Selective and sensitive voltammetric sensor based on modified multiwall carbon nanotubes paste electrode for simultaneous determination of l-cysteine and folic acid

This paper reports the selective and sensitive voltammetric determination of l-cysteine in the presence of folic acid using ethynylferrocene modified carbon nanotubes paste electrode in 0.1 M phosphate buffer solution (pH 7.0). Using square wave voltammetry, we could measure l-cysteine and folic acid in one mixture independently from each other by a potential difference of about 410 mV for the first time. Square wave voltammetric peak current of l-cysteine and folic acid increased linearly with their concentrations in the ranges of 0.2–250.0 and 1.0–500.0 μmol?L^?1, respectively. The detection limits of 0.07 and 0.6 μmol?L^?1 were achieved for l-cysteine and folic acid, respectively. The proposed voltammetric sensor was successfully applied to the determination of l-cysteine and folic acid in real samples.     

Legendre multiwavelet collocation method for solving the linear fractional time delay systems

In this article the Legendre multiwavelet basis with aid of collocation method has been applied to give approximate solution for fractional delay systems. The properties of Legendre multiwavelet are presented. These properties together with the collocation method are then utilized to reduce the problem to the solution of algebraic system. Numerical results and comparison with exact solutions in the cases when we have exact solution are given in test examples in order to demonstrate the applicability and efficiency of the method.     

A novel chemically modified carbon paste electrode based on a new mercury(II) complex for selective potentiometric determination of bromide ion

A new modified carbon paste electrode based on a recently synthesized mercury (II) complex of a pyridine containing proton transfer compound as a suitable carrier for Br⁻ ion is described. The electrode has a linear dynamic range between 3.00×10⁻² and 1.0×10⁻⁵ M with a near-Nernastian slope of 61.0±0.9 mV per decade and a detection limit of 4.0×10⁻⁶ M (0.32 ppm). The potentiometric response is independent of the pH of the solution in the pH range 4.0–8.3. The electrode possesses the advantages of low resistance, fast response and good over a variety of other anions. It was applied as an indicator electrode in potentiometric titration of bromide ions and for the recovery of Br⁻ from tap water.     

The C*-algebra of the N-dimensional harmonic oscillator

In this paper we study the Fredholm thoery of a C*-algebraOl of o-order pseudo-differential operators on L²(ⁿ). IfK denotes the ideal of all compact operators of L², the algebraOl will be generated by (i) the idealK, (ii) a function algebra CS(ⁿ) and (iii) by the bounded operators x_j, D_j, j=1,...,n, = H^–1/2, H=1+¦x¦²–. We show thatOl/K is a commutative C*-algebra with identity and obtain its Gelfany space M. This provides Fredholm criterion and index formula for a graded algebra of partial differential operators including all oeprators with polynomial coefficients. We also give Fredholm criterion and index formula for systems of such operators.     

On fuzzy linear projection equation and applications

This paper introduces the concept of fuzzy projection of a fuzzy number on a set of fuzzy numbers based on r-cut approach. It is proved that the projection of a fuzzy number on the set of all fuzzy numbers is itself and under a special metric, the proposed fuzzy projection is a non-expansive mapping. By using this definition, the concept of fuzzy linear projection equation is defined and to solve it, a numerical method is applied. Based on the proposed algorithm and as an important application, two different types of system of fuzzy linear equations with fuzzy variables are solved. Numerical results illustrate the applicabilities of proposed approach.     

Preparation of Zinc (II) and cadmium (II) complexes of the tetradentate Schiff base ligand 2-((E)-(2-(2-(pyridine-2-yl)- ethylthio)ethylimino)methyl)-4-bromophenol (PytBrsalH)

We describe the synthesis and characterization of two new zinc (II) and cadmium (II) complexes of the tetradentate dissymmetric Schiff base ligand 2-((E)-(2-(2-(pyridine-2-yl)ethylthio)ethylimino)methyl)-4-bromophenol (PytBrsalH), prepared from 1-(2-pyridyl)-3-thia-5-aminopentane (pyta) and 5-bromosalicylaldehyde. The complexes were synthesized by treating an ethanolic solution of the ligand with equimolar amounts of appropriate metal salts in 1 M methanolic solution of NaOH or alternatively, by a more direct route in which the two reactants are added to a solution of the ligand immediately after formation of the latter and prior to any isolation. The complexes were characterized by elemental analysis, FTIR, (1)H-NMR, electronic spectra and molar conductivity. According to obtained data, the probable coordination geometries of zinc and cadmium in these complexes with mixed N, S and O donor atoms are tetrahedral- and octahedral-like,respectively. Both complexes were found to be 1:1 electrolyte systems in acetonitrile.     

Existence and stability analysis of bifurcating periodic solutions in a delayed five-neuron BAM neural network model

In this paper, a bidirectional associative memory (BAM) neural network model, which consists of two neurons in the X-layer and three neurons in the Y-layer, with two time delays, will be considered. By analyzing the associated characteristic equation, we obtain that Hopf bifurcation occurs and a family of periodic solutions appears. Moreover, the stability and the period of the bifurcating periodic solutions are studied. To illustrate our theoretical results, numerical simulations are presented.     

Structural Diversity in the Solid-State Structures of the Rubidium and Cesium Salts of 2,6-Dimesitylphenylphosphane

A coordination environment reminiscent of a paddle-wheel is exhibited by aryl groups about one of the two cesium ions in CsP(H)Dmp (Dmp=2,6-dimesitylphenyl; structure depicted on the right), which has now been synthesized and is found to exhibit Cs⁺{Cs₂[P(H)Dmp]₃}⁻ contact ion pairs in the solid state. In contrast, the analogous rubidium compound displays a Rb₄P₄ cube as the central structural motif.     

Ion trap collisional activation of the deprotonated deoxymononucleoside and deoxydinucleoside monophosphates

Deoxymononucleoside and deoxydinucleoside monophosphate anions formed by electrospray have been subjected to ion trap collisional activation. The threshold for decomposition via loss of base is significantly lower for the deoxymononucleoside 3′-monophosphates than for the corresponding 5′-monophosphates, which indicates that the presence of a charged 3′ phosphate group facilitates base loss. The behavior of the bases among each class of isomers shows slight variation in threshold and tandem mass spectrometry efficiency with tile notable exception of 2′-deoxyguanosine 5′-monophosphate. This ion is exceptionally stable toward decomposition via base loss, which reflects a strong hydrogen bonding interaction between the base and the phosphate group. All dinucleotides fragment via similar mechanisms, but the propensity for neutral base loss relative to loss of a charged base is highly dependent on the identities of both the 5′ and 3′ bases. The behavior of the dinucleotides under collisional activation conditions supports the proposal that base loss proceeds via a proton-bound dimer intermediate in which loss of the charged base directly competes with loss of the neutral base. Application of the kinetic method allows for quantitative predictions of the differences of the gas-phase acidities of the dimer components.