排序方式: 共有37条查询结果,搜索用时 15 毫秒
11.
Menka Petkovska 《Adsorption》2008,14(2-3):223-239
A new method for investigation of adsorption equilibrium and kinetics, named Nonlinear Frequency Response-Zero Length Column
(NFR-ZLC) method, is introduced. It combines the advantages of the Nonlinear FR method (the potential to identify a model
corresponding to the most probable kinetic mechanism and to estimate the equilibrium and kinetic parameters of the identified
model) and of the ZLC method (the potential to derive direct information about the processes on the particle level, by eliminating
the influence of the adsorber). The frequency response functions of a ZLC system, up to the third order, and for three simple
kinetic mechanisms (film resistance control, micropore diffusion control and pore-surface diffusion control) are derived and
simulated. The procedure for estimation of the equilibrium and kinetic parameters is defined and illustrated based on numerical
simulations. 相似文献
12.
The detailed structural characterization of complex polymer architectures, like copolymers and polymer mixtures, by mass spectrometry
presents a challenge. Even though soft ionization analyses revolutionized the characterization of large molecules and provided
a means for determining the polymer’s molecular weight distribution, polydispersity, and end groups, full microstructure elucidation
and monomer sequencing by soft ionization alone is not possible. The combination of high-resolution Fourier transform mass
spectrometry (FTMS) and tandem mass spectrometry (MSn) provides a powerful analytical tool for addressing these challenges. This tool was used in our work to separate and identify
the products of polymerization between 12-hydroxystearic acid (HSA) and stearic acid (SA), to provide precise information
about the exact location of caprolactones on the Tris(2-hydroxyethyl)isocyanurate (THEIC) molecule, and to sequence a glycidyl
methacrylate/methyl methacrylate (GMA/MMA) copolymer. The results highlight the value of ultrahigh resolution and tandem mass
spectrometry for fine structural characterization and sequencing of polymers. 相似文献
13.
In order to estimate single solute adsorption isotherms, the nonlinear frequency response (FR) of a chromatographic column is analyzed experimentally and evaluated using the concept of higher order frequency response functions (FRFs) based on the Volterra series and generalized Fourier transform. In this case study, it has been investigated the adsorption of ethyl benzoate on octadecyl silica from a mixture of methanol and water (60:40) as a solvent. Experiments are performed using a standard gradient HPLC unit. For estimation of adsorption isotherms by the nonlinear FR method the column inlet concentration is changed in a nearly sine waveform around several steady-state concentrations. Using this method the first three local derivatives of a single solute adsorption isotherm are estimated from the low frequency asymptotes of the corresponding functions, i.e. the phase and first order derivative of the FRFs. For an accurate estimation of isotherm coefficients periodical experiments should be preformed for frequencies below a certain critical frequency. This is the frequency needed for approaching the low frequency asymptotic behaviour of the corresponding functions close enough, so that errors due to the non-feasibility of experiments with zero frequency can be neglected. Unfortunately, depending on the properties of the system, it can happen (as for the system investigated here) that experiments for the critical frequency would be too long and cannot be realized. In order to study the loss of accuracy of the nonlinear FR method, when it is applied for non-optimal frequencies, experiments are performed for frequencies approximately one order of magnitude higher than the critical frequency required to evaluate the FRF phases. The obtained isotherm model coefficients are compared with the ones estimated using conventional frontal analysis as a reference method. The isotherms determined by two methods are similar, however a closer look reveals that peaks predicted under overloading conditions differ. 相似文献
14.
Tadić V Bojović D Arsić I Dorđević S Aksentijevic K Stamenić M Janković S 《Molecules (Basel, Switzerland)》2012,17(3):2683-2703
Sideritis scardica Griseb., Lamiaceae (ironwort, mountain tea), an endemic plant of the Balkan Peninsula, has been used in traditional medicine in the treatment of antimicrobial infections, gastrointestinal complaints, inflammation and rheumatic disorders. This study reports a comparison between conventional (hydrodistillation HD and solvent extraction SE) and alternative (supercritical carbon dioxide SC CO?) extraction methods regarding the qualitative and quantitative composition of the obtained extracts as analyzed by GC and GC-MS techniques and their anitimicrobial activity. Different types of extracts were tested, the essential oil EO obtained by HD, EO-CO? and AO-CO? obtained by SC CO? at different preasures 10 and 30 MPa, at 40 °C, respectively, and the fractions A, B, C and D obtained by successive solvent extraction (SE) A: ethanol, B: diethyl ether, C: ethyl acetate and D: n-butanol). While EO was characterized by the presence of the high percentage of oxygenated monoterpenes and sesquiterpenes (30.01 and 25.54%, respectively), the rest of the investigated samples were the most abundant in fatty acids and their esters and diterpenes (from 16.72 to 71.07% for fatty acids and their esters, and from 23.30 to 72.76%, for diterpenes). Microbial susceptibility tests revealed the strong to moderate activity of all investigated extracts against the tested microorganisms (MIC from 40 to 2,560 μg/mL). Although differences in the chemical compositions determined by GC and GC-MS analysis were established, the displayed antimicrobial activity was similar for the all investigated extracts. 相似文献
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16.
Menka Petkovska Danijela Antov-Bozalo Ana Markovic Patrick Sullivan 《Adsorption》2007,13(3-4):357-372
Mathematical modeling of an Electric-Swing Adsorption (ESA) system (adsorption cycle with electrothermal desorption step,
performed by direct heating of the adsorbent particles by passing electric current through them), with annular, radial-flow,
cartridge-type fixed-bed and in-vessel condensation, is performed by using Comsol Multiphysics™ software. Three multiphysics
models are built, in order to describe three stages of a compete ESA cycle: adsorption, electrothermal desorption before the
start of condensation and electrothermal desorption with in-vessel condensation. In order to describe the complete ESA cycle
the models for the three stages are integrated, by using a combination of Comsol Multiphysics™ and Matlab™. The models were
successfully used for simulation of separate stages of the process and of the complete ESA cycles, as well as for investigation
of the influences of the main operational parameters on the process performance.
The views and conclusions contained herein are those of the author and should not be interpreted as necessarily representing
the official policies or endorsements, either expressed or implied, of the Air Force Office of Scientific Research or the
U.S. Government. 相似文献
17.
Milica Ilić Menka Petkovska Andreas Seidel-Morgenstern 《Journal of chromatography. A》2009,1216(33):6108-6118
This paper demonstrates an experimental application of the nonlinear frequency response (FR) method extension to determine adsorption isotherms of binary mixtures. This method, based on the analysis of the response of a chromatographic column subjected to the sinusoidal inlet concentration changes, is shown to be an alternative for isotherm determination. The critical issue related to the successful application of the method is to reach experimentally the low frequency asymptotic behaviour of the corresponding frequency response functions (FRFs). Although, there are different possibilities to perform periodical inlet concentration changes, in this paper only simultaneous changes for both components were considered. The adsorption of phenol and 2-phenylethanol on octadecyl silica was analyzed experimentally using a mixture of methanol and water as a solvent. Parameters of competitive isotherms were also estimated for comparison using the classical perturbation method. Despite certain differences between competitive isotherms estimated with the two methods that were found, the obtained results show the potential of the nonlinear FR method for measuring competitive isotherms. 相似文献
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19.
Berta Holló Milena Krstić Sofija P. Sovilj György Pokol Katalin Mészáros Szécsényi 《Journal of Thermal Analysis and Calorimetry》2011,105(1):27-32
Thermal decomposition of chlorpromazine hydrochloride (CP·HCl), trifluoperazine dihydrochloride (TF·2HCl) and thioridazine
hydrochloride (TR·HCl), and the ruthenium complexes with dimethyl sulfoxide (dmso) of composition [RuCl2(dmso)4] and L[RuCl3(dmso)3]·xEtOH, L = CP·HCl, TF·2HCl or TR·HCl is described. The phenothiazines are stable to temperature range of 200–280 °C with an
increasing stability order of TF·2HCl < CP·HCl < TR·HCl. The decomposition of all the compounds takes place in superposing
steps. For detection of chlorides and sulfides, EGD analysis was performed. The decomposition pattern of the complexes, due
to their similar structure, is similar. The thermal data unambiguously resolve the contradiction between the elemental analysis
and X-ray structural data for (TF·2HCl)[RuCl3(dmso)3]Cl·EtOH. The compound crystallizes with one EtOH, evaporating in part at room temperature. 相似文献
20.
Berta Holló Milena Krstić Sofija P. Sovilj Katalin Mészáros Szécsényi 《Journal of Thermal Analysis and Calorimetry》2013,111(3):1927-1932
The thermal decomposition of [RuCl2(η6-p-cymene)]2 (1) and its biologically active N-alkylphenothiazine compounds of composition L[RuCl3(η6-p-cymene)] where L = CPH+ (2), TFH+·HCl (3), and TRH+ (4) (chlorpromazine hydrochloride, CP·HCl; trifluoperazine dihydrochloride, TF·2HCl; and thioridazine hydrochloride, TR·HCl, respectively) has been studied. The crystal and molecular structure of compound 3 was determined earlier by single crystal X-ray diffraction analysis. The thermal data were collected by simultaneous TG/DSC measurements. For evolved gas detection, the qualitative reaction of chlorides with AgNO3 in an acidic solution was applied. The measurements were carried out in the temperature range to 700 °C in nitrogen atmosphere. Compounds of L[RuCl3(η6-p-cymene)] crystallize with water or water/2-propanole. On the basis of thermal data, the trend in the solvent bonding energies was assessed. 相似文献