles of different size) is first evidenced. These observations are consistent with the heat conductivity data. Tomography images demonstrate that the intumescence process is a dynamic process since non degraded polymer is left at the beginning of the fire test, which is not the case for longer time. The dispersion of fillers has finally been investigated in the chars and it is evidenced different steps of intumescence's development in the material. 相似文献
992.
Sarah Coffinet Ahmad Rifai Christophe Genty Yasmine Souissi Sophie Bourcier Michel Sablier Stéphane Bouchonnet 《Journal of mass spectrometry : JMS》2012,47(12):1582-1593
Aqueous solutions of metolachlor and metolachlor‐d6 were photolyzed with UV‐visible radiations. The structures of 15 by‐products of metolachlor were determined through gas chromatography‐mass spectrometry analyses using electron and chemical ionization combined with multistage mass spectrometry. The photolysis by‐products of metolachlor resulted mainly from dehalogenation and hydroxylation, in some cases accompanied by cyclization. In silico tests for toxicity prediction showed that the toxicity of some photolysis products is expected to be greater than that of metolachlor. Persistence studies showed that the by‐product relative abundances vary in large amounts with the irradiation time. The post‐photolysis evolution of the solution was also studied, in order to determine the persistence of the main by‐products. It allowed to establish that most of the by‐products can be found more than 12 h after the end of the photolysis, which is of a great concern as treated water is generally available for consumption only a few hours after treatment in most of industrial processes. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
993.
Stéphane Bouchonnet Christophe Genty Sophie Bourcier Michel Sablier 《Rapid communications in mass spectrometry : RCM》2010,24(7):973-978
With the future aim of using gas chromatography coupled with mass spectrometry to characterize the transformation products of estrone submitted to UV‐photolysis or to waste water treatment plants, an interpretation of the electron impact mass spectrum of estrone is presented. Fragmentation mechanisms are proposed on the basis of high‐resolution measurements performed with a magnetic sector analyzer. Multiple‐stage mass spectrometry experiments were carried out using an ion trap mass spectrometer. The structures proposed for product ions were confirmed by the m/z shifts observed in the estrone‐d4 and estrone methyl ether electron ionization mass spectra. If the formation of some of the most abundant ions may easily be explained by α‐cleavages and retro‐Diels‐Alder type rearrangements, complex mechanisms need to be considered to rationalize the formation of others. Isotope labelling allows discrimination of isobaric ions. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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995.
Inside Back Cover: A Heteroleptic Ferrous Complex with Mesoionic Bis(1,2,3‐triazol‐5‐ylidene) Ligands: Taming the MLCT Excited State of Iron(II) (Chem. Eur. J. 9/2015)
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Dr. Yizhu Liu Dr. Kasper S. Kjær Dr. Lisa A. Fredin Dr. Pavel Chábera Tobias Harlang Dr. Sophie E. Canton Prof. Sven Lidin Dr. Jianxin Zhang Prof. Reiner Lomoth Dr. Karl‐Erik Bergquist Prof. Petter Persson Prof. Kenneth Wärnmark Prof. Villy Sundström 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(9):3831-3831
996.
Anne‐Sophie Cuvier Dr. Florence Babonneau Jan Berton Prof. Christian V. Stevens Dr. Giulia C. Fadda Isabelle Genois Patrick Le Griel Gérard Péhau‐Arnaudet Dr. Niki Baccile 《化学:亚洲杂志》2015,10(11):2419-2426
Control over size monodispersity in chiral self‐assembled systems is important for potential applications like templating, tissue engineering or enantioselective chromatography, just to cite a few examples. In this context, it was reported that the saturated form of sophorolipids (SL), a bioderived glycolipid, are able to form self‐assembled twisted ribbons in water at neutral pH. Here, we show the possibility to control their size dispersion, generally between 10 and 40 nm after synthesis to a value of 13.5±1.5 nm, by a simple dialysis step eliminating the excess of NaCl. We use transmission electron microscopy under cryogenic conditions (cryo‐TEM) combined with small angle neutron scattering (SANS) to characterize the ribbon dispersion both visually and statistically. Two negative controls show the importance of salt in the aggregation process of the ribbons. 相似文献
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999.
Mechanistic Insight into Heptosyltransferase Inhibition by using Kdo Multivalent Glycoclusters
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Dr. Abdellatif Tikad Huixiao Fu Dr. Charlotte M. Sevrain Prof. Sophie Laurent Dr. Jean‐François Nierengarten Prof. Stéphane P. Vincent 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(37):13147-13155
The synthesis of unprecedented multimeric Kdo glycoclusters based on fullerene and calix[4]arene central scaffolds is reported. The compounds were used to study the mechanism and scope of multivalent glycosyltransferase inhibition. Multimeric mannosides based on porphyrin and pillar[5]arenes were also generated in a controlled manner. Twelve glycoclusters and their monomeric ligands were thus assayed against heptosyltransferase WaaC, which is an important bacterial glycosyltransferase that is involved in lipopolysaccharide biosynthesis. It was first found that all the multimers interact solely with the acceptor binding site of the enzyme even when the multimeric ligands mimic the heptose donor. Second, the novel Kdo glycofullerenes displayed very potent inhibition (Ki=0.14 μm for the best inhibitor); an inhibition level rarely observed with glycosyltransferases. Although the observed “multivalent effects” (i.e., the enhancement of affinity of a ligand when presented in a multimeric fashion) were in general modest, a dramatic effect of the central scaffold on the inhibition level was evidenced: the fullerene and the porphyrin scaffolds being by far superior to the calix‐ and pillar‐arenes. We could also show, by dynamic light scattering analysis, that the best inhibitor had the propensity to form aggregates with the heptosyltransferase. This aggregative property may contribute to the global multivalent enzyme inhibition, but probably do not constitute the main origin of inhibition. 相似文献
1000.