全文获取类型
收费全文 | 19515篇 |
免费 | 2785篇 |
国内免费 | 2164篇 |
专业分类
化学 | 14919篇 |
晶体学 | 288篇 |
力学 | 996篇 |
综合类 | 187篇 |
数学 | 1812篇 |
物理学 | 6262篇 |
出版年
2024年 | 36篇 |
2023年 | 278篇 |
2022年 | 565篇 |
2021年 | 600篇 |
2020年 | 663篇 |
2019年 | 675篇 |
2018年 | 518篇 |
2017年 | 528篇 |
2016年 | 869篇 |
2015年 | 858篇 |
2014年 | 1007篇 |
2013年 | 1401篇 |
2012年 | 1726篇 |
2011年 | 1772篇 |
2010年 | 1248篇 |
2009年 | 1085篇 |
2008年 | 1295篇 |
2007年 | 1090篇 |
2006年 | 1066篇 |
2005年 | 1021篇 |
2004年 | 819篇 |
2003年 | 710篇 |
2002年 | 793篇 |
2001年 | 512篇 |
2000年 | 459篇 |
1999年 | 415篇 |
1998年 | 306篇 |
1997年 | 276篇 |
1996年 | 268篇 |
1995年 | 246篇 |
1994年 | 201篇 |
1993年 | 180篇 |
1992年 | 162篇 |
1991年 | 145篇 |
1990年 | 130篇 |
1989年 | 106篇 |
1988年 | 89篇 |
1987年 | 57篇 |
1986年 | 61篇 |
1985年 | 68篇 |
1984年 | 35篇 |
1983年 | 33篇 |
1982年 | 21篇 |
1981年 | 24篇 |
1980年 | 12篇 |
1979年 | 8篇 |
1978年 | 4篇 |
1971年 | 2篇 |
1970年 | 2篇 |
1957年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 18 毫秒
31.
Dong‐Cheol Shin Yun‐Hi Kim Hong You Jae Gyu Jin Soon‐Ki Kwon 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5636-5646
A poly(p‐phenylenevinylene) (PPV) derivative containing a bulky (2,2‐diphenylvinyl)phenyl group in the side chain, EHDVP‐PPV, was synthesized by Gilch route. The reduced tolane‐bisbenzyl (TBB) defects, as well as the structure of the polymer, was confirmed by various spectroscopic methods. The intramolecular energy transfer from the (2,2‐diphenylvinyl)phenyl side group to the PPV backbone was studied by UV‐vis and photoluminescence (PL) of the obtained polymer and model compound. The polymer film showed maximum absorption and emission peaks at 454 and 546 nm, respectively, and high PL efficiency of 57%. A yellow electroluminescence (λmax = 548 nm) was obtained with intensities of 6479 cd/m2 when the light‐emitting diodes of ITO/PEDOT/EHDVP‐PPV/LiF/Al were fabricated. The maximum power efficiency of the devices was 0.729 lm/W with a turn‐on voltage of 3.6 V. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5636–5646, 2004 相似文献
32.
Dong Il Han Hoe Jin Hah Hong-Woo Park Sang Man Koo 《Journal of Sol-Gel Science and Technology》2004,32(1-3):47-51
Composite silica particles were synthesized by a two-step (acid-base) process in an aqueous solution with a mixture of organoalkoxysilane monomers. The two-step process separates the hydrolysis and condensation procedures to easily control condensation rate. In this study, the silane monomers used were phenyltrimethoxysilane (PTMS), vinyltrimethoxysilane (VTMS), methyltrimethoxysilane (MTMS), and tetraethyl-orthosilicate (TEOS). The physical properties of the resultant composite particles were investigated with the change in the molar ratio of monomers. The size of the particles increased with increasing the molar ratio of RaSi(OR)3/RbSi(OR)3 or RaSi(OR)3/TEOS (Ra: phenyl; Rb: vinyl, methyl). 相似文献
33.
Sang‐Uk Kim Choonkeun Lee Saimani Sundar Wonbong Jang Seung‐Jin Yang Haksoo Han 《Journal of Polymer Science.Polymer Physics》2004,42(23):4303-4312
A series of polyimides were synthesized from 2,2‐Bis(3,4‐dicarboxyphenyl)hexafluoropropane, 2,2‐bis(3‐amino‐4‐hydroxyphenyl)‐hexafluoropropane, and 4,4′‐oxydianiline by chemical imidization. The effects of the diamine ratios on the properties of the films were evaluated through the study of their thermal, electrical, and morphological properties. All the polymers exhibited better solubility in most of the organic solvents and hence were easily processable. Polyimides with more 2,2‐bis(3‐amino‐4‐hydroxyphenyl)‐hexafluoropropane exhibited better solubility and a low refractive index, which is highly desired for microelectronic applications. The dielectric constant and birefringence were strongly dependent on the fluorine content. With an increase in the fluorine substitution, both the dielectric constant and birefringence decreased. All the polymers exhibited high thermal stability (>400 °C). The absence of crystalline melting in differential scanning calorimetry and broad wide‐angle X‐ray diffraction patterns revealed the amorphous nature of the polymers, which was due to the presence of bulky CF3 groups and hinged ether linkages of the diamine component. The residual stress values decreased with an increase in the 4,4′‐oxydianiline content, and the results were in agreement with the dielectric constant. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4303–4312, 2004 相似文献
34.
Seok‐Ho Hwang Kyung Soo Yoo Charles N. Moorefield Sang‐Won Lee George R. Newkome 《Journal of Polymer Science.Polymer Physics》2004,42(8):1487-1495
A series of metallodendrimers, assembled by means of bis(terpyridinyl)Ru(II) connectivity on poly(propylene imine) dendrimer scaffolds, with homogeneous or heterogeneous surfaces, were prepared. Differential scanning calorimetry and thermogravimetric analysis were used to determine their thermal behavior, glass‐transition temperatures, and the decomposition kinetics and temperatures; no synergy effects for these properties were observed for the heterogeneously surfaced constructs in contrast to the corresponding homogeneously coated materials, which exhibited different values depending on their surface functionalities. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1487–1495, 2004 相似文献
35.
Won Keun Son Ji Ho Youk Taek Seung Lee Won Ho Park 《Journal of Polymer Science.Polymer Physics》2004,42(1):5-11
Electrospinning of cellulose acetate (CA) in a new solvent system and the deacetylation of the resulting ultrafine CA fibers were investigated. Ultrafine CA fibers (∼2.3 μm) were successfully prepared via electrospinning of CA in a mixed solvent of acetone/water at water contents of 10–15 wt %, and more ultrafine CA fibers (0.46 μm) were produced under basic pH conditions. Ultrafine cellulose fibers were regenerated from the homogeneous deacetylation of ultrafine CA fibers in KOH/ethanol. It was very rapid and completed within 20 min. The crystal structure, thermal properties, and morphology of ultrafine CA fibers were changed according to the degree of deacetylation, finally to those of pure cellulose, but the nonwoven fibrous mat structure was maintained. The activation energy for the deacetylation of ultrafine CA fibers was 10.3 kcal/mol. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 5–11, 2004 相似文献
36.
Tae Young Kim Dong Myung Kim Won Jung Kim Tae Hee Lee Kwang S. Suh 《Journal of Polymer Science.Polymer Physics》2004,42(15):2813-2820
The effect of the triblock copolymer poly[styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene] (SEBS) on the formation of the space charge of immiscible low‐density polyethylene (LDPE)/polystyrene (PS) blends was investigated. Blends of 70/30 (wt %) LDPE/PS were prepared through melt blending in an internal mixer at a blend temperature of 220 °C. The amount of charge that accumulated in the 70% LDPE/30% PS blends decreased when the SEBS content increased up to 10 wt %. For compatibilized and uncompatibilized blends, no significant change in the degree of crystallinity of LDPE in the blends was observed, and so the effect of crystallization on the space charge distribution could be excluded. Morphological observations showed that the addition of SEBS resulted in a domain size reduction of the dispersed PS phase and better interfacial adhesion between the LDPE and PS phases. The location of SEBS at a domain interface enabled charges to migrate from one phase to the other via the domain interface and, therefore, resulted in a significant decrease in the amount of space charge for the LDPE/PS blends with SEBS. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2813–2820, 2004 相似文献
37.
Baker‘s yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently differentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products. 相似文献
38.
PinHuaLI LeiWANG MinWANG JinCanYAN 《中国化学快报》2004,15(11):1295-1298
A Glaser coupling reaction of terminal alkynes in the presence of nickel chloride withoutany organics and bases in hot water has been developed, which produces the correspondinghomo-coupling products in good yields. 相似文献
39.
Zhao Fang BAI Jin Chuan HOU 《数学学报(英文版)》2005,21(5):1167-1182
Let X be a (real or complex) Banach space with dimension greater than 2 and let B0(X) be the subspace of B(X) spanned by all nilpotent operators on X. We get a complete classification of surjective additive maps Ф on B0(X) which preserve nilpotent operators in both directions. In particular, if X is infinite-dimensional, we prove that Ф has the form either Ф(T) = cATA^-1 or Ф(T) = cAT'A^-1, where A is an invertible bounded linear or conjugate linear operator, c is a scalar, T' denotes the adjoint of T. As an application of these results, we show that every additive surjective map on B(X) preserving spectral radius has a similar form to the above with |c| = 1. 相似文献
40.