Thermoanalytical study of water-based aluminium rolling fluids combined with direct observation

During cold-rolling of aluminium sheets the auxiliary lubricant fluids used decompose giving rise to discolouring of the sheet surface. In the present study a combined TGA-DTG-DTA analysis has been used in combination with direct observation of the colour change of carboxylate-based fluids in oxidizing and inert atmosphere to determine the temperature region of decomposition and/or polymerization. Significant effects have been observed depending not only on the type of atmosphere but also on the type of the cationic part of the organic component in these fluids.     

Field of linear frames as a fundamental self-interacting system

We present some philosophical and physical arguments supporting the hypothesis that the most fundamental self-interacting field in an amorphous space-time is the field of linear frames, i.e. the quadruple of vector bosons. We construct a wide class of Lagrangian dynamical models invariant under the total group of diffeomorphisms and under the natural action of the proper linear group GL⁺ (4, R) on the tetrad field. There exist some links between these models and the Hamiltonian dynamical systems on GL⁺ (3, R) (the mechanics of affinely-rigid bodies [23] [27]). We present the general form of field equations, conservation laws and Bianchi identities. There exist some formal similarities between our Lagrangians and those used in non-linear electrodynamics, in particular in the Born–Infeld theory [21]. We also give a few rough remarks concerning models invariant under natural subgroups of GL⁺ (4, R), i.e. under SL(4, R) and SO(1, 3; R) (special linear group and Lorentz group). The latter class includes the conventional Einstein relativity and the more general metrical-parallelism models. It turns out that there are GL⁺ (4, R)-invariant Lagrangians which are structurally alike the conventional Einstein Lagrangian.We have not derived as yet either mathematical or physical consequences of the presented model. Nevertheless, it seems to follow from our discussion that, a priori, the GL⁺ (4, R)-invariant tetrad models could be competitive with the Einstein theory. The next thing to be done would be a careful mathematical analysis of these models and attempts to compare their consequences with those of the Einstein relativity and of other field theories.     

Локалъная чувствите лъностъ фотокатодов фотоумножителей

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The local sensitivity of photo-multiplier photo-cathodes

The influence of the non-uniform distribution of the sensitivity of a photo-multiplier photo-cathode on the spectrum shape of the output pulses from a scintillation detector is studied. Methods of scanning the local sensitivity and determining its distribution function are described. The theory was compared qualitatively with measurement on a slow-neutron detector from a mixture of zinc sulphate and boric acid.

     

Two-barrier detector

The paper describes the principle of a detector with two opposite surface barriers and the experimental verification of its functioning. The detector permits double the effective depth to be attained on the material with a given bias voltage. The principle of opposite barriers also permits a reduction in the system of dE/dx andE detectors to one detector.

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The authors thank A. Irra for carefully preparing the plates, K. Putz and J. imková for very effective help in measuring on the cyclotron and the members of of the cyclotron staff for their cooperation.     

Eine polarographische Methode zur Bestimmung von 3-(α-Phenyl-β-acetyl-äthyl)-4-hydroxycumarin (Warfarin)

Ohne Zusammenfassung     

Analytic wave functions and energies for two-dimensional \mathcal{P}\mathcal{T} -symmetric quartic potentials

Analytic wave functions and the corresponding energies for a class of the $ \mathcal{P}\mathcal{T} $ -symmetric two-dimensional quartic potentials are found. The general form of the solutions is discussed.     

Hydrogen adsorption on palladium and palladium hydride at 1 bar

The dissociative sticking probability for H₂ on Pd films supported on sputtered Highly Ordered Pyrolytic Graphite (HOPG) has been derived from measurements of the rate of the H–D exchange reaction at 1 bar. The sticking probability for H₂, S, is higher on Pd hydride than on Pd (a factor of 1.4 at 140 °C), but the apparent desorption energy derived from S is the same on Pd and Pd hydride within the uncertainty of the experiment. Density Functional Theory (DFT) calculations for the (1 1 1) surfaces of Pd and Pd hydride show that, at a surface H coverage of a full mono layer, H binds less strongly to Pd hydride than to Pd. The activation barrier for desorption at a H coverage of one mono layer is slightly lower on Pd hydride, whereas the activation energy for adsorption is similar on Pd and Pd hydride. It is concluded that the higher sticking probability on Pd hydride is most likely caused by a slightly lower equilibrium coverage of H, which is a consequence of the lower heat of adsorption for H on Pd hydride.