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101.
Kenneth J. Hochberg Amir Sandach Mitchell Snyder Uzi Vishne 《Methodology and Computing in Applied Probability》2013,15(4):987-1002
Risk-score indices are a simple, applicable, and easy-to-calculate tool for regression models, which can be used when computers are not available. The risk-score index is a partial summation of the rounded model coefficients that maintains essential properties of the model coefficients, such as their weight in the model and the correlation matrix. In a certain sense, the risk score can be viewed as a transformation into a pre-selected scale. The risk score is generally represented as a point estimate. Thus, the risk-score index is a categorical variable that relates each and every category uniquely to risk. The main argument of this paper is that the risk score, which is calculated as a partial summation of rounded beta coefficients, is a statistic, and, therefore, it has its own variance. This variance is divided into three factors—the original β-coefficients variances, the rounding-error variance, and the variance from the relations between these two factors. Since the variance of the score is typically not negligible, it is preferable to consider the confidence interval centered at the point estimate and not just the point estimate itself. By using the confidence interval for the risk score, one can quantify the accuracy of the score and also compare different scores, which otherwise is not always possible. 相似文献
102.
Maxwell Thomas Dylla Stephen Dongmin Kang G. Jeffrey Snyder 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(17):5557-5566
Perovskite oxides are candidate materials in catalysis, fuel cells, thermoelectrics, and electronics, where electronic transport is vital to their use. While the fundamental transport properties of these materials have been heavily studied, there are still key features that are not well understood, including the temperature‐squared behavior of their resistivities. Standard transport models fail to account for this atypical property because Fermi surfaces of many perovskite oxides are low‐dimensional and distinct from traditional semiconductors. In this work, the low‐dimensional Fermi surfaces of perovskite oxides are chemically interpreted in terms of two‐dimensional crystal orbitals that form the conduction bands. Using SrTiO3 as a case study, the d/p‐hybridization that creates these low‐dimensional electronic structures is reviewed and connected to its fundamentally different electronic properties. A low‐dimensional band model explains several experimental transport properties, including the temperature and carrier‐density dependence of the effective mass, the carrier‐density dependence of scattering, and the temperature dependence of resistivity. This work highlights how chemical bonding influences semiconductor transport. 相似文献
103.
104.
Zhou Y Beeler AB Cho S Wang Y Franzblau SG Snyder JK 《Journal of combinatorial chemistry》2008,10(4):534-540
The chemistry of 5,6,7,8-tetrahydro-1,6-naphthyridine scaffolds, synthesized by intramolecular cobalt-catalyzed [2 + 2 + 2] cyclizations, has been exploited for library synthesis. Urea, amide, and sulfonamide formations were used in the synthesis of a 101-membered library. Screening of the library for antituberculosis activity revealed three lead compounds. 相似文献
105.
Analysis of formaldehyde formation in wastewater using on-fiber derivatization-solid-phase microextraction-gas chromatography-mass spectrometry 总被引:1,自引:0,他引:1
A method has been developed for the quantification of the formation of formaldehyde during the advanced oxidation treatment (AOT) of wastewater destined for reuse. This method uses solid-phase microextraction (SPME) with on-fiber derivatization followed by gas chromatography-mass spectrometry (GC-MS) analysis. Based on calculated method detection limits (MDL) and ambient background levels, the method reporting (MRL) limit for formaldehyde was set at 10 microg/L. Precision for formaldehyde using this technique resulted in 23% relative standard deviation (RSD), while the internal standard, acetone-d(6), was only 6%. This method was used to evaluate the formation of formaldehyde in bench scale UV-AOT experiments using natural organic matter (NOM) fortified reagent water and tertiary treated wastewater effluent. Results suggest that the formation of formaldehyde increases in both the reagent water and wastewater matrices with increasing UV exposure and hydrogen peroxide concentrations, with overall higher concentrations of formaldehyde in the wastewater samples. No appreciable amount of formaldehyde formation was observed when UV was applied in the absence of hydrogen peroxide in both matrices tested. 相似文献
106.
JPC – Journal of Planar Chromatography – Modern TLC - The role of the mobile phase in controlling selectivity for adsorption chromatography–with either thin-layer plates or... 相似文献
107.
Xu S Wei Y Kirkham M Liu J Mai W Davidovic D Snyder RL Wang ZL 《Journal of the American Chemical Society》2008,130(45):14958-14959
We report an approach for growing aligned ZnO nanowire arrays with a high degree control over size, orientation, dimensionality, uniformity, and possibly shape. Our method combines e-beam lithography and a low temperature hydrothermal method to achieve patterned and aligned growth of ZnO NWs at <100degreesC on general inorganic substrates, such as Si and GaN, without using catalyst. This approach opens up the possibility of applying ZnO nanowires as sensor arrays, piezoelectric antenna arrays, two-dimensional photonic crystals, IC interconnects, and nanogenerators. 相似文献
108.
In the present report, we have crystallized a single enantiomer and the racemate of N-3,5-dinitrobenzoyl (DNB) leucine. In both cases, the X-ray structures show clear evidence of homochiral dimerization in the solid state. Moreover, only homochiral dimers were observed in the unit cell of the racemate, a result of solid-state enantioselective complexation. The crystal structures support a chiral recognition mechanism involving two hydrogen bonds and an offset pi-pi interaction between the DNB rings. 相似文献
109.
Hierarchical nanomanufacturing: from shaped zeolite nanoparticles to high-performance separation membranes 总被引:1,自引:0,他引:1
Despite more than a decade of intense research on the high-resolution selectivity of thin zeolite films as alternatives to energy-intensive industrial separations, membranes consisting of intergrown, oriented zeolite crystals have fallen short of gaining wide commercial application. Factors including poor performance, high cost, and difficulties in scale up have contributed to this, and have also stunted their application in other niche markets. Until recently, rational design of these materials was limited because of the elusive mechanism of zeolite growth, and forced more empirical approaches. New understanding of zeolite growth along with recent advances in the molecular engineering of crystal microstructure and morphology, assembly of crystal monolayers, and synthesis of ordered films constitute a strong foundation for meeting stringent industrial demands in the future. Together with new processing capabilities, such a foundation should make it possible to synthesize commercially viable zeolite membranes through hierarchical approaches. Such advances open exciting prospects beyond the realm of separations for assembly of novel and complex functional materials including molecular sensors, mechanically stable dielectrics, and novel reaction-diffusion devices. 相似文献
110.