Studies on some ternary complexes of copper(II) involving an amino penicillin drug

Multiple equilibrium studies by pH-metric measurements in the ternary copper(II) complexes with ampicillin(amp) as ligand A and glycine(gly), dl-2-aminobutanoic acid(2aba), dl-3-aminobutanoic acid(3aba), 1,2-diaminopropane(dp), 1,3-diaminopropane(tp), dl-2,3-diaminopropanoic acid(dapa), dl-2,4-diaminobutanoic acid(daba) & dl-2,5-diaminopentanoic acid(ornithine)(orn) as ligands B show the presence of CuABH, CuAB or CuAH?1 B ternary complex species. In the CuAB species the binding of the ligands A and B is similar to their binding in their respective binary complexes. In CuABH_?1 species the deprotonation occurs with amp(A) ligand. The Δlog K values indicate higher stabilities for the ternary complexes than the binary species. The CuAB species with B = gly, 2aba, dapa & orn have been isolated and characterized. The conductivity measurements indicate that the complexes are non-electrolytes. Magnetic susceptibility and electronic spectral data suggest a square pyramidal geometry for CuAB with B = gly/2aba complexes and distorted octahedral geometry for CuAB with B = dapa/orn. The vibrational spectra are interpreted to find the mode of binding of ligand to metal. The TG/DTA studies reveal that the complexes decompose in three steps, indicating non-involvement of hydrated or coordinated water molecules in the complex. The cyclic voltammograms indicate a quasi reversible Cu²⁺/Cu⁺ couple. The antimicrobial activity and CT-DNA cleavage ability of the complexes show higher activity for ternary complexes.     

Photo switchable pendant furyl and thienyl fulgimides containing polypyrroles

We report the new pendant furyl and thienyl fulgimides photochromic switch bearing polypyrroles. The functionalized pyrrole monomers synthesized and structures are ascertained by NMR and mass spectral techniques. The yield of fulgides and fulgimides are improved by using trifluoroacetic anhydride (TFA) as a dehydrating agent. The photo-switching properties of fulgimides monomers are explained by electronic structures of HOMO–LUMO of the monomers using Gaussian 03 packages. The electro-active polymer films deposited on indium tin oxide (ITO) electrodes are characterized by cyclic voltammetry and atomic force microscopy (AFM). The electrochemically formed thin films undergoes photo-switching between open and closed state of fulgimides moiety. The photo-switching properties of the polymer films have been confirmed by UV/vis spectroscopy. Though the films are photochemically stable, their mechanical stability with respect to adhesion to electrode is found to be sensitive to the solvent and electrode material.     

Double diffusive convection of anomalous density fluids in a porous cavity

A numerical study has been performed to analyze the combined effect of temperature and species gradients on the buoyancy-driven natural convection flow of cold water near its density extremum contained in a porous cavity. The governing equations are descretized using the finite volume method. The results of the investigation are presented in the form of steady-state streamlines, velocity vectors, isotherms, and isoconcentrationlines. The results are discussed for different porosities, Darcy numbers, and Grashof numbers. The heat and mass transfer rates calculated are found to behave nonlinearly with hot wall temperature. The heat and mass transfer are increased with increasing Darcy number and porosity. It is found that the convective heat and mass transfer rate are greatly affected by the presence of density maximum.     

Synthesis, spectroscopic, antimicrobial, DNA binding and cleavage studies of some metal complexes involving symmetrical bidentate N, N donor Schiff base ligand

The Schiff base ligand, N,N′-bis-(4-isopropylbenzaldimine)-1,2-diaminoethane (L), obtained by the condensation of 4-isopropylbenzaldehyde and 1,2-diaminoethane, has been used to synthesize the complexes of the type [ML₂X₂] [M = Co(II), Ni(II) and Zn(II); X = Cl and OAc]. The newly synthesized ligand (L) and its complexes have been characterized on the basis of elemental analyses, mass, ¹H and ¹³C-NMR, molar conductance, IR, UV–vis, magnetic moment, CV and thermal analyses, powder XRD and SEM. IR spectral data show that the ligand is coordinated to the metal ions in a bidentate manner. The geometrical structures of these complexes are found to be octahedral. Interestingly, reaction with Cu(II) ion with this ligand undergoes hydrolytic cleavage to form ethylenediamine copper(II) complex and the corresponding aldehyde. The antimicrobial results indicate that the chloro complexes exhibit more activity than the acetato complexes. The complexes bind to CT–DNA by intercalation modes. Novel chloroform soluble ZnL₂Cl₂ complex exhibits tremendous antimicrobial, DNA binding and cleaving properties.     

Enhanced response of microbial fuel cell using sulfonated poly ether ether ketone membrane as a biochemical oxygen demand sensor

The present study is focused on the development of single chamber microbial fuel cell (SCMFC) using sulfonated poly ether ether ketone (SPEEK) membrane to determine the biochemical oxygen demand (BOD) matter present in artificial wastewater (AW). The biosensor produces a good linear relationship with the BOD concentration up to 650 ppm when using artificial wastewater. This sensing range was 62.5% higher than that of Nafion^®. The most serious problem in using MFC as a BOD sensor is the oxygen diffusion into the anode compartment, which consumes electrons in the anode compartment, thereby reducing the coulomb yield and reducing the electrical signal from the MFC. SPEEK exhibited one order lesser oxygen permeability than Nafion^®, resulting in low internal resistance and substrate loss, thus improving the sensing range of BOD. The system was further improved by making a double membrane electrode assembly (MEA) with an increased electrode surface area which provide high surface area for electrically active bacteria.     

Non-isothermal flow through a rotating straight duct with wide range of rotational and pressure driven parameters

Numerical study is performed to investigate the Non-isothermal flow in a rotating straight duct under various flow conditions. Spectral method is applied as a main tool for the numerical technique, where the Chebyshev polynomial, the Collocation methods, the Arc-length method and the Newton-Raphson method are also used as secondary tools. The characteristics of the flow mentioned above are described here. The incompressible viscous steady Non-isothermal flow through a straight duct of rectangular cross-section rotating at a constant angular velocity about the center of the duct cross-section is investigated numerically to examine the combined effects of Rotation parameter (Coriolis force), Grashof number (parameter which is used in heat, transfer studies involving free, forced or natural convection and is equql to \(\frac{{L^3 g\beta \Delta {\rm T}}}{{v^2 }}\), where L is the characteristic length, ρ the density, g the acceleration due to gravity, β the thermal expansion coefficient, ΔT the temperature difference, μ the viscosity and ν the kinematic viscosity of the fluid. The expansion coefficient β is a measure of the rate at which the volume V of the fluid changes with temperature at a given pressure P), Prandtl number, aspect ratio and Pressure-driven parameter (centrifugal force) on the flow. We examine the structures in case of rotation of the duct axis and the Pressure-driven parameter with large aspect ratio where other parameters are fixed. The calculations are carried out for 0 ≤ T _r ≤ 300, 2 ≤ γ ≤ 6, G _r = 100, P _r = 7.0 and 0 ≤ P _r ≤ 800 by applying the Spectral method. When Ω > 0 and the rotation is in the same direction as the Coriolis force enforces the centrifugal force, multiple solutions of Non-symmetric the secondary flow patterns with 10-vortex (maximum) are obtained in case of T _r = 100 and 150 with large aspect ratio. The intense of the temperature field is very strong near the heated wall in all cases. Finally, the overall solutions of the problems considered in conclusion.     

Observation of two state behavior in the instability spectra of saturable nonlinear media

We investigate the modulational instability (MI) in the saturable nonlinear system (SNL). We identified the unique behavior of MI in the SNL system, which we called as the two state behavior. Unlike the case of Kerr type nonlinearity the so called critical modulational frequency does not monotonously increases, rather behaves in such way, that the increase in power increases the CMF upto the saturation power, and further increase in power decreases the CMF. This behavior is identified to be unusual in the context of MI and thus makes the study of MI interesting.     

Effect of Discrete Heating on Natural Convection in a Rectangular Porous Enclosure

The main objective of this article is to study the effect of discrete heating on free convection heat transfer in a rectangular porous enclosure containing a heat-generating substance. The left wall of the enclosure has two discrete heat sources and the right wall is isothermally cooled at a lower temperature. The top and bottom walls, and the unheated portions of the left wall are adiabatic. The vorticity–stream function formulation of the governing equations is numerically solved using an implicit finite difference method. The effects of aspect ratio, Darcy number, heat source length, and modified Rayleigh number on the flow and heat transfer are analyzed. The numerical results reveal that the rate of heat transfer increases as the modified Rayleigh number and the Darcy number increases, but decreases on increasing the aspect ratio. The average heat transfer rate is found to be higher at the bottom heater than at the top heater in almost all considered parameter cases except for ε = 0.5. Also, the maximum temperature takes place generally at the top heater except for the case ε = 0.5, where the maximum temperature is found at the bottom heater. Further, the numerical results reveal that the maximum temperature decreases with the modified Rayleigh number and increases with the aspect ratio.     

Lie group analysis of natural convection heat and mass transfer in an inclined surface with chemical reaction

In this paper we examine the convective flow, heat and mass transfer of an incompressible viscous fluid past a semi-infinite inclined surface with first-order homogeneous chemical reaction by Lie group analysis. The governing partial differential equations are reduced to a system of ordinary differential equations using scaling symmetries. Numerical solutions of the resulting ordinary differential equations are obtained using the fourth-order Runge–Kutta method. From the numerical results, it is observed that the thickness of the momentum boundary layer increases with increasing the chemical reaction parameter and the Schmidt number. The thicknesses of the thermal and concentration boundary layers are decreased with increasing the chemical reaction parameter and the Schmidt number.