A novel route for waste water treatment: photo-assisted Fenton degradation of dye pollutants accumulated in natural polyelectrolyte microshells

The efficient accumulation of dyes in constructed natural polyelectrolyte microshells under moderate conditions, combined with the photo-assisted Fenton reagent, opens a new route for the effective elimination of dye pollutants from waste water.     

Potential energy surfaces for HenNe+ ions: ab initio and diatomics-in-molecule results

The potential energy surface of He2Ne+ has been reinvestigated using a combination of ab initio and diatomics-in-molecule (DIM) calculations. In contrast to the reports of two recent studies the ion is found to have an asymmetric linear He-Ne-He structure, with no barrier to formation from the separated atoms on the ground-state surface. The He-Ne+ bond lengths at the potential minimum are 1.51 and 1.81 A, and the total bonding energy is 0.717 eV. Comparing the He2Ne+ energy to that of HeNe+, the bonding energy for the second helium atom is 0.06 eV, about 10% of that of the first He atom. The saddle point between the two equivalent minima is a symmetric structure, 0.0074 eV above the potential minimum. A symmetric geometry becomes the overall potential minimum if the 2s hole on the Ne is excluded from the reference states of a multireference configuration interaction calculation. A DIM potential was created for the HenNe+ family of ions. The DIM potential is consistent with the asymmetric He2Ne+ ion serving as a core; it predicts a slightly more asymmetric geometry than the ab initio results. Additional helium atoms form five-membered rings around the bonds of the core ion to fill the first shell and then add to the ends of the cluster. The asymmetric core ion and the highly compact structure help to account for the lack of apparent shell structure in the mass spectrometry of HenNe+ clusters. Finally, we recommend that the value De=0.63+/-0.04 eV be adopted for the ground state of HeNe+.     

Experimental study of natural convection heat transfer between an outer horizontal cylindrical envelope and an inner concentric heated square cylinder with two slots

This paper presents the results of an experimental study of natural convection heat transfer between a horizontal cylindrical envelope and an internal concentric heated square cylinder with two slots. The internal cylinder was a hollow one with horizontal slots on its top and bottom surfaces. The ratio of slot widthS to the side heightH was 0.0612 and 0.3878. The ratio of the envelope inner diameterD _o to the side heightH was 2.653. Air was used as the working fluid. The range of Ray-leigh number was 1.77×10²8.72×10⁶ forS/H=0.0612 and 1.32×10²6.25×10⁶ forS/H=0.3878. The results show that there are three different heat transfer regimes in different Ray-leigh number regions, i.e. pure conduction regime, transition regime and convection regime. The average heat transfer results were correlated into two empirical equations. Comparison was made with the non-slotted case. It is found that slots of the internal cylinder can significantly enhance the heat transfer.

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Experimentelle Untersuchung des Wärmeübergangs bei natürlicher Konvektion zwischen einer horizontalen zylindrischen Außenhülle und einem konzentrischen, beheizten, quadratischen Prisma mit zwei Schlitzen

Zusammenfassung In der Arbeit werden die Ergebnisse einer experimentellen Untersuchung des Wärmeübergangs bei natürlicher Konvektion zwischen einer horizontalen zylindrischen Außenhülle und einem beheizten quadratischen Prisma mit zwei Schlitzen vorgestellt. Das Prisma selbst ist hohl und weist in der oberen und unteren Begrenzungsfläche je einen horizontalen Längsschlitz auf. Das Verhältnis von SchlitzweiteS zu SeitenhöheH beträgt 0,0612 und 0,3878, das des HülleninnendurchmessersD _o zur SeitenhöheH beträgt 2,653. Als Arbeitsmedium diente Luft. Die Rayleigh-Zahlen variierten zwischen 1,7·10² und 8,72·10⁶ fürS/H=0,0612 und zwischen 1,32·10² und 6,25·10⁶ fürS/H=0,3878. Die Ergebnisse belegen die Existenz dreier unterschiedlicher Wärmeübergangsregime in den verschiedenen Rayleigh-Zahl-Bereichen, und zwar reiner Leitungsbereich, Übergangsgebiet und Konvektionsbereich. Die Ergebnisse für den Wärmeübergang werden im Vergleich mit jenen für ein Prisma ohne Schlitze durch zwei Korrelationbeziehungen dargestellt. Es zeigt sich, daß durch Anbringung von Schlitzen am Innenprisma der Wärmeübergang wesentlich verstärkt werden kann.

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Nomenclature C _p specific heat at constant pressure, J/(kg·K) - D _i diameter of the related circular cylinder whose circumferential area is equal to that of the unslotted square cylinder, m - D _o internal diameter of the outer circular envelope, m - F _i surface area of the inner two slot cylinder, m - g gravitational acceleration, m/s² - H distance between the opposite sides of the square cylinder with two slots, m - K _eq dimensionless equivalent thermal conductivity - L axial length of the test section, m - m ratio of the area of the unslotted square cylinder surface to that of the slotted square cylinder - P pressure in the enclosure, Pa - Q total power input to the enclosure, W - Q _cond radial heat conduction, W - Q _conv convective heat transfer, W - Q _r radiation heat transfer, W - Q _los end heat dissipation, W - R air gas constant, J/(kg·K) - Ra Rayleigh number - S slot width, m - T _i wall temperature of the inner cylinder, K - T _o wall temperature of the outer envelope, K - T _m mean temperature, K - T temperature difference=T _i –T _o , K - W maximum gap width of the test annuli=(D _o –H)/2 for the square case, m Greek symbols ₀ black body radiation constant, W/(m²·K⁴) - _s equation system emissivity - air thermal conductivity, W/(m·K) - _eq equivalent thermal conductivity, W/(m·K) - air dynamic viscosity, kg/(m·s) This work was supported by the National Natural Science Foundation of China.