Semidilute solution structure of cellulose in an ionic liquid and its mixture with a polar organic co‐solvent studied by small‐angle X‐ray scattering

Structural and thermodynamic properties of cellulose solutions in the ionic liquid 1‐ethyl‐3‐methylimidazolium acetate (EMIMAc) and its binary mixtures with N,N‐dimethyl formamide (DMF) are studied by small‐angle X‐ray scattering (SAXS). These measurements indicate molecular dissolution of the cellulose chains without any significant aggregation. The power–law relationships of the evaluated correlation length and osmotic modulus to concentration exhibit exponents of ?0.76 and 2.06 for EMIMAc and ?0.80 and 2.14 for DMF/EMIMAc solvent mixture, respectively. Thus, these solvents can be considered to be good solvents for cellulose. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55 , 888–894     

Blue-LED Synthesis of Pummerer's Ketones by Peroxidase-Lignin-Catalyzed Oxidative Coupling of Substituted Phenols

Pummerer's ketones resembling the tricyclic scaffold of bioactive natural substances were synthesized by blue-LED driven Horseradish Peroxidase oxidative coupling of substituted phenols in 2-methyltetrahydrofuran by using meso-tetraphenylporphyrin as photosensitizer and dioxygen as primary oxidant. The application of functionalized lignin nanoparticles as a renewable and efficient platform for the immobilization of the enzyme extended the effectiveness of the overall process to heterogeneous catalysis under buffer limiting conditions.     

A Categorical Structure for the Virtual Braid Group

This article gives a new interpretation of the virtual braid group in terms of a strict monoidal category SC that is freely generated by one object and three morphisms, two of the morphisms corresponding to basic pure virtual braids and one morphism corresponding to a transposition in the symmetric group. This point of view makes many relationships between the virtual braid group and the pure virtual braid group apparent, and makes representations of the virtual braid groups and pure virtual braid groups via solutions to the algebraic Yang–Baxter Equation equally transparent. In this categorical framework, the virtual braid group has nothing to do with the plane and nothing to do with virtual crossings. It is a natural group associated with the structure of algebraic braiding.     

Infinite dimensional duality and applications

The usual duality theory cannot be applied to infinite dimensional problems because the underlying constraint set mostly has an empty interior and the constraints are possibly nonlinear. In this paper we present an infinite dimensional nonlinear duality theory obtained by using new separation theorems based on the notion of quasi-relative interior, which, in all the concrete problems considered, is nonempty. We apply this theory to solve the until now unsolved problem of finding, in the infinite dimensional case, the Lagrange multipliers associated to optimization problems or to variational inequalities. As an example, we find the Lagrange multiplier associated to a general elastic–plastic torsion problem.     

Value theory without symmetry

We investigate quasi-values of finite games – solution concepts that satisfy the axioms of Shapley (1953) with the possible exception of symmetry.  Following Owen (1972), we define “random arrival', or path, values: players are assumed to “enter' the game randomly, according to independently distributed arrival times, between 0 and 1; the payoff of a player is his expected marginal contribution to the set of players that have arrived before him.  The main result of the paper characterizes quasi-values, symmetric with respect to some coalition structure with infinite elements (types), as random path values, with identically distributed random arrival times for all players of the same type.  General quasi-values are shown to be the random order values (as in Weber (1988) for a finite universe of players).  Pseudo-values (non-symmetric generalization of semivalues) are also characterized, under different assumptions of symmetry. Received: April 1998/Revised version: February 2000     

On countable connected locally connected almost regular Urysohn spaces

We construct connected, locally connected, almost regular, countable, Urysohn spaces. This answers a problem of G.X. Ritter. We show that there are 2^c such non-homeomorphic spaces. We also show that there are 2^c non-homeomorphic spaces which are further rigid. We discuss the group of homeomorphisms of such spaces.The following question was raised by G.X. Ritter: Does there exist a countable connected locally connected Urysohn space which is almost regular? We answer this question in the affirmative and in fact, show that not only are there as many as 2^c such spaces but that there are just as many rigid spaces with the same properties. Furthermore we show that every countable Urysohn space is a subspace of such a space. We also prove that every countable group is isomorphic to the group of autohomeomorphisms of some connected locally connected almost regular Urysohn space. Examples are given of groups of order c which can be represented in this manner.     

The exterior magnetic field for the multilayer ellipsoidal model of the brain

The magnetic induction field in the exterior of an ellipsoidallyinhomogeneous, four-conducting-layer model of the human headis obtained analytically up to its quadrupole approximation.The interior ellipsoidal core represents the homogeneous brainwhile each one of the shells represents the cerebrospinal fluid,the skull and the scalp, all characterized by different conductivities.The inhomogeneities of these four domains, together with theanisotropy imposed by the use of the ellipsoidal geometry, providethe most realistic physical and geometrical model of the brainfor which an analytic solution of the biomagnetic forward problemis possible. It is shown that in contrast to the spherical model,where shells of different conductivity are magnetically invisible,the magnetic induction field in ellipsoidal geometry is stronglydependent on the conductivity supports. The fact that sphericalshells of different conductivity are invisible has enhancedthe common belief that the biomagnetic forward solution doesnot depend on the conductivity profiles. As we demonstrate inthe present work, this is not true. Hence, the proposed multilayeredellipsoidal model provides a qualitative improvement of therealistic interpretation of magnetoencephalography (MEG) measurements.We show that the presence of the shells of different conductivitycan be incorporated in the form of the dipole vector for thehomogeneous model. Numerical investigations show that the effectsof shell inhomogeneities are almost as sound as the level ofMEG measurements themselves. The degenerate cases, where eitherthe differences of the conductivities within the shells disappear,or the ellipsoidal geometry is reduced to the spherical one,are also considered.     

Structure formation and phase behaviour in ferrofluid monolayers: theory and computer simulations

In order to investigate the peculiarities brought by the quasi-2D geometry into the aggregation processes in ferrofluids, a combination of density functional theory (DFT), and molecular dynamics (MD) simulations is presented. The microstructure formation and the phase behaviour of monodisperse ferrofluid monolayers is studied. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)