全文获取类型
收费全文 | 3849篇 |
免费 | 204篇 |
国内免费 | 23篇 |
专业分类
化学 | 2892篇 |
晶体学 | 49篇 |
力学 | 90篇 |
数学 | 213篇 |
物理学 | 832篇 |
出版年
2023年 | 24篇 |
2022年 | 27篇 |
2021年 | 102篇 |
2020年 | 81篇 |
2019年 | 93篇 |
2018年 | 73篇 |
2017年 | 59篇 |
2016年 | 131篇 |
2015年 | 127篇 |
2014年 | 160篇 |
2013年 | 241篇 |
2012年 | 308篇 |
2011年 | 359篇 |
2010年 | 201篇 |
2009年 | 186篇 |
2008年 | 291篇 |
2007年 | 235篇 |
2006年 | 235篇 |
2005年 | 228篇 |
2004年 | 165篇 |
2003年 | 134篇 |
2002年 | 128篇 |
2001年 | 68篇 |
2000年 | 73篇 |
1999年 | 42篇 |
1998年 | 31篇 |
1997年 | 24篇 |
1996年 | 28篇 |
1995年 | 21篇 |
1994年 | 24篇 |
1993年 | 17篇 |
1992年 | 15篇 |
1991年 | 16篇 |
1990年 | 20篇 |
1989年 | 9篇 |
1988年 | 11篇 |
1987年 | 12篇 |
1986年 | 10篇 |
1985年 | 11篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1979年 | 6篇 |
1978年 | 6篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1967年 | 4篇 |
排序方式: 共有4076条查询结果,搜索用时 109 毫秒
21.
The solubility and diffusion coefficient of carbon dioxide in intermediate‐moisture starch–water mixtures were determined both experimentally and theoretically at elevated pressures up to 16 MPa at 50 °C. A high‐pressure decay sorption system was assembled to measure the equilibrium CO2 mass uptake by the starch–water system. The experimentally measured solubilities accounted for the estimated swollen volume by Sanchez–Lacombe equation of state (S‐L EOS) were found to increase almost linearly with pressure, yielding 4.0 g CO2/g starch–water system at 16 MPa. Moreover, CO2 solubilities above 5 MPa displayed a solubility increase, which was not contributed by the water fraction in the starch–water mixture. The solubilities, however, showed no dependence on the degree of gelatinization (DG) of starch. The diffusion coefficient of CO2 was found to increase with concentration of dissolved CO2, which is pressure‐dependent, and decrease with increasing DG in the range of 50–100%. A free‐volume‐based diffusion model proposed by Areerat was employed to predict the CO2 diffusivity in terms of pressure, temperature, and the concentration of dissolved CO2. S‐L EOS was once more used to determine the specific free volume of the mixture system. The predicted diffusion coefficients showed to correlate well with the measured values for all starch–water mixtures. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 607–621, 2006 相似文献
22.
H. Fawcett S. Barlag H. Becker E. Belau T. Böhringer M. Bosman V. Castillo V. Chabaud D. Bucholz C. Damerell C. Daum G. De Rijk H. Dietl S. Gill A. Gillman R. Gilmore T. Gooch P. Gras Z. Hajduk E. Higon B. Hyams D. Kelsey J. Kemmer R. Klanner U. Kötz S. Kwan B. Lücking G. Lütjens G. Lutz J. Malos W. Männer E. Neugebauer H. Palka M. Pepé G. Polok J. Richardson M. Rozanska K. Rybicki H. Seebrunner U. Stierlin R. Tapper H. Tiecke M. Turala G. Waltermann S. Watts P. Weilhammer F. Wickens L. Wiggers A. Wylie T. Zeludziewicz ACCMOR Collaboration 《Zeitschrift fur Physik C Particles and Fields》1990,46(4):513-519
The production of the neutralK ? (892) resonances by 200 GeVK ? andπ ? has been studied over the kinematic range 0.0<x f<1.0 andp t 2 <5.0 GeV2. Longitudinal and transverse momentum distributions are presented. In addition the decay angular distributions inK ? fragmentation to \(\bar K^{0*} \) have been investigated. 相似文献
23.
24.
Self-assembly of a new precursor [Cu(L)](ClO4)2 (1) (L = macrocyclic ligand) with octacyanometalates [M(CN)8]3- (M = Mo, W) produced two-dimensional cyano-bridged Cu(II)-M(V) bimetallic assemblies [Cu(L)]3n[M(CN)8]2n.6nH2O [M = Mo (2), W (3)] with novel honeycomblike structures, characterized by spectroscopic data, single-crystal X-ray diffraction studies, and magnetic measurements. The crystallographic determination reveals that compounds 2 and 3 are isostructural and crystallize in the triclinic system (P). The Cu atom in a distorted octahedral environment experiences a tetragonal elongation of apical nitrogen atoms exhibiting average Cu-Nax lengths of 2.566 Angstroms for 2 and 2.593 Angstroms for 3, which accounts for the Jahn-Teller effect of a Cu(II) ion. The Cu-NC angles are magnetically important, ranging from 135.7 to 159.2 degrees. Three types of L in the crystal lattice are observed, which are dependent on the relative positions of the pendant hydroxyl groups with respect to the CuN4 basal plane. The positions are correlated with hydrogen bonding of OH groups to neighboring atoms. The magnetic data indicate that ferromagnetic and antiferromagnetic interactions between Cu(II) and M(V) through the CN linkage coexist. 相似文献
25.
Controlled growth of calcium carbonate by poly(ethylenimine) at the air/water interface 总被引:1,自引:0,他引:1
Two metastable calcium carbonate polymorphs, hemispherical vaterite and needle-like aragonite, are selectively formed at the air/water interface by the mediation of poly(ethyleneimine)(with molecular weights of 25000 and 2000, respectively) dissolved in supersaturated calcium bicarbonate solution. 相似文献
26.
Hae‐Jeong Lee Christopher L. Soles Da‐Wei Liu Barry J. Bauer Wen‐Li Wu 《Journal of Polymer Science.Polymer Physics》2002,40(19):2170-2177
X‐ray reflectivity has been used to determine the mass uptake of probe molecules in porous thin films supported on thick silicon wafers. The adsorption occurs by capillary condensation when the films are exposed to probe vapor at controlled partial vapor pressures. The probe solvent partial pressure was varied by mixing saturated air and dry air at constant temperature or by changing sample temperature at a constant vapor concentration. Pore size distribution in the films can be calculated from the probe uptake with typical porosimetric approaches such as the application of the Kelvin equation to convert partial pressure into pore size. For illustration, the pore size distribution of three different nanoporous thin films, the primary candidate of ultra‐low‐k interlevel dielectrics in the next generation of integrated circuit chips, was determined with this technique. These samples represent different generations of low‐k dielectrics developed by industry. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2170–2177, 2002 相似文献
27.
Jeong Gwi-Taek Park Don-Hee Hwang Baik Park Kyungmoon Kim Si-Wouk Woo Je-Chang 《Applied biochemistry and biotechnology》2002,98(1-9):1115-1127
The growth properties of Panax ginseng hairy roots transformed by Agrobacterium rhizogenes were compared between flask and aerated column or stirred bioreactor. In flask cultures, sucrose, initially 30 g/L, was nearly
exhausted after 45 d of culture. The pH of the medium dropped from 5.5 to 4.96 after 10 d, but afterward it gradually increased
to 6.4. After 45 d, hairy roots grew about 16-folds. The growth rate of hairy roots in air-bubble column or stirred bioreactor
cultures was 1.13 (1.11) to 1.23 (1.20) g fresh wt (dry wt)/(g of cells·d), respectively. For both bioreactors, growth was
about three times as high as in the flask cultivation. 相似文献
28.
The surface-enhanced Raman scatterings of dimethyl sulfide, diethyl sulfide and dimethyl disulfide have been investigated in silver sol. The dimethyl disulfide molecule decomposes on silver to the corresponding mercaptide implying facile cleavage of its S---S bond. The C---S bond in dialkyl monosulfide appears not to cleave on silver. For diethyl sulfide, the C2 conformation seems to be favorable on silver than other conformations. 相似文献
29.
Tae Oan Ahn Jung Ho Kim Jong Chan Lee Han Mo Jeong Jong-Yoon Park 《Journal of polymer science. Part A, Polymer chemistry》1993,31(2):435-441
A macro-azoinitiator containing polyarylate segment and azo group was prepared by the solution polycondensation of azobiscyanopentanoyl chloride and hydroxy-terminated polyarylates having viscosity-average molecular weights of 6200, 8100, and 12 400. These macro-azoinitiators were used in the radical polymerization of styrene to synthesize polyarylate-polystyrene block copolymers. Thermal properties measured by the differential scanning calorimetry indicated the phase separated morphology of the block copolymers except at low molecular weight of the block constituents. © 1993 John Wiley & Sons, Inc. 相似文献
30.
S. Barlag H. Becker T. Böhringer M. Bosman V. Castillo V. Chabaud D. Buchholz C. Damerell C. Daum H. Dietl H. Fawcett S. Gill A. Gillman R. Gilmore T. Gooch L. Görlich P. Gras Z. Hajduk E. Higon B. D. Hyams D. P. Kelsey J. Kemmer R. Klanner U. Kötz S. Kwan B. Lücking G. Lütiens G. Lutz J. Malos W. Männer E. Neugebauer H. Palka M. Pepé J. Richardson G. De Rijk K. Rybicki H. J. Seebrunner U. Stierlin H. G. Tiecke M. Turala G. Waltermann S. Watts P. Weilhammer F. Wickens L. W. Wiggers A. Wylie T. Zeludziewicz ACCMOR Collaboration 《Zeitschrift fur Physik C Particles and Fields》1987,37(1):17-23
We have measured the lifetimes of hadronically produced charged and neutralD mesons using silicon microstrip detectors and an active silicon target in the NA32 spectrometer at the CERN SPS. We obtainτ D± = (10.9± 1.5 1.9 )·10?13s andτ D (?)10 = (4.2±0.5)·10?13s based on 59 and 90 fully reconstructed decays respectively, giving a ratioτ D±/τ D (?)10 of 2.6 ±0.5. 相似文献