From conventional to microphotochemistry: photodecarboxylation reactions involving phthalimides

A series of acetone-sensitized photodecarboxylation reactions involving phthalimides have been investigated using conventional and microphotochemistry. Both, intra- and intermolecular transformations were compared. In all cases examined, the reactions performed in microreactors were superior in terms of conversions or isolated yields. These findings unambiguously prove the advantage of microphotochemistry over conventional photochemical techniques.     

Application of liquid chromatography in polymer non-ionic antistatic additives analysis

This article investigates the applicability of HPLC-UV, ultra performance LC-evaporative light-scattering detection (UPLC-ELSD), HPLC-ESI(+)-MS and HPLC-hybrid linear ion trap (LTQ) Orbitrap MS for the analysis of different non-ionic antistatic additives, Span 20, Span 60, Span 65, Span 80, Span 85 (sorbitan fatty acid esters), Atmer 129 (glycerol fatty acid ester) and Atmer 163 (ethoxylated alkylamine). Several alkyl chain length or different degrees of esterification of polyol derivatives can be present in commercial mixtures of these polymer additives. Therefore, their identification and quantification is complicated. Qualitative composition of the studied compounds was analysed by MS. HPLC-UV, UPLC-ELSD and HPLC-LTQ Orbitrap MS methods were applied to the quantitative determination of the different Spans, Atmer 129 and Atmer 163, respectively. Quality parameters of these methods were established and no derivatization was necessary.     

Quantitative Analysis of Caffeoylquinic Acids and Styrylpyrones in Sweetia panamensis Bark by UPLC

Six secondary metabolites from the methanolic extract of Sweetia panamensis (Fabaceae) bark were isolated and characterised. Along with the pyrones desmethylangonine β-d-O-glucopyranoside and desmethylangonine β-d-O-glucopyranosyl-(1→6)-O-β-d-glucopyranoside, already reported in this species, 5-O-caffeoylquinic acid (chlorogenic acid), 4-O-caffeoylquinic acid, 3-O-caffeoylquinic acid and the isoflavonoid 5-O-methylgenistein 7-O-β-d-glucopyranoside were isolated for the first time from S. panamensis. Additionally, an LC-ESI-MS qualitative analysis was performed and an ultra performance liquid chromatography (UPLC) method was developed and validated for the determination of these compounds. The UPLC method was applied to the quantitative analysis of plant samples. Pyrones and caffeoylquinic acids resulted to be the main compounds in the extract; in particular desmethylangonine β-d-O-glucopyranosyl-(1→6)-O-β-d-glucopyranoside was the most abundant compound.

     

Quantitative Analysis of Caffeoylquinic Acids and Styrylpyrones in Sweetia panamensis Bark by UPLC

Six secondary metabolites from the methanolic extract of Sweetia panamensis (Fabaceae) bark were isolated and characterised. Along with the pyrones desmethylangonine β-d-O-glucopyranoside and desmethylangonine β-d-O-glucopyranosyl-(1→6)-O-β-d-glucopyranoside, already reported in this species, 5-O-caffeoylquinic acid (chlorogenic acid), 4-O-caffeoylquinic acid, 3-O-caffeoylquinic acid and the isoflavonoid 5-O-methylgenistein 7-O-β-d-glucopyranoside were isolated for the first time from S. panamensis. Additionally, an LC-ESI-MS qualitative analysis was performed and an ultra performance liquid chromatography (UPLC) method was developed and validated for the determination of these compounds. The UPLC method was applied to the quantitative analysis of plant samples. Pyrones and caffeoylquinic acids resulted to be the main compounds in the extract; in particular desmethylangonine β-d-O-glucopyranosyl-(1→6)-O-β-d-glucopyranoside was the most abundant compound.     

DABCO-mediated substitution of vinylic iodides: synthesis of β-cyano Baylis-Hillman acetates

Nucleophilic substitution of vinyl β-iodo Baylis-Hillman acetates using 1,4-diazabicyclo[2.2.2] octane (DABCO) and then KCN, provides a stereoselective method for the synthesis of the corresponding β-cyano Baylis-Hillman acetates in high yields.     

Special symmetric periodic solutions of differential systems with distributed delay

We discuss the existence of periodic solutions to a system of differential equations with distributed delay which shows a certain type of symmetry. For this, such solutions are related to the solutions of a system of second-order ordinary differential equations.     

Lasing of a single crystal Nd fluoride fiber

We present laser action in a single crystal fluoride fiber obtained by the micro-pulling-down technique. The 700 μm diameter and 1 cm long Nd:LiYF₄ fiber was pumped by a beam shaped diode bar emitting at 806 nm. A peak power of 300 mW was achieved with a slope efficiency of 12%. When considering the pump power fraction absorbed by the laser mode, a slope efficiency of 37% was achieved. To the best of our knowledge, this is the first report of a Nd: LiYF₄ fiber laser.     

Unsupervised classification of children’s bodies using currents

Object classification according to their shape and size is of key importance in many scientific fields. This work focuses on the case where the size and shape of an object is characterized by a current. A current is a mathematical object which has been proved relevant to the modeling of geometrical data, like submanifolds, through integration of vector fields along them. As a consequence of the choice of a vector-valued reproducing kernel Hilbert space (RKHS) as a test space for integrating manifolds, it is possible to consider that shapes are embedded in this Hilbert Space. A vector-valued RKHS is a Hilbert space of vector fields; therefore, it is possible to compute a mean of shapes, or to calculate a distance between two manifolds. This embedding enables us to consider size-and-shape clustering algorithms. These algorithms are applied to a 3D database obtained from an anthropometric survey of the Spanish child population with a potential application to online sales of children’s wear.     

Cocycle deformations and Galois objects for semisimple Hopf algebras of dimension p3 and pq2

Let p and q be distinct prime numbers. We study the Galois objects and cocycle deformations of the noncommutative, noncocommutative, semisimple Hopf algebras of odd dimension $p^3$ and of dimension $p{q}^2$. We obtain that the $p+1$ non-isomorphic self-dual semisimple Hopf algebras of dimension $p^3$ classified by Masuoka have no non-trivial cocycle deformations, extending his previous results for the 8-dimensional Kac–Paljutkin Hopf algebra. This is done as a consequence of the classification of categorical Morita equivalence classes among semisimple Hopf algebras of odd dimension $p^3$, established by the third-named author in an appendix.