The capillary force in micro- and nano-indentation with different indenter shapes

The influence of the indenter shapes and various parameters on the magnitude of the capillary force is studied on the basis of models describing the wet adhesion of indenters and substrates joined by liquid bridges. In the former, we consider several shapes, such as conical, spherical and truncated conical one with a spherical end. In the latter, the effects of the contact angle, the radius of the wetting circle, the volume of the liquid bridge, the environmental humidity, the gap between the indenter and the substrate, the conical angle, the radius of the spherical indenter, the opening angle of the spherical end in the truncated conical indenter are included. The meniscus of the bridge is described using a circular approximation, which is reasonable under some conditions. Different dependences of the capillary force on the indenter shapes and the geometric parameters are observed. The results can be applicable to the micro- and nano-indentation experiments. It shows that the measured hardness is underestimated due to the effect of the capillary force.     

BBOⅠ类相位匹配光参量放大中群速失配的补偿

描述了在BBOⅠ类相位匹配的飞秒光参量放大（OPA）中，利用非共线结构和倾斜抽运光的脉 冲波面来完全补偿三波群速失配的方法.理论计算了三波群速匹配时，非共线角、相位匹配 角、抽运光的脉冲波面倾斜角随信号光波长的变化，并分析了对抽运光光斑尺寸的要求和对 空间走离长度的影响.结果表明，利用该方法不仅能够实现最大的参量带宽，而且能够完全 补偿飞秒OPA中三波的群速失配.此外，选取合适的抽运光光斑尺寸和非线性晶体的长度对提 高参量增益也至关重要. 关键词： 群速匹配 非共线相位匹配 脉冲波面倾斜 飞秒光参量放大     

飞秒光参量放大中三波群速失配的补偿

为了消除群速失配对参量放大的不利影响，描述了利用脉冲波面倾斜与非共线相位匹配相结 合，完全补偿飞秒光参量放大（OPA）中三波群速失配的新方法.计算了在BBOⅠ类、Ⅱ类相 位匹配条件下， 三波实现群速匹配时，相位匹配角、脉冲波面倾斜角以及非共线角随信号 光波长的变化.并分析了三波群速匹配对空间走离长度、参量增益和参量带宽的影响.结果表 明，在BBOⅠ类、Ⅱ类相位匹配条件下，利用该方法均能实现飞秒OPA连续调谐时三波的群速 匹配，从而大大增加了三波的有效互作用长度，为能够获得高增益，窄脉宽的参量光脉冲提 供了理论依据和指导. 关键词： 群速匹配 脉冲波面倾斜 非共线相位匹配 飞秒光参量放大     

On Triazoles. XIII. The reaction of 5-benzalimino-1,2,4-triazoles with substituted acetyl chlorides

The reaction of Schiff bases prepared from 1- and 2-substituted-5-amino-1,2,4-triazoles with phenoxyacetyl chlorides in the presence of triethylamine and a mixture of phosphorus oxychloride and dichloroacetic acid in dimethylformamide to yield β-lactam 4 , a dihydro-1,2,4-triazolo[4,3-a]pyrimidine-5(1H)-one 5, a 1,2,4-triazolo[1,5-a]pyrimidin-5(3H)-one 9 and the corresponding 1,2,4-triazolo[4,3-a]pyrimidine-5(1H)-one 10 derivatives was studied.     

氩气/空气介质阻挡放电自组织超六边形斑图实验研究

采用双水电极介质阻挡放电装置,在氩气/空气混合气体放电中,在三种边界条件下得到了一种新型的超六边形斑图.给出了超六边形斑图的傅里叶变换及其不同模强度随旋转角的变化.实验测量了超六边形斑图随空气含量和外加电压变化的相图.研究了超六边形斑图的时空动力学,发现超六边形斑图是由两套子结构嵌套而成.在四边形边界条件下,研究了放电面积的大小对斑图模式选择的影响.发现超四边形斑图的形成受边界条件影响很大,而超六边形斑图则是自组织的结果. 关键词： 介质阻挡放电 超六边形斑图 时空动力学 边界条件     

H_2气氛退火处理对Nb掺杂TiO_2薄膜光电性能的影响

采用电子束沉积方法,以钛酸锶(SrTiO3)为衬底制备铌(Nb)掺杂TiO2薄膜并研究后续H2气氛退火处理对其薄膜样品光电性能的影响.结果发现H2气氛热退火处理能有效改善Nb掺杂TiO2薄膜的导电率,最佳电阻率达到5.46×10-3Ω·cm,在可见光范围内的透光率为60%—80%.导电性能的改善与H2气氛退火处理后多晶薄膜的晶粒尺寸变大和大量的氧空位形成及H原子掺杂有关.     

Stereochemical studies—75 : Saturated heterocycles—62. connection between the diastereoselectivity and the dominant conformation in the formation of condensed- skeleton 1,3-oxazines,first X-ray diffraction evidence of N-outside conformation

The rapid, spontaneous epimerization occurring at the C(2) chirality centre of a new diastereomeric (r-4,c-2,c-5)-2-(p-nitrophenyl)-3-methyl-4,5-tetramethylenetetrahydro-1,3-oxazine led to the conclusion that the configuration at C(2) of the bicyclic 1,3-oxazines formed by the cyclization of alicyclic 1,3-aminoalcohols with aldehydes is determined by the dominant conformation of the product. The first X-ray diffraction evidence is given for the N-outside conformation of compounds of this type.     

Synthesis and Stereostructure of Saturated Isoindolone-Fused Hetero Tri-, Tetra-, and Pentacyclic Compounds

Summary. t-2-Benzoyl-t-4-phenylcyclohexane-r-1-carboxylic acid reacts with hydrazine to give the saturated 1,7-diphenyl-trans-phthalazin-4(3H)-one. The reaction of the acid with ethylenediamine yields diastereomeric trans-imidazo[2,3-a]isoindoles, which differ in their C-1 configuration. The cyclizations of the acid with cis-2-aminocyclohexane- or 4-cyclohexenemethanol result in trans-isoindolo[2,1-a][3,1]benzoxazines, while in its reactions with the analogous di-endo- and di-exo-norbornane- and -norborneneamino alcohols, the acid gives methylene-bridged isomeric di-endo-norbornanes or a norbornene derivative; the corresponding diastereomeric di-exo derivatives have also been prepared. After isolation, the structures were established by means of ¹H and ¹³C NMR spectroscopy, with application of DIFFNOE, DEPT, HMQC, HMBC, and 2D-COSY techniques.