全文获取类型
收费全文 | 311篇 |
免费 | 12篇 |
国内免费 | 4篇 |
专业分类
化学 | 226篇 |
晶体学 | 17篇 |
力学 | 15篇 |
数学 | 17篇 |
物理学 | 52篇 |
出版年
2023年 | 5篇 |
2022年 | 6篇 |
2021年 | 8篇 |
2020年 | 7篇 |
2019年 | 17篇 |
2018年 | 9篇 |
2017年 | 8篇 |
2016年 | 22篇 |
2015年 | 12篇 |
2014年 | 13篇 |
2013年 | 33篇 |
2012年 | 29篇 |
2011年 | 30篇 |
2010年 | 19篇 |
2009年 | 9篇 |
2008年 | 12篇 |
2007年 | 14篇 |
2006年 | 13篇 |
2005年 | 12篇 |
2004年 | 6篇 |
2003年 | 6篇 |
2002年 | 6篇 |
1999年 | 1篇 |
1997年 | 1篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1935年 | 1篇 |
排序方式: 共有327条查询结果,搜索用时 15 毫秒
111.
The synthesis of one-dimensional titanium oxide nanostructures has been accelerated by performing the reaction in a microfluidic environment as opposed to a classical batch process. 相似文献
112.
Thangaraj Anand Gandhi Sivaraman Murugan Iniya Ayyanar Siva Duraisamy Chellappa 《Analytica chimica acta》2015
Chemosensors based on aminobenzohydrazide Schiff bases bearing pyrene/anthracene as fluorophores have been designed and synthesized for F− ion recognition. The addition of fluoride ions to the receptors causes a dramatically observable colour change from pale yellow to brown/red. 1H NMR studies confirm that the F− ion facilitates its recognition by forming hydrogen bond with hydrogens of amide and amine groups. Moreover these sensors have also been successfully applied to detection of fluoride ion in commercial tooth paste solution. 相似文献
113.
S. Lakshmi Reddy N. C. Gangi Reddy R. Rama Subba Reddy G. Siva Reddy P. Sambasiva Rao B. Jagannatha Reddy 《辐射效应与固体损伤》2013,168(9):537-543
Red sandalwood sample was subjected to ICP-mass spectrometer analysis for the determination of minor elements. The ash of the sample was also analysed for the presence of major elements. The minor elements present include Cu (281.256), Ba (3722.064), Sr (6365.482), Rb (45.285), Ce (49.863), Zn (375.433) and Pb (80.944) all in ppt. The major elements detected are Cd, Fe, Mn and Ni. Optical absorption spectrum indicates that Fe(III) and Ni(II) are in tetragonal distortion with octahedral geo-metry. ESR (electron spin resonance) spectral analysis also confirms Fe(III) in tetragonal distortion, and the g-values observed for Fe(III) are 6.52, 2.63 and 1.92 and for Mn(II) is 1.99. NIR spectrum is due to carbonate overtones and harmonics and water fundamentals. 相似文献
114.
B.V. Subba Reddy A.V. GaneshA. Siva Krishna G.G.K.S. Narayana KumarJ.S. Yadav 《Tetrahedron letters》2011,52(26):3342-3344
Ttandem ene-Prins cyclization between an aldehyde and an olefin tethered sugar aldehyde has been achieved using a catalytic amount of scandium triflate (10 mol %) at ambient temperature to give a novel series of sugar annulated pyranopyran derivatives in good yields with high selectivity. This is the first report on sugar based ene-Prins cyclization between an aldehyde and O-prenyl derivative of a sugar aldehyde. 相似文献
115.
Subhabrata Sen Siva R. KammaVenkata R. Potti Y.L.N. Murthy Avinash B. Chaudhary 《Tetrahedron letters》2011,52(43):5585-5588
We report a facile diversity oriented synthesis of α- and β-amino acids, by utilizing the pluripotent α-methylene group in a chiral bicyclic lactam as our key point of transformation. 相似文献
116.
117.
Solvents are known to affect the triplet state structure and reactivity. In this paper, we have employed time-resolved resonance Raman (TR3) spectroscopy to understand solvent-induced subtle structural changes in the lowest excited triplet state of thioxanthone. Density functional theory (DFT) combined with the self-consistent reaction field (SCRF) implicit solvation model has been used to calculate the vibrational frequencies in the solvents. Here, we report a unique observation of the coexistence of two triplets, which has been substantiated by the probe wavelength-dependent Raman experiments. The coexistence of two triplets has been further supported by photoreduction experiments carried out at various temperatures. 相似文献
118.
Characterization of nanometer-scale porosity in reservoir carbonate rock by focused ion beam-scanning electron microscopy 总被引:1,自引:0,他引:1
Sedimentary carbonate rocks are one of the principal porous structures in natural reservoirs of hydrocarbons such as crude oil and natural gas. Efficient hydrocarbon recovery requires an understanding of the carbonate pore structure, but the nature of sedimentary carbonate rock formation and the toughness of the material make proper analysis difficult. In this study, a novel preparation method was used on a dolomitic carbonate sample, and selected regions were then serially sectioned and imaged by focused ion beam-scanning electron microscopy. The resulting series of images were used to construct detailed three-dimensional representations of the microscopic pore spaces and analyze them quantitatively. We show for the first time the presence of nanometer-scale pores (50-300 nm) inside the solid dolomite matrix. We also show the degree of connectivity of these pores with micron-scale pores (2-5 μm) that were observed to further link with bulk pores outside the matrix. 相似文献
119.
Siva Prasad DasJeena Jyoti Boruah Hiran ChetryNashreen S. Islam 《Tetrahedron letters》2012,53(9):1163-1168
Clean conversion of a variety of sulfides and dibenzothiophene (DBT) to the corresponding sulfoxide or sulfone could be achieved in high yields at room temperature using mononuclear as well as dinuclear diperoxo complexes of tungsten as oxidants, by a variation of reaction conditions. The compounds could also effectively catalyze oxidation of sulfides by H2O2 to selectively yield sulfone with reasonably good turnover frequency (TOF). 相似文献
120.
Babita Mallick Adithya Lakhsmanna Siva Umapathy 《Journal of Raman spectroscopy : JRS》2011,42(10):1883-1890
In this paper, we report on the concept and the design principle of ultrafast Raman loss spectroscopy (URLS) as a structure‐elucidating tool. URLS is an analogue of stimulated Raman scattering (SRS) but more sensitive than SRS with better signal‐to‐noise ratio. It involves the interaction of two laser sources, namely, a picosecond (ps) Raman pump pulse and a white‐light (WL) continuum, with a sample, leading to the generation of loss signals on the higher energy (blue) side with respect to the wavelength of the Raman pump unlike the gain signal observed on the lower energy (red) side in SRS. These loss signals are at least 1.5 times more intense than the SRS signals. An experimental study providing an insight into the origin of this extra intensity in URLS as compared to SRS is reported. Furthermore, the very requirement of the experimental protocol for the signal detection to be on the higher energy side by design eliminates the interference from fluorescence, which appears on the red side. Unlike CARS, URLS signals are not precluded by the non‐resonant background and, being a self‐phase‐matched process, URLS is experimentally easier. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献