Ferroelectric and dielectric properties of SrBi<Subscript>4</Subscript>Ti<Subscript>4</Subscript>O<Subscript>15</Subscript> thin films grown on Bi<Subscript>4</Subscript>Ti<Subscript>3</Subscript>O<Subscript>12</Subscript> film layer

Ferroelectric and dielectric properties of bilayered ferroelectric thin films, SrBi₄Ti₄O₁₅ grown on Bi₄Ti₃O₁₂, were investigated. The thin films were annealed at 700°C under oxygen atmosphere. The bilayered thin films were prepared on a Pt(111)/Ti/SiO₂/Si substrate by a chemical solution deposition method. The dielectric constant and dielectric loss of the bilayered thin films were 645 and 0.09, respectively, at 100 kHz. The value of remnant polarization (2P _r) measured from the ferroelectric thin film capacitors was 60.5 μC/cm² at electric field of 200 kV/cm. The remnant polarization was reduced by 22% of the initial value after 10¹⁰ switching cycles. The results showed that the ferroelectric and dielectric properties of the SrBi₄Ti₄O₁₅ on Bi₄Ti₃O₁₂ ferroelectric thin films were better than those of the SrBi₄Ti₄O₁₅ grown on a Pt-coated Si substrate suggesting that the improved properties may be due to the different nucleation and growth kinetics of SrBi₄Ti₄O₁₅ on the c-axis-oriented Bi₄Ti₃O₁₂ layer or on the Pt-coated Si substrate.     

Investigation of structural and optical properties of ZnO films co-doped with fluorine and indium

Undoped ZnO film and ZnO films, which are co-doped with F and In (FIZO) at different concentrations, were synthesized by sol–gel technique and the effects of co-doping of F and In on structural and optical properties of ZnO thin films were investigated. The concentration ratio of [F]/[Zn] was altered from 0.25 to 1.75 with 0.50 step at.% mole and [In]/[Zn] was altered from 0.25 to 1.00 with 0.25 step at.% mole. X-ray diffraction analysis indicates that the films have polycrystalline nature and the (0 0 2) preferred orientation is the stronger peak. No extra phases involving zinc, fluorine and indium compounds were observed even at high F and In content. The grain size of undoped ZnO and FIZO thin films varied between 15 and 20 nm with a small fluctuation. From the SEM images, although the undoped ZnO had a smooth and particle-shaped surface, FIZO films had nanofiber-networks shapes over the surface with average size of 500 nm. The surface morphologies and crystallite sizes for the F and In doped films were slightly different from than those of undoped film. From the optical study, a slight shrinkage of band gap was backwardly observed from 3.36 to 3.25 eV with the increasing of F and In content.     

Unique geometric and electronic structure of CO adsorbed on Ge(100): A DFT study

CO adsorption on the Ge(100) surface has been investigated using a slab model with density functional theory implemented in SIESTA. CO was found to be exclusively adsorbed on the asymmetric dimer with C attaching on the lower Ge dimer atom. The adsorption process is barrierless. The calculated adsorption energy and vibration frequencies are comparable to previous experimental results. The crystal orbital Hamilton analysis showed that the bonding between Ge and CO is mainly attributable to the Ge 4p_z orbital overlapping with C 2 s, or with CO molecular orbitals 3σ and 4σ. The repulsive energy between adsorbed CO molecules is less than 1 kcal/mol. The diffusion barrier of CO on the Ge(100) surface is about 14 kcal/mol.     

Analysis of High Power Millimeter Wave Waveguide Mode Converters with Input Mode Mixture

Based on the coupled mode theory, this paper presents the study on the influence of input mode mixture in circular oversized waveguide mode converters. Three kinds of commonly used waveguide mode converters, including the waveguide mode converters with varying wall radius or small axis perturbations, and the waveguide mode converters with bent structures, are taken as the examples. The results show that the spurious input modes do not simply superimpose onto the output modes, and in some cases they may deteriorate the conversion efficiency for the main output mode. Methods for transforming such spurious input mode mixture simultaneously into the main output mode are also presented in this paper.     

Influence of structural defects on the magnetization process in high-magnetic fields in the Fe61Co10Y8Nb1B20 alloy in the form of ribbons and plates

Amorphous samples of the Fe₆₁Co₁₀Y₈Nb₁B₂₀ alloy in the form of a ribbon with thickness of approximately 30 μm and in the form of a plate with thickness of 0.5 mm have been investigated. Plates were obtained by a suction-casting method, and ribbons by a single roller melt-spinning method. Microstructural studies, using X-ray spectroscopy, confirmed that samples in the as-quenched state were fully amorphous. Measurements carried out using a vibrating sample magnetometer allowed values of coercivity and saturation magnetization to be obtained; it also facilitated the estimation of size and nature of structural defects in the investigated samples. All of the investigated samples of this alloy in the as-quenched state have high values of saturation magnetization of greater than 1.25 T.     

Studies on terbium activated yttrium based tantalate phosphors

Terbium activated yttrium niobium tantalate phosphors were prepared by solid-state reaction and were characterized by photoluminescence measurements, X-ray diffraction and scanning electron microscopy. Photoluminescence (PL) of Y_0.95Tb_0.05Ta_1?xNb_xO₄ phosphors (x = 0–1) are influenced by the host-lattice composition, degree of crystalline order and particle morphology and size. The effect of the morpho-structural properties on PL characteristics of Y(Ta,Nb)O₄:Tb powders is reported.     

Optical and acoustic study of nucleation and growth of bubbles at a liquid-solid interface induced by nanosecond-pulsed-laser heating

The dynamics of liquid-vapor phase-change in the nanosecond time-scale induced by pulsed-laser heating of a liquid on a solid sample is studied by means of optical reflectance and scattering measurements, and the piezoelectric detection technique. The liquids studied include water, ethanol, methanol, IsoproPropyl Alcohol (IPA), and mixtures of water and IPA. The threshold fluence for nucleation is determined with high accuracy using the optical and acoustic signals. Heat diffusion calculations performed for the threshold fluences indicate that the liquids are sufficiently superheated before nucleation sets on. The transient optical reflectance signal is analyzed by an effective-medium theory to provide bubble-growth kinetics, so that the bubble-growth velocity for the test liquids could be estimated. In addition, it is observed that, following the thermally induced nucleation, repetitive acoustic cavitation at the surface of the solid sample occurs, with a time interval related to the speed of sound in the liquid.     

On performance comparison of MR/GI/1 queues

In this paper we are interested in the effect that dependencies in the arrival process to a queue have on queueing properties such as mean queue length and mean waiting time. We start with a review of the well known relations used to compare random variables and random vectors, e.g., stochastic orderings, stochastic increasing convexity, and strong stochastic increasing concavity. These relations and others are used to compare interarrival times in Markov renewal processes first in the case where the interarrival time distributions depend only on the current state in the underlying Markov chain and then in the general case where these interarrivai times depend on both the current state and the next state in that chain. These results are used to study a problem previously considered by Patuwo et al. [14].Then, in order to keep the marginal distributions of the interarrivai times constant, we build a particular transition matrix for the underlying Markov chain depending on a single parameter,p. This Markov renewal process is used in the Patuwo et al. [14] problem so as to investigate the behavior of the mean queue length and mean waiting time on a correlation measure depending only onp. As constructed, the interarrival time distributions do not depend onp so that the effects we find depend only on correlation in the arrival process.As a result of this latter construction, we find that the mean queue length is always larger in the case where correlations are non-zero than they are in the more usual case of renewal arrivals (i.e., where the correlations are zero). The implications of our results are clear.