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Shipra Baluja Pranav Inamdar Mayur Soni 《物理化学学报》2004,20(9):1104-1107
Density, viscosity and ultrasonic velocity of solutions of four Schiff bases in 1, 4-dioxane and dimethylformamide (DMF) were measured at 308. 15 K. Various acoustical properties such as specific impedance (Z), adiabatic compressibility (κ), Rao‘s molar sound function (Rm), the van der Waals constant (b), molar compressibility (W),intermolecular free length (L1), relaxation strength ( r ), solvation number ( Sn), were calculated. The results are interpreted in terms of molecular interactions occurring in the solutions. 相似文献
276.
Soni Bhupendra K. Kelley Robert L. Srivastava Vipul J. 《Applied biochemistry and biotechnology》1998,(1):651-659
A two-stage process for the manufacture of propylene oxide is described. The preliminary economics based on use of methanol
as a regeneration factor has resulted in a production cost of $12.10/lb of propylene oxide based on propylene oxide production
rate of 40 mg/g-cell/h in conventional reactor. Increasing the propylene oxide production from 40 to 500 mg/g-cell/h resulted
in a cost reduction from $12.10 to 5.8/lb of propylene oxide. The granular-activated, carbon-fluidized bed reactor (GAC-FBR)
absorbs the propylene oxide and when saturated is eluted with ethyl acetate, and the bed is regenerated by steam to drive
off the residual solvents. The estimated manufacturing costs are approx 59% lower (from $12.10/lb in conventional reactors
to $5.00/lb for GAC-FBRs) for products that are highly inhibitory such as epoxides. In the GAC-FBR reactor, enhancing the
propylene oxide production rate from 120 to 1500 mg/g-cell/h has resulted in the cost reduction to $2.00/lb. Enhancing the
production capacity from 1 million lb to 10 million lb/yr has further reduced the cost of production to $1.00/lb. 相似文献
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Soni Bhupendra K. Paterek J. Robert Pradhan Salil Srivastava Vlpul J. 《Applied biochemistry and biotechnology》1998,(1):709-718
Oil-gas exploration and production (E&P) soils contaminated with total petroleum hydrocarbons (TPHs) have been tested for
degradation by two different treatments: biological and chemical. Biological treatment includes the use of native microorganisms
for transformation of the various hydrocarbons found in E&P soils. Degradation of TPH of 80 and 86%, was achieved for two
different soils, respectively in control experiments. The effect of growth stimulants such as glucose, acetic acid, and valeric
acid was examined on TPH degradation. Incorporation of inducer (valerate) enhanced the degradation up to 89 and 93%, for the
two soils, respectively. A large portion (> 41%) of contaminant in one soil was comprised of compounds in the carbon range
of C10-C16 and < 7% constituted carbon range of C24-C28. The degradation of C10-C16 compounds was higher (> 98%) as compared to C24-C28 compounds (< 75%). Likewise, the degradation rate was also higher (58 mg/kg/d) for lower compounds as compared to higher
carbon range compounds (6.7 mg/kg/d). Experiments conducted on chemical treatment included the effect of chelators on stabilization
of H2O2, comparative studies between buffer and water (used for soil preparation), and the effect of pH on TPH degradation. The rate
of oxygen evolution from H2O2 was significantly reduced with use of either chelated iron or phosphate buffer using naphthelene as a model compound. Chemical
treatment demonstrated a higher degradation of TPH from contaminated soils at pH 4.0 as compared to a pH of 7.0. More degradation
was obtained with slurry prepared in phosphate buffer as compared to deionized water. 相似文献
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Garg S Bhaskar T Soni K Muthu Kumaran G Muto A Sakata Y Murali Dhar G 《Chemical communications (Cambridge, England)》2008,(42):5310-5311
FSM-16 (Folded Sheet Silica) supported catalysts could accommodate 12 wt% Mo (18% MoO(3)) as a monolayer with higher dispersion than any other silica support; these catalysts showed outstanding HDS and HYD activities compared to gamma-Al(2)O(3), amorphous silica, and other mesoporous silica supported catalysts. 相似文献