A New Chair‐shaped Conformation Containing HgHgOHgHgO: Synthesis and Structure of Hg4(L2)2(NO3)4 (L2 = morpholin‐4‐ylpyridin‐2‐ylmethyleneamine)

. The complex Hg₄(L²)₂(NO₃)₄ ( 1 ) (L² = morpholin‐4‐ylpyridin‐2‐ylmethyleneamine) has been synthesized and characterized by CHN analysis, IR, and UV/Vis spectroscopy. The crystal structure of 1 was determined using single‐crystal X‐ray diffraction. The crystal structure of 1 contains four mercury atoms, four nitrate anions (two terminal and two bridge ones) and two L² ligand molecules. A chair shape, six‐membered ring is formed with the sequence OHgHgOHgHg built from Hg–Hg dumbbells and oxygen atoms from the nitrate co‐ligands. In the crystal structure, the asymmetric unit of the compound is built up by one‐half of the molecule. It contains the Hg₂²⁺ moiety with a mercury–mercury bonded core, in which one diimine ligand is coordinated to one of the mercury atoms. The nitrate anions act as anisobidentate and bidentate ligands.     

Codismantlability and projective dimension of the Stanley–Reisner ring of special hypergraphs

In this paper, we generalize the concept of codismantlable graphs to hypergraphs and show that some special vertex decomposable hypergraphs are codismantlable. Then we generalize the concept of bouquet in graphs to hypergraphs to extend some combinatorial invariants of graphs about disjointness of a set of bouquets. We use these invariants to characterize the projective dimension of Stanley–Reisner ring of special hypergraphs in some sense.     

Electrocatalytic Reduction of Dioxygen on the Surface of Glassy Carbon Electrodes Modified with Cobalt Porphyrin Complexes

The preparation and electrocatalytic behavior of glassy carbon electrodes modified with three different cobalt porphyrin complexes were investigated. The electrocatalytic ability of the modified electrodes for the reduction of dioxygen to hydrogen peroxide and water in air‐saturated aqueous solutions was examined by cyclic voltammetry and chronoamperometry techniques. The porphyrin‐adsorbed glassy carbon electrodes possess excellent electrocatalytic abilities for dioxygen reduction with overpotential about 0.5 V lower than that at a plain glassy carbon electrode. The experimental parameters were optimized and the mechanism of the catalytic process was discussed. The possible effects of the electron‐donating properties of groups in the meso‐position of the porphyrin ring were investigated.     

Study of bending loss and mode field diameter in depressed inner core triple-clad single-mode optical fibers

In this paper, the bending loss and the mode field diameter (MFD) of the R-type depressed inner core triple clad single-mode optical fibers are investigated. The effects of the optical and geometrical parameters on the bending loss and the MFD are examined in these fibers. The simulation results indicate that with increasing of the core radius (a), which is desired from manufacturing point of view, the bending loss and MFD coefficients are decreased. Consequently, the large core radius can be used to optimize the bending loss in the foregoing fibers. In the meantime, simulation outcomes show that the Δ and Q have considerable impact on the bending loss in the RI and RII fibers, respectively. The MFD and bending loss is decreased with increasing of Δ, but the case is inversed for Q. Based on the presented simulations, it is found out that the bending loss strongly depends on the distribution profile of the electric field in the cladding region for a given MFD. In other words, the field amplitude and damping rate in the cladding region determine the fiber bending loss.     

t-clique ideal and t-independence ideal of a graph

In this paper, we introduce and study families of squarefree monomial ideals called clique ideals and independence ideals that can be associated to a finite graph. A family of clique ideals with linear resolutions has been characterized. Moreover, some families of graphs for which the quotient ring of their clique ideal is Cohen–Macaulay are introduced and some homological invariants of the clique ideal of a graph G, which is the complement of a path graph or a cycle graph, are obtained. Also some algebraic properties of the independence ideal of path graphs, cycle graphs and chordal graphs are studied.     

Application of a 1‐benzyl‐4‐ferrocenyl‐1H‐[1,2,3]‐triazole/carbon nanotube modified glassy carbon electrode for voltammetric determination of hydrazine in water samples

The electrochemical behaviour of hydrazine at a 1‐benzyl‐4‐ferrocenyl‐1H‐[1,2,3]‐triazole‐triazole/carbon nanotube modified glassy carbon electrode has been studied. The modified electrode shows an excellent electrocatalytic activity for the oxidation of hydrazine and accelerates electron transfer rate. The electrocatalytic current increases linearly with hydrazine concentration in the range 0.5–700.0 μm and the detection limit for hydrazine was 33.0 ± 2.0 nm . The diffusion coefficient (D = 2.5 ± 0.1 × 10^?5 cm² s^?1) and kinetic parameters such as the electron transfer coefficient, (α = 0.52) and the heterogeneous rate constant (k′ = 5.5 ± 0.1 × 10^?3 cm s^?1) for hydrazine were determined using electrochemical approaches. Finally, the method was employed for the determination of hydrazine in water samples. Copyright © 2013 John Wiley & Sons, Ltd.     

Study of structural changes and mesomorphic transitions of oriented poly(ethylene therephthalate) fibers in supercritical CO2

Supercritical carbon dioxide (scCO₂), an environmentally friendly solvent, can change the fine structure of fibers depending on treatment temperature and pressure. Samples of partially oriented yarn (POY) PET fibers were uniaxially drawn below the glass transition temperature (T_g) and then exposed to scCO₂ under tension to induce morphological changes in them. The effects of draw ratio and scCO₂ exposure on the structural changes and mesomorphic transitions were evaluated. For this purpose, thermal characteristics of the structure, especially the rearrangement of polymer chains in the amorphous phase induced by cold-drawing and exposure to scCO₂, were evaluated by differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR). The orientation factor of the fibers was measured using a polarizing microscope. The paracrystalline portion and the crystallite sizes of exposed samples were estimated by wide-angle X-ray diffraction. To evaluate the solubility of CO₂ molecules in the samples, density and fractional free volumes were also measured. A good correlation was obtained between the results obtained from various measurement techniques. Results showed that cold-drawing of PET fibers leads to a strain-induced crystallization and that exposure to scCO₂ changes the structure of the oriented PET samples. To investigate mesophase transitions, percentage of extended chains in the amorphous regions was calculated by analyzing the results of DSC and FTIR. Results showed that the amount of extended chains developing during cold-drawing in the amorphous regions decreased when exposed to scCO₂.