迷宫密封转子系统非线性动力稳定性的研究

研究迷宫密封对转子系统动力稳定性的影响，迷宫密封的气动力采用Muszynska非线性力模型，计算了单盘Jeffcott转子非线性动力学特性。对Jacobi矩阵的分析表明，在密封力的影响下，转子达到一定转速后开始失稳，发生Hopf分岔，进入周期涡动状态，涡动幅度随转速的提高而增大，提高到一定程度，密封和转子发生碰摩，采用Runge-Kutta法数值模拟了转子的轴心轨迹。最后分析了迷宫密封的物理和结构参数对系统运动特性的影响。     

利用原位氟化保护层改善三维锡锂合金/碳纸负极贫电解液下性能

金属锂具有最高的理论比容量(3860 mAh·g^?1)和最低的还原电势(?3.04 V),是新型高能量密度电池负极材料的最佳选择之一。然而由于金属锂负极表面自发生成的固态电解质界面(SEI)十分不稳定,导致锂枝晶的产生和电池容量快速衰减,严重限制了锂金属电池的商业化应用。因此,本工作利用碳酸双(2,2,2-三氟乙基)酯(DTFEC)添加剂在三维锡锂合金/碳纸负极(SnLi/Cp)表面原位构筑了高机械强度和离子穿透性的含氟化物(LiF和SnF2)保护层,有效地改善了锂负极的倍率性能和循环稳定性。结果显示,SnLi/Cp对称电池在8 mA·cm^?2的电流密度下经过100次循环后过电位仅为90 mV。当将电解液降低到12μL(1.5μL·(mAh)?1)时,在5 mA·cm^?2的电流密度下对称电池仍具有优异的稳定性;SnLi/Cp||NMC811电池在1C(1.5 mA·cm^?2)条件下能稳定循环300圈以上,库伦效率高达98.1%。这种方法能够显著改善锂金属负极的循环稳定性,有助于实现高能量密度锂金属电池的实际应用。     

深空网测控模式△DOR测量建模与精度分析

差分干涉测量技术是获取深空探测器高精度角位置信息的重要技术手段. 本文以中国深空网在嫦娥3 号(CE'3 号) 任务中首次应用为背景,论述深空网测控模式差分干涉测量技术的测量模型,相对于传统的短时交替观测模式,该方法能够全时段确保目标航天器的遥测、遥控通信,克服短时交替引起的航天器遥测信息中断以及应急遥控指令无法发送的问题. 基于CE'3 号环月轨道段的实测数据处理结果,通过与事后精密轨道的精度比对表明,测量数据时延精度在1 ns 量级,相应于角位置精度97 nrad(地月距离上CE'3 号位置精度37 m),与具有相似基线构型的采用短时交替模式的CVN 网测量精度在同等量级.      

ITER极向场馈线系统冷屏初步设计

ITER极向场馈线系统采用冷屏以降低4K温区低温部件的热负荷。该文对极向场馈线冷屏的初步设计进行介绍,并计算了冷屏的热负荷。     

防毒面具语言清晰度试验研究

在低背景噪声的野外环境中,采用小闭集汉语（声母）清晰度测试方法,试验比较了四种防毒面具的清晰度水平。测试结果证实：与不佩戴面具相比,佩戴面具后语言清晰度得分严重降低,并随通话距离的增加而进一步恶化;以７５％清晰度得分作为通话性能的可接受限度,那么,不佩戴面具及佩戴四种面具的有效通话距离分别为６３．６、１５．７、１８．６、２５．０和２６．９ｍ。此外,结合对四种面具传声特性测定结果,本文还分析了清晰度测试方法及其结果的合理性。     

Spin Waves in a Semi-Infinite Heisenberg Ferromagnet with Magnetocrystalline Anisotropy

A Green function formalism is employed to investigate the effect of magnetocrystalline anisotropy on surface spin waves in semi-infinite Heisenberg ferromagnets at low temperatures T << T_c. The dispersion relations are investigated in detail. The density of states (DOS) of surface spin waves and layered magnetizations are also derived.     

具有TVD性质的三阶精度GODUNOV格式在粘性流场计算中的应用

本文发展了一种具有TVD性质的三阶精度的Godunov格式。隐式部分采用迎风对角线形隐式近似因式分解法。并引入了粘性通量的简化算法。显式部分采用三阶精度TVD格式。为进一步增强格式的稳定性及对间断的捕捉能力,在单元边界上构造Riemann问题。应用上述方法对某型涡轮高压级及压气机进行了数值模拟。     

基于全氟酞菁铜和碗烯双分子体系在银和石墨表面自组装行为的低温扫描隧道显微镜研究

Corannulene (COR) is considered a promising molecular building block for organic electronics owing to its intriguing geometrical and electronic properties. Intensive research efforts have been devoted to understanding the assembly behavior and electronic structure of COR and its derivatives on various metal surfaces via low-temperature scanning tunneling microscopy (LT-STM). Here we report the formation of binary molecular networks of copper hexadecafluorophthalocyanine (F₁₆CuPc)-COR self-assembled on the highly oriented pyrolytic graphite (HOPG) and Ag (111) substrates. Intermolecular hydrogen bonding between F₁₆CuPc and COR facilitates the formation of binary molecular networks on HOPG and further induces a preference for bowl-down configured COR molecules. This observed configuration preference disappears on Ag (111) substrate, where COR molecules lie on the substrate with their bowl openings pointing up and down randomly. We propose that strong interfacial interactions between the molecule and Ag (111) surface constrain the bowl inversion of the COR molecule, which thus retains its initial configuration upon adsorption.     

High-efficiency and magnetically separable nanocatalyst: β-cyclodextrin modified core–shell hybrid magnetic nanoparticles

A novel hybrid magnetic nanoparticle, which was fabricated by Fe₃O₄ nanoparticle modified with β-cyclodextrin (Fe₃O₄@SiO₂-GPTSCD), was prepared via a flexible method, including thermal decomposition, sol–gel process and ring-opening reaction of epoxy group. The structures had been characterized by fourier transform infrared spectra, transmission electron microscopy, and thermogravimetric analysis. The magnetic property of the resulting nanoparticles was kept, that they could be used for magnetic separation. Most excitingly, they showed high-efficiency catalytic activity with sodium hypochlorite and hydrogen peroxide as the oxidant in selective oxidation of benzyl alcohol, even higher than pure β-cyclodextrin (CD). It suggests that the hybrid nanoparticles are expected to be applied in more extensive fields, due to the combination of the activity of CD immobilized on the surface of nanoparticles and the characteristic of nanomaterials.     

Physicochemical Properties, <Superscript>1</Superscript>H-NMR,Ab Initio Calculations and Molecular Interaction in Binary Mixtures of <Emphasis Type="Italic">N</Emphasis>-methylimidazole with Methanol

Over the full molar fraction range, the density, viscosity, refractive index, conductivity and pH at the temperatures (298.15, 308.15, and 318.15) K, mixing enthalpy at T?=?298.15 K, and ¹H-NMR were measured for the binary mixtures of x N-methylimidazole (hereafter abbreviated to N-mim)?+?(1???x) methanol, together with ab initio calculations. The thermodynamic parameters of activation for viscous flow were calculated and analyzed. The excess molar volume, viscosity deviation, deviation for the logarithm of viscosity, refractive index deviation and the excess refractive index, excess Gibbs energy of activation of viscous flow and the molar mixing enthalpy were calculated and fitted with a Redlich–Kister equation. The partial molar mixing enthalpies and the protons’ chemical shift changes of N-mim and methanol were calculated and explained. An increase in temperature leads to the excess molar volume becoming more negative, whereas the deviations for the logarithm of viscosity, viscosity deviation and the excess Gibbs energy of activation of viscous flow become less positive; in contrast the refractive index deviation and the excess refractive index become less positive at first and then become more positive. The activation of the viscous fluid is a more ordered process. The physicochemical properties, ab initio calculations, combined with the ¹H-NMR results reveal that the molecular interactions among unlike molecules is stronger than that between like ones. There is an ionization process and hydrogen bond interaction between N-mim and methanol, the predominant interaction is N-mim:methanol?=?1:1 hydrogen-bonded network, where the methyl groups of methanol and N-mim, respectively, are electron-withdrawing and electron-donating groups.