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71.
Andromahi Tegou Sofia Papadimitriou Georgios Kokkinidis Sotirios Sotiropoulos 《Journal of Solid State Electrochemistry》2010,14(2):175-184
Platinized nickel and cobalt coatings, Pt(Ni) and Pt(Co), have been prepared on glassy carbon, GC, rotating disc electrode
substrates by a two-step room temperature procedure that involved the electrodeposition of nickel and cobalt layers and their
spontaneous partial replacement by platinum (“transmetalation”) when immersed into a chloroplatinic acid solution. By tuning
the quantity of initially deposited nickel and cobalt, Pt(Ni) and Pt(Co) bimetallic coatings having a 26% atom Ni and 30%
atom Co composition have been prepared. For both materials typical Pt surface electrochemistry was recorded during fast voltammetry
in deaerated acid, pointing to the existence of a continuous Pt skin over a Pt–Ni and Pt–Co core. Oxygen reduction at the
Pt(Ni)/GC and Pt(Co)/GC electrodes was studied by means of steady-state voltammetry at a rotating disc electrode and the construction
of Tafel plots from corresponding voltammetric data. It was found that, when the initial potential of the voltammetric sweep
allowed the formation of a complete Pt oxide monolayer, then oxygen reduction was hindered for low overpotentials at Pt(Ni)
and Pt(Co), compared to pure bulk Pt. On the other hand, when the initial potential was less positive (thus leading to the
formation of a fraction of surface oxide monolayer) the presence of Ni and Co enhanced the kinetics of oxygen reduction. The
former behaviour is attributed to a decrease in oxide reduction ability of Pt in the presence of Ni and Co, while the latter
to an increase in dissociative oxygen chemisorption due to Ni and Co. 相似文献
72.
Sofia Georgakakou Michael Kazanis Irene Panderi 《Analytical and bioanalytical chemistry》2010,397(6):2161-2170
A validated method based on liquid chromatography/positive ion electrospray–mass spectrometry (LC-ESI/MS) is described for the quantification of perindopril and its active metabolite, perindoprilat, in human plasma. The assay was based on 500-μL plasma samples, following solid-phase extraction using Oasis HLB cartridges. All analytes and the internal standard (trandolapril) were separated by hydrophilic interaction liquid chromatography using a SeQuant Zic-HILIC analytical column (150.0?×?2.1 mm i.d., particle size 3.5 μm, 200 Å) with isocratic elution. The mobile phase consisted of 10% 5.0 mM ammonium acetate water solution in a binary mixture of acetonitrile/methanol (60:40, v/v) and pumped at a flow rate of 0.10 mL min?1. Quantitation of the analytes was performed with selected ion monitoring (SIM) in positive ionization mode using electrospray ionization interface. The assay was found to be linear in the concentration range of 5.0–500.0 ng mL?1 for perindopril and perindoprilat. Intermediate precision were found less than 3.5% over the tested concentration ranges. A run time of less than 6.0 min for each sample made it possible to analyze a large number of human plasma samples per day. The method is the first reported application of HILIC in the analysis of angiotensin-converting enzyme inhibitors and can be used to quantify perindopril and perindoprilat in human plasma covering a variety of pharmacokinetic or bioequivalence studies. 相似文献
73.
Sofia Quinodoz Michael A. Thomas Jörn Dunkel Eva-Maria Schötz 《Journal of statistical physics》2011,142(6):1324-1336
The trade-off between traits in life-history strategies has been widely studied for sexual and parthenogenetic organisms,
but relatively little is known about the reproduction strategies of asexual animals. Here, we investigate clonal reproduction
in the freshwater planarian Schmidtea mediterranea, an important model organism for regeneration and stem cell research. We find that these flatworms adopt a randomized reproduction
strategy that comprises both asymmetric binary fission and fragmentation (generation of multiple offspring during a reproduction
cycle). Fragmentation in planarians has primarily been regarded as an abnormal behavior in the past; using a large-scale experimental
approach, we now show that about one third of the reproduction events in S. mediterranea are fragmentations, implying that fragmentation is part of their normal reproductive behavior. Our analysis further suggests
that certain characteristic aspects of the reproduction statistics can be explained in terms of a maximum relative entropy
principle. 相似文献
74.
We demonstrate the acquisition of stimulated Raman scattering spectra with the use of a single femtosecond pulse. High-resolution vibrational spectra are obtained by shifting the phase of a narrow band of frequencies within the input pulse spectrum, using spectral shaping. The vibrational lines are resolved via amplitude features formed in the spectrum after interaction with the sample. Using this technique, low-frequency Raman lines (<100 cm?1) are observed on both the Stokes and anti-Stokes sides. 相似文献
75.
76.
Elena Pyanzina Sofia Kantorovich Juan J. CerdàChristian Holm 《Journal of magnetism and magnetic materials》2011,323(10):1263-1268
In this paper we present theoretical and simulation results on the structure factor of mono- and bidisperse ferrofluids with chain aggregates, both with and without an applied external magnetic field. Chain distribution is obtained by the density functional theory (DFT). The radial distribution function (RDF) is calculated directly on the basis of the chain distribution and Fourier transformed to calculate the structure factor. An extensive comparison of the theoretical predictions to the results of the molecular dynamics computer simulations is provided. The proposed combined approach allows to elucidate the connection between experimentally observed small angle neutron scattering (SANS) images and the ferrofluid microstructure. 相似文献
77.
Joint optimization of spare parts ordering and maintenance policies for multiple identical items subject to silent failures 总被引:1,自引:0,他引:1
In this paper the joint maintenance and spare parts ordering problem for more than one identical operating items is studied. The operating items may suffer two types of silent failures: a minor failure, which results in item malfunctioning, and a major failure, which renders the item completely out-of-function. Inspections are periodically held to detect any failures and the inspected items are preventively maintained, repaired or replaced according to their condition. Two ordering policies are investigated to supply the necessary spare parts: a periodic review and a continuous review policy. The expected total maintenance and inventory cost per time unit is derived and the proposed models are optimized for real case data. In addition, the sensitivity of the proposed models is studied through numerical examples and the effect of some key problem characteristics on the optimal decisions is discussed. 相似文献
78.
79.
The concept of uniform connectedness is introduced into the theory of nearness frames. Various equivalent conditions of this concept are presented in this setting. 相似文献
80.
Semidilute solution structure of cellulose in an ionic liquid and its mixture with a polar organic co‐solvent studied by small‐angle X‐ray scattering
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Sofia Napso Dmitry M. Rein Rafail Khalfin Yachin Cohen 《Journal of Polymer Science.Polymer Physics》2017,55(11):888-894
Structural and thermodynamic properties of cellulose solutions in the ionic liquid 1‐ethyl‐3‐methylimidazolium acetate (EMIMAc) and its binary mixtures with N,N‐dimethyl formamide (DMF) are studied by small‐angle X‐ray scattering (SAXS). These measurements indicate molecular dissolution of the cellulose chains without any significant aggregation. The power–law relationships of the evaluated correlation length and osmotic modulus to concentration exhibit exponents of ?0.76 and 2.06 for EMIMAc and ?0.80 and 2.14 for DMF/EMIMAc solvent mixture, respectively. Thus, these solvents can be considered to be good solvents for cellulose. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55 , 888–894 相似文献