Investigation on the stress behavior of cellulose acetate and the development of highly moisture‐resistant optical films for display devices

An optical film with high optical anisotropy was prepared by the stretching of a cellulose acetate film and the consequential orienting of a retardation‐enhancing additive. The change in retardation in response to moisture absorption was explored and it was found that the degree of the retardation variation is strongly related to the stretching temperature. Stress generated by the stretching and its relaxation was systematically investigated to elucidate the effect of stretching temperature on the irreversible change in retardation upon moisture absorption. The results show that the magnitude of releasable stress plays an important role in controlling changes in optical properties. In addition, the difference in the deformation behavior between glassy and rubbery states should be taken into account in the development of a moisture‐resistant optical film. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 1470–1478     

Thermal stability of ester linkage in the presence of 1,2,3‐Triazole moiety generated by click reaction

The copper(I)‐catalyzed alkyne‐azide cycloaddition (CuAAC), so‐called “click” reaction, is one of most useful synthetic strategies to connect two polymer chains. 1,2,3‐Triazole ring (TA) produced by the click reaction has good thermal and chemical stability. However, we observed that block copolymers synthesized by the click reaction showed thermal degradation to give homopolymers when they are thermally annealed at high temperature, which is required for obtaining equilibrium microdomain structure. To investigate the origin of thermal instability of block copolymers, we synthesized model polystyrenes (PSs) using systematically designed bi‐functional atom transfer radical polymerization (ATRP) initiators containing TA. PS including both ester and TA groups showed thermal decomposition at relatively low temperature (e.g., 140 °C). MALDI‐TOF analysis clearly demonstrated that the cleavage site is the ester group adjacent to TA. We also found that the bromine group located at the polymer chain end plays an important role in pyrolysis of ester groups at low temperature. The pyrolysis occurs by syn‐elimination of the ester group. This result implies that the phase behavior of block copolymer synthesized by click reaction should be carefully investigated when high temperature thermal annealing is required. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 427–436     

Turbulence Modeling Effects on the Prediction of Equilibrium States of Buoyant Shear Flows

The effects of turbulence modeling on the prediction of equilibrium states of turbulent buoyant shear flows were investigated. The velocity field models used include a two-equation closure, a Reynolds-stress closure assuming two different pressure-strain models and three different dissipation rate tensor models. As for the thermal field closure models, two different pressure-scrambling models and nine different temperature variance dissipation rate ɛ_τ) equations were considered. The emphasis of this paper is focused on the effects of the ɛ_τ-equation, of the dissipation rate models, of the pressure-strain models and of the pressure-scrambling models on the prediction of the approach to equilibrium turbulence. Equilibrium turbulence is defined by the time rate of change of the scaled Reynolds stress anisotropic tensor and heat flux vector becoming zero. These conditions lead to the equilibrium state parameters, given by /ɛ, _τ/ɛ_τ, , Sk/ɛ and G/ɛ, becoming constant. Here, and _τ are the production of turbulent kinetic energy k and temperature variance , respectively, ɛ and ɛ_τ are their respective dissipation rates, R is the mixed time scale ratio, G is the buoyant production of k and S is the mean shear gradient. Calculations show that the ɛ_τ-equation has a significant effect on the prediction of the approach to equilibrium turbulence. For a particular ɛ_τ-equation, all velocity closure models considered give an equilibrium state if anisotropic dissipation is accounted for in one form or another in the dissipation rate tensor or in the ɛ-equation. It is further found that the models considered for the pressure-strain tensor and the pressure-scrambling vector have little or no effect on the prediction of the approach to equilibrium turbulence. Received 21 April 2000 and accepted 21 February 2001     

An explicit algebraic Reynolds stress and heat flux model for incompressible turbulence: Part I Non-isothermal flow

Tensor representation theory is used to derive an explicit algebraic model that consists of an explicit algebraic stress model (EASM) and an explicit algebraic heat flux model (EAHFM) for two-dimensional (2-D) incompressible non-isothermal turbulent flows. The representation methodology used for the heat flux vector is adapted from that used for the polynomial representation of the Reynolds stress anisotropy tensor. Since the methodology is based on the formation of invariants from either vector or tensor basis sets, it is possible to derive explicit polynomial vector expansions for the heat flux vector. The resulting EAHFM is necessarily coupled with the turbulent velocity field through an EASM for the Reynolds stress anisotropy. An EASM has previously been derived by Jongen and Gatski [10]. Therefore, it is used in conjunction with the derived EAHFM to form the explicit algebraic model for incompressible 2-D flows. This explicit algebraic model is analyzed and compared with previous formulations including its ability to approximate the commonly accepted value for the turbulent Prandtl number. The effect of pressure-scrambling vector model calibration on predictive performance is also assessed. Finally, the explicit algebraic model is validated against a 2-D homogeneous shear flow with a variety of thermal gradients. Dedicated to the memory of the late Professor Charles G. Speziale of Boston University     

Swirl effects on variable-density jet mixing in confined flows

An experimental investigation on swirl effects on inhomogeneous confined jet mixing in a combustor configuration is reported. The confined swirling flow was simulated by a swirler with a central jet mounted in a cyclindrical tube. Helium and air jets set at different velocities were injected into the confined swirling air flow. The resulting flow fields due to two vane swirlers with constant vane angles of 35° and 66° were compared. Results show that the 35° vane swirler produces a solid-body rotation core with a slope about twice that created by the 66° vane swirler. It is the behavior of this solid-body rotation core that determines jet mixing rather than the swirler vane angle. Consequently, the coaxial jet decays much faster, the mixing is more intense, and the turbulence intensities are higher for the 35° vane swirler. In view of these results, combustor designers should be more concerned with behavior of the solid-body rotation core produced by the swirler, instead of the swirler vane angle.     

A non-linear fluid force model for vortex-induced vibration of an elastic cylinder

Even under the assumption of a sinusoidal lift and drag force at a single frequency for a stationary cylinder in a cross flow, higher harmonics that represent non-linearity in the fluid-structure interaction process are present. This fact is considered in the formulation of a non-linear fluid force model for a freely vibrating cylinder in a cross flow. The force model is developed based on an iterative process and the modal analysis approach. The fluid force components in the model can be evaluated from measured vibration data with the help of the auto-regressive moving averaging (ARMA) technique. An example is used to illustrate that non-linear (higher order) force components are present at resonance, even for a case with relatively weak fluid-structure interaction. Further analysis reveals that the fluid force components are dependent on structural damping and mass ratio. The non-linear fluid force model is further modified by taking these considerations into account and is used to predict the dynamic characteristics of a freely vibrating cylinder over a range of Reynolds numbers, mass and structural damping ratios. On comparison with measurements obtained from four different experiments and predictions made by previous single-degree-of-freedom model, good agreement is found over a wide range of these parameters.