Evaluation of visibility improvement in fog by the range gating technique

An analysis of the propagation process in fog has been performed by means of the Monte Carlo method. The effect of multiple scattering on image quality and on visibility range has been studied, together with the detailed time dependence of the light at the receiving system. The improvement in visibility achievable with range gating techniques has been evaluated.     

Coulomb energy differences between isobaric analogue states in 70Br and 70Se

Gamma ray transitions de-exciting states in the N = Z nucleus ⁷⁰Br have been identified for the first time using the GASP and EUROBALL arrays coupled with ancillary detectors. The level scheme of ⁷⁰Br has been established by means of particle-gated γ-γ and γ-γ-γ coincidences. The Coulomb energy differences between isobaric analogue states in ⁷⁰Br and ⁷⁰Se show a deviation from the expected behaviour which could be related to dripline effects. Received: 18 July 2001 / Accepted: 25 September 2001     

Supercontinuum generation in ultra-flat near zero dispersion PCF with selective liquid infiltration

We present a new design study of ultra-flat near zero dispersion PCF with selectively liquid infiltration with all uniform air-holes in the cladding. The dependence of the individual parameters upon dispersion has been presented in detail. The study establishes that varying Λ influences the total dispersion, whereas d has the desired effect of modifying the dispersion slope, and varying n_L modifies both. With the above study we could achieve near zero ultra-flat dispersion as small as 0 ± 0.41 ps/nm/km for broad wavelength range of 452 nm. The optimized near zero ultra-flat dispersion PCF has been targeted for smooth and flat broadband spectrum supercontinuum generation (SCG) for near Infrared (IR) applications. Broadband SC generations corresponding to three different designs of ultra-flat dispersion fiber have been carried out by using picoseconds pulse laser around the first zero dispersion wavelengths (ZDW). The numerical results show that FWHM of around 400 nm with less than a meter long fiber can be achieved with these fibers that cover most of the communication wavelength bands. The proposed design study will be applicable for applications in the field of tomography, Dense Wavelength Division Multiplexing (DWDM) system, spectroscopy, etc.     

Determination of bromadiolone in pheasants and foxes by differential pulse voltammetry

Bromadiolone, a commercially used anticoagulant rodenticide, was determined in tissues of various animals by differential pulse voltammetry with a carbon-paste electrode. Under the most suitable experimental conditions (step potential of 25?mV?s^?1 and 0.2?mol?L^?1 acetate buffer, pH 4.2), the limit of detection was 0.5?ng?mL^?1. The electroanalytical method was consequently used to investigate the bromadiolone transport within the food chain. Pheasants were exposed to bromadiolone and then used as feed for a fox. The average levels were 528 and 198?ng of bromadiolone per gram of fresh weight of liver of pheasant and fox, respectively. Due to the surprisingly lower content of bromadiolone in the latter, a basic biochemical analysis, particularly blood coagulation, was performed. Among the parameters studied (thrombin time, prothrombin time, activated partial thromboplastin time, and fibrinogen), there was prolongation of the prothrombin time and activated partial thromboplastin time.     

Doxorubicin Encapsulation Investigated by Capillary Electrophoresis with Laser-Induced Fluorescence Detection

Doxorubicin (DOX) belongs to the group of anthracycline antibiotics with very effective anticancer properties. On the other hand, the cardiotoxic effects limit its application over the maximum cumulative dose. To overcome this obstacle, encapsulation of this drug into the protective nanotransporter such as apoferritin is beneficial. In this study, fluorescent behavior of DOX in various solvents was determined by fluorescence spectrometry, demonstrating the fluorescence quenching effect of water, which is often used as a solvent. It was found that by increasing the amount of the organic phase in the DOX solvent the dynamic quenching is significantly suppressed. Ethanol, acetonitrile and dimethyl sulfoxide were tested and the best linearity of the calibration curve was obtained when above 50 % of the solvent was present in the binary mixture with water. Moreover, pH influence on the DOX fluorescence was also observed within the range of 4–10. Two times higher fluorescence intensity was observed at pH 4 compared to pH 10. Further, the DOX behavior in capillary electrophoresis (CE) was investigated. Electrophoretic mobilities (CE) in various pH of the background electrolyte were determined within the range from 16.3 to −13.3 × 10 ⁻⁹ m⁻² V⁻¹ s⁻¹. Finally, CE was also used to monitor the encapsulation of DOX into the cavity of apoferritin as well as the pH-triggered release.

     

Fluorescent 6‐hydroxy‐ and 6,7‐dihydroxy‐4‐trifluoro‐methylcarbostyrils and formation of o‐carboxymethylated derivatives via o‐succinimide esters

Stepwise demethylation of fluorescent 6,7‐dimethoxy‐3‐trifluoromethylcarbostyrils 5 leads to 6‐hydroxy derivatives 6 and 6,7‐dihydroxyderivative 7 . Phenolate formation shifts excitation and emission maxima from 370 and 430 nm to 430 and 480 nm for the anion of 6 and as far as 500 and 580 nm for the dianion of 7 . Dependence of fluorescence quantum yield on media and polar structure, varying from 0.02 to 0.51, is discussed. O‐Alkylation of 6 with alkyl bromoacetate yields esters of type 8 in good yield. Reactive succinimidoyl (OSu) esters of type 11 were prepared after saponification to acids 9 . With amino acids or their esters, peptides and aminoglucose, linking to labeled derivatives 13 or 15 could be achieved under mild conditions in slightly basic aqueous media.     

Theoretical analysis of electron acoustic shock waves in magnetized superthermal plasma with electron beam

We have analysed the small-amplitude non-linear electron acoustic shock waves by taking into account the effects of electron beam in magnetized plasma. Satellite observations in different regions of the Earth's magnetosphere have shown that the electrostatic solitary waves are generally associated with electron or/and ion beams. The nonlinear Korteweg-de-Vries Burgers (KdVB) equation has been derived by considering the basic fluid equations and dissipation effects. The nonlinear coefficient of KdVB equation comes out to be negative. Only dip-shaped potential structures are reported here. For the parameters discussed in this paper, we did not find positive polarity shocks. This could be due to the restrictions on the plasma parameters since we are using the fixed densities of the cold, hot, and beam electrons as observed by the Viking satellite in the auroral region. In this paper, the importance of the cold electron to hot electron temperature in conjunction with the beam speed is pointed out. Increase in beam density, kinematic viscosity, and magnetic field results in increase in the amplitude while the increase in hot electron concentration and superthermality leads to decrease in potential. The numerical analysis is presented for the parameters corresponding to the observation of burst b event by Viking satellite in the dayside auroral zone of the earth's magnetosphere.     

Fast ethylamine gas sensing based on intermolecular charge-transfer complexation

We have investigated the fast ethylamine gas sensing of 2-chloro-3,5-dinitrobenzotrifluoride(CDBF) loaded poly(acrylonitrile) nanofiber based on an intermolecular charge-transfer complexation.Reversible response and recovery were achieved using alternating gas exposure.This system shows a fast ethylamine gas sensing within 0.4 s.     

Obliquely Propagating Electron Acoustic Shock Waves in Magnetized Plasma

Obliquely propagating electron acoustic shock waves in plasma with stationary ions, cold and superthermal hot electrons are investigated in magnetized plasma. Employing reductive perturbation method, Korteweg-de Vries-Burgers equation (KdVB) is derived in the small amplitude approximation limit. The analytical and numerical calculations of the KdVB equation show the variation of shock waves structure (amplitude, velocity, and width) with different plasma parameters. Particle density (α), superthermal parameter (κ), electron temperature ratio (??), kinetic viscosity (η₀), obliqueness (k_z), and strength of magnetic field (ω_c) significantly modify the properties of the shock waves structures. The present investigation is useful to understand dissipative structures observed in space or laboratory plasma where multielectrons population with superthermal electrons are prevalent.