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101.
Seema Yadav Sriparna Ray Ajeet Singh Shaikh M. Mobin Tapta Kanchan Roy Chandrakanta Dash 《应用有机金属化学》2020,34(11):e5942
Dinuclear gold(I)-N-heterocyclic carbene complexes were developed for the hydrohydrazidation of terminal alkynes. The gold(I)-N-heterocyclic carbene complexes 2a-2b were synthesized in good yields from silver complexes synthesized in situ, which in turn were obtained from the corresponding imidazolium salts with Ag2O in dichloromethane as a solvent. The new air-stable gold(I)-NHC complexes, 2a - 2b, were characterized using NMR spectroscopy, elemental analysis, infrared, and mass spectroscopy studies. The gold(I) complex 2a was characterized using X-ray crystallography. Bis-N-heterocyclic carbene–based gold(I) complexes 2a - 2b exhibited excellent catalytic activities for hydrohydrazidation of terminal alkynes yielding acylhydrazone derivatives. The working catalytic system can be used in gram-scale synthesis. In addition, the catalytic reaction mechanism of the hydrohydrazidation of terminal alkynes by gold(I)-NHC complex was studied in detail using density functional theory. 相似文献
102.
103.
Versatile pathways for in situ polyolefin functionalization with heteroatoms: catalytic chain transfer 总被引:1,自引:0,他引:1
Chain-transfer processes represent highly effective chemical means to achieve selective, in situ d- and f-block-metal catalyzed functionalization of polyolefins. A diverse variety of electron-poor and electron-rich chain-transfer agents, including silanes, boranes, alanes, phosphines, and amines, effect efficient chain termination with concomitant carbon-heteroelement bond formation during single-site olefin-polymerization processes. High polymerization activities, control of polyolefin molecular weight and microstructure, and selective chain functionalization are all possible, with distinctly different mechanisms operative for the electron-poor and electron-rich reagents. A variety of metal centers (early transition metals, lanthanides, late transition metals) and single-site ancillary ligand arrays (metallocene, half-metallocene, non-metallocene) are able to mediate these selective chain-termination/functionalization processes. 相似文献
104.
Selenite adsorption on water-washed manganese nodule leached residues (WMNLR) was studied with the aim of detoxifying industrial effluents before their safe disposal into the environment. WMNLR, a solid waste material, was characterized with the help of XRD, FTIR, TG-DTA, pH(pzc), BET surface area, surface oxygen, surface hydroxyl group, and chemical analyses. The adsorption behavior of WMNLR toward selenite was studied as a function of time, pH, temperature, and concentration of adsorbate and adsorbent. Increased adsorption capacity with rise in temperature indicates that the adsorption process was endothermic in nature. Based on the thermodynamic parameters such as the Gibbs free energy change, standard enthalpy change, and standard entropy change, the adsorption process was found to be spontaneous and endothermic in nature. Adsorption followed second-order kinetics. The adsorption capacity of the material was found to be 54.6 mg g(-1) at 60 mg L(-1) of selenite concentration at pH 5 in 3 h contact time. 相似文献
105.
The kinetics of base hydrolysis of some (aminomonocarboxylato)(tetraethylenepentamine)cobalt(III) complexes, [(tetren)CoO2CR]2+ (R= NH2CH2, pyridine‐2 , NH2CH2CH2, NH2CH(CH3) (αβS isomer); R= NH2CH(CH3) (αβR isomer)), have been investigated in methanol–water media (0–80 vol % MeOH) at 15.0≤t°C≤40.0 (0.02 mol dm−3 NaOH). The second‐order rate constant at zero ionic strength, k2°, increases nonlinearly with XMeOH. The transfer free energy of the initial state and the transition state of the amido conjugate base ([ΔtG (i)](s←w)) for the glycinato‐ and pyridine‐2–carboxylato complexes have been calculated using the solubility data of their picrate salts, pK NH date of their N‐protonated forms, and the k2° values in mixed solvent media. The kinetic solvent effects have been interpreted in terms of preferential solvation of the initial state, transition state, and the solvent structure. The activation enthalpies and entropies varied nonlinearly with XMeOH displaying extrema, which is attributable to the solvent structural effects on these thermodynamic parameters. It is also evident that the mutation process, αβR→αβS isomer for the α‐alaninato complex, where this isomerisation refers to the arrangement of the tetren skeleton around the planar secondary NH is sensitive to the nature of the cosolvent molecules and solvent structure. The mutation process is generally more favorable for the five coordinate amido conjugate bases than the initial state. © 1999 John Wiley & Sons, Inc. Int J Chem Kinet 31: 55–64, 1999 相似文献
106.
Condition monitoring is implementation of the advanced diagnostic
techniques to reduce downtime and to increase the efficiency and reliability.
The research is for determining the usage of advanced techniques like Vibration
analysis, Oil analysis and Thermography to diagnose ensuing problems of the
Plant and Machinery at an early stage and plan to take corrective and preventive
actions to eliminate the forthcoming breakdown and enhancing the reliability of
the system. Nowadays, the most of the industries have adopted the condition
monitoring techniques as a part of support system to the basic maintenance strategies.
Major condition monitoring technique they follow is Vibration Spectrum
Analysis, which can detect faults at a very early stage. However implementation
of other techniques like Oil analysis or Ferrography, Thermography etc. can
further enhance the data interpretation as they would detect the source of abnormality
at much early stage thus providing us with a longer lead time to plan and take
the corrective actions. In Large Captive Power Plants and Aluminium Smelters,
Integrated Condition Monitoring techniques play an important role as stoppage
of primary system and its auxiliaries (boiler, steam turbine, generator, coal and
ash handling plants etc.) results into the stoppage of the entire plant, which in turn
leads to loss of productivity. From economical and operational point of view, it is
desirable to ensure optimum level of system availability. 相似文献
107.
108.
Growth of Ag islands under ultrahigh vacuum condition on air-exposed Si(0 0 1)-(2 × 1) surfaces has been investigated by in-situ reflection high energy electron diffraction (RHEED). A thin oxide is formed on Si via exposure of the clean Si(0 0 1)-(2 × 1) surface to air. Deposition of Ag on this oxidized surface was carried out at different substrate temperatures. Deposition at room temperature leads to the growth of randomly oriented Ag islands while well-oriented Ag islands, with (0 0 1)Ag||(0 0 1)Si, [1 1 0]Ag||[1 1 0]Si, have been found to grow at substrate temperatures of ≥350 °C in spite of the presence of the oxide layer between Ag islands and Si. The RHEED patterns show similarities with the case of Ag deposition on H-passivated Si(0 0 1) surfaces. 相似文献
109.
S. Kataria Satyaprakash Sahoo S.A. Barve S. Dash D.S. Patil A.K. Tyagi A.K. Arora 《Solid State Communications》2009,149(43-44):1881-1883
Diamond-like carbon films are deposited on silicon substrates at different substrate bias using ECR-CVD technique. Raman spectroscopic studies show the presence of broad G and D peaks. In contrast to the position of D peak, the G peak shows a systematic red-shift with increase in the bias voltage. From the analysis it is found that an increase in bias voltage decreases the sp2 cluster diameter. Furthermore, two additional Raman peaks at around 690 and 880 cm?1 are also observed. These peaks, forbidden in the first order Raman scattering, arise due to the breakdown of phonon selection rule in graphitic nanoclusters. 相似文献
110.
The comonomer 5-hexenylsilane is introduced into organotitanium-mediated ethylene polymerizations to produce silane-terminated ethylene/5-hexenylsilane copolymers. The resulting polymers were characterized by 1H and 13C NMR, GPC, and DSC. High activities (up to 107 g polymer/(mol Ti.atm ethylene.h)) and narrow polydispersities are observed in the polymerization/chain transfer process. Ethylene/5-hexenylsilane copolymer molecular weights are found to be inversely proportional to 5-hexenylsilane concentration, supporting a silanolytic chain transfer mechanism. Control experiments indicate that chain transfer mechanism by 5-hexenylsilane is significantly more efficient than that of n-hexylsilane for organotitanium-mediated ethylene polymerization. The present study represents the first case in which a functionalized comonomer is efficiently used to effect both propagation and chain transfer chemistry during olefin polymerization. 相似文献